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Intercalant structure determination of ICl-graphite by X-ray absorption spectroscopy

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Chemical Physics of Intercalation

Part of the book series: NATO ASI Series ((NSSB,volume 172))

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Abstract

A x-ray absorption (XA) study of the local structure of intercalated ICl molecules in graphite is reported. The near-edge (NEXAFS) as well as the extended XA fine structure (EXAFS) measured on the Cl-K and I-LI, III thresholds contain informations on the chemical form of the intercalated molecules and on their relative positions. We observed a significant increase of the intramolecular I-Cl bondlength and we propose an improved model for the intercalate structure.

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Author information

Authors and Affiliations

  1. Fachbereich Physik, Freie Universität Berlin, D-1000, Berlin 33, Germany

    W. Krone, G. Wortmann & G. Kaindl

  2. Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-1000, Berlin 33, Germany

    R. Schlögl

Authors
  1. W. Krone
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  2. G. Wortmann
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  3. G. Kaindl
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  4. R. Schlögl
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Editor information

Editors and Affiliations

  1. ESPCI, Paris, France

    A. P. Legrand

  2. Domaine Universitaire, Talence, France

    S. Flandrois

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© 1987 Springer Science+Business Media New York

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Krone, W., Wortmann, G., Kaindl, G., Schlögl, R. (1987). Intercalant structure determination of ICl-graphite by X-ray absorption spectroscopy. In: Legrand, A.P., Flandrois, S. (eds) Chemical Physics of Intercalation. NATO ASI Series, vol 172. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9649-0_23

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  • DOI: https://doi.org/10.1007/978-1-4757-9649-0_23

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9651-3

  • Online ISBN: 978-1-4757-9649-0

  • eBook Packages: Springer Book Archive

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