Skip to main content

Recent Trends in Food Applications of Antioxidants

  • Chapter
Autoxidation in Food and Biological Systems

Abstract

In this paper, I shall discuss the important trends of the past seven years in applications of antioxidants in foods. The nature and course of lipid autoxidation and antioxidant action have been treated in a previous paper of this Symposium (Symposium, 1979), as has the effect of water activity. Other papers will deal with the biological effects of antioxidant use, including antimicrobial action. Natural antioxidants will also be treated elsewhere. Therefore, I shall discuss primarily the use of the commonly added synthetic antioxidants (Fig. 1) and four naturally occurring ones — α-tocopherol and ascorbic (Fig. 2), citric and phosphoric acids, which common usage seems to segregate from the “natural” antioxidants. In addition, I shall handle many secondary antioxygenic compounds and treatments, such as oxygen exclusion or scavenging, browning antioxidants, and products produced by fermentation, smoking, nitrite curing, and hydrolysis of vegetable protein.

This paper was presented at the Basic Symposium on “Food Lipids,” Institute of Food Technologists, St. Louis, MO, June 1979.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Abbot, J. and Waite, R., 1965, The effect of antioxidants on the keeping quality of whole milk powder. II. Tocopherols, J. Dairy Res., 32: 143.

    Article  CAS  Google Scholar 

  • Adamson, A. W., 1967, “Physical Chemistry of Surfaces,”, Second Edition, Interscience Publications, New York, p. 520.

    Google Scholar 

  • Allan, W. A. and Wood, H. L., 1970, Copper-catalyzed oxidation of linoleic acid in buffered aqueous solutions. J. Sci. Fd. Agr., 21: 282.

    Article  CAS  Google Scholar 

  • Anderson, R. H. and Huntley, T. E., 1964, Pro-oxidant effect of some carbonyl compounds in vegetable oils, JAOCS, 41: 686.

    Article  CAS  Google Scholar 

  • Anon, 1963, The Atlas HLB Systems, Fourth Printing, Atlas Chemical Industries, Wilmington, DE.

    Google Scholar 

  • Astill, B. D., Terhaar, C. J., Krasavage, W. J., Wolf, G. L., Roudabush, R. C., Fassett, D. W., and Morgareidge, K., 1975, Safety evaluation and biochemical behavior of monotertiarybutyl hydroquinone, JAOCS, 52: 53.

    Article  CAS  Google Scholar 

  • Aurand, W., Boone, N. H., and Giddings, G. G., 1977, Superoxide and singlet oxygen in milk lipid peroxidation, J. Dairy Sci., 60: 363.

    Article  CAS  Google Scholar 

  • Barnard, D., Bateman, L., Cole, E. R., and Cunneen, J. I., 1958, Sulfoxides and thiolsulfinates as inhibitors of autoxidation and other free radical reactions, Chem. and Ind. (Rev.), 918.

    Google Scholar 

  • Bateman, L., Bolland, J. L., Gee, G., 1951, Determination of absolute rate constants for olefinic oxidations by measurement of photochemical pre-and after-effects. Part II. -At “low” oxygen pressures, Trans. Faraday Soc., 47: 274.

    Article  CAS  Google Scholar 

  • Benedict, R. C., Strange, E. C., and Swift, C. E., 1975, Effect of lipid antioxidants on the stability of meat during storage, J. Agr. Food Chem., 23: 167.

    Article  CAS  Google Scholar 

  • Berner, D. L., Conte, J. A., and Jacobson, G. A., 1974, Rapid method for determining antioxidant activity and fat stability, JAOCS, 51: 292.

    Article  CAS  Google Scholar 

  • Betts, A. T. and Uri, N., 1963, Some unusual observations in comparison of liquid and solid phase autoxidation, Nature, 199: 568.

    Article  CAS  Google Scholar 

  • Betts, A. T. and Uri, N., 1966, The conversion of metal catalysts into inhibitors of autoxidation, Makromol. Chem., 95: 22.

    Article  CAS  Google Scholar 

  • Bishov, S. J. and Henick, A. S., 1974, The method of stabilizing foods with an antioxidant, U.S. Patent 3,852, 502.

    Google Scholar 

  • Bishov, S. J. and Henick, A. S., 1972, Antioxidant effect of protein hydrolyzates in a freeze-dried model system, J. Food Sci., 37: 873.

    Article  CAS  Google Scholar 

  • Bishov, S. J. and Henick, A. S., 1975, Antioxidant effect of protein hydrolyzates in freeze-dried model systems. Synergistic action with a series of phenolic antioxidants, J. Food Sci., 40:345.

    Google Scholar 

  • Bishov, S. J., Henick, A. S., Giffee, J. W., Nii, I. T., Prell, P. A., and Wolf, M., 1971, Quality and stability of some freezedried foods in “zero” oxygen headspace, J. Food Sci., 36: 532.

    Google Scholar 

  • Boehm, E. and Williams, R., 1945, Propyl gallate and autoxidation of oils, Quarterly J. Pharm. Pharmacology, 16: 232.

    Google Scholar 

  • Boehme, M. A. and Branen, A. L., 1977, Effects of food antioxidants on prostaglandin biosynthesis, J. Food Sci., 42: 1243.

    Article  CAS  Google Scholar 

  • Bolland, J. L. and Ten Have, P., 1947, The inhibitory effects of phenolic compounds on the thermal oxidation of ethyl linoleate, Disc. Far. Soc., 2: 252.

    Article  Google Scholar 

  • Braddock, R. J. and Dugan, L. R., Jr., 1973, Reaction of autoxidizing linoleate with coho salmon myosin, JAOCS, 50: 343.

    Article  CAS  Google Scholar 

  • Branen, A. L., 1975, Toxicology and biochemistry of butylated hydroxyanisole and butylated hydroxytoluene, JAOCS, 52: 59.

    Article  CAS  Google Scholar 

  • Branen, A. L., 1978, Antimicrobial effect of phenolic antioxidants, Abstract 77, 69th Ann. AOCS Spring Mtg., St. Louis, MO, JAOCS, 55: 242A.

    Google Scholar 

  • Brownlie, I. T. and Ingold, K. V., 1967, The inhibited autoxidation of styrene. Part VII. Inhibition by nitroxides and hydroxyl-amines, Can. J. Chem., 45: 2427.

    Article  CAS  Google Scholar 

  • Brugh, M., Jr., 1977, Butylated hydroxytoluene protects chickens exposed to Newcastle disease virus, Sci., 197: 1291.

    Article  CAS  Google Scholar 

  • Brunner, J. R., 1965, Physical equilibria in milk. The lipid phase, in: “Fundamentals of Dairy Chemistry,” B. H. Webb and A. H. Johnson, eds., Avi Publ. Co., Westport, CT, p. 403.

    Google Scholar 

  • Bullerman, L. B., Lieu, F. Y., and Scier, S. A., 1977, Inhibition of growth and aflatoxin production by cinnamon and clove oils. Cinnamic aldehyde and eugenol, J. Food Sci., 42: 1107.

    Article  CAS  Google Scholar 

  • Carlsson, D. J., Suprunchuk, T., and Wiles, D. M., 1976, Photooxidation of unsaturated oils: Effect of singlet oxygen quenchers, JAOCS, 53: 656.

    Article  CAS  Google Scholar 

  • Chahine, M. H. and MacNeill, R. F., 1974, Effect of stabilization of crude whale oil with tertiary butylhydroquinone and other antioxidants upon keeping quality of resultant deodorized oil, JAOCS, 51: 37.

    Article  CAS  Google Scholar 

  • Chio, K. S. and Tappel, A. L., 1969, Synthesis and characterization of the fluorescent products derived from malonaldehyde and amino acids, Biochem., 8: 2821.

    Article  CAS  Google Scholar 

  • Chipault, J. R., 1962, Antioxidants for use in foods, in: “Autoxidation and Antioxidants,” W. 0. Lundberg, ed., Interscience, Vol. 2, New York, p. 477.

    Google Scholar 

  • Chipault, J. R. and Hawkins, J. M., 1971, Lipid oxidation in freeze-dried meats, J. Agr. Food Chem., 19: 495.

    Article  CAS  Google Scholar 

  • Chipault, J. R., Mizuno, G. R., and Lundberg, W. 0., 1956, The antioxidant properties of spices in foods, Food Technol., 10: 209.

    CAS  Google Scholar 

  • Chou, H. E., Acott, K. M., and Labuza, T. P., 1973, Sorption hysteresis and chemical reactivity, J. Food Sci., 38: 316.

    Article  CAS  Google Scholar 

  • Cornell, D. G., DeVilbiss, E. D., and Pallansch, M. J., 1970, Partition coefficients of some antioxidants in butteroil-water model systems, J. Dairy Sci., 53: 529.

    Article  CAS  Google Scholar 

  • Cort, W. M., 1974, Antioxidant activity of tocopherols, ascorbyl palmitate and ascorbic acid and their mode of action, JAOCS, 51: 321.

    Article  CAS  Google Scholar 

  • Cort, W. M., Mergens, W., and Greene, A., 1978, Stability of a-and y-tocopherol: Fe3+ and Cut+ interactions, J. Food Sci., 43: 797.

    Article  CAS  Google Scholar 

  • Cort, W. M., Scott, J. W., Araujo, M., Mergens, W. J., Cannalonga, M. A., Osadca, M., Harley, H., Parrish, D. R., and Pool, W. R., 1975, Antioxidant activity and stability of 6-hydroxy-,5,7,8tetramethyl chroman-2-carboxylic acid, JAOCS, 52: 174.

    Article  CAS  Google Scholar 

  • Cross, J. W., Briggs, W. R., Dohrmann, U. C., and Ray, P. M., 1978, Auxin receptors of maize coleoptile membranes do not have ATPase activity, Pl. Physiol., 61: 581.

    Article  CAS  Google Scholar 

  • De Boland, A. R., Garner, G. B., and O’Dell, B. L., 1975, Identification and properties of “phytate” in cereal grains and oilseed products, J. Agr. Food Chem., 23: 1186.

    Article  Google Scholar 

  • El-Gharbawi, M. L. and Dugan, L. R., Jr., 1965, Stability of nitrogenous compounds and lipids during storage of freeze-dried raw beef, J. Food Sci., 30: 817.

    Article  CAS  Google Scholar 

  • Emanuel, N. M. and Lyaskovskaya, Y. N., 1965, “The Inhibition of Fat Oxidation Processes,” Pergamon Press, New York.

    Google Scholar 

  • Erkilla, I., Fung, T., Kandiah, M., Wilkins, J., Moran, J. J., and Blake, J. A., 1978, Study of the accelerated oxidation of low and high erucic rapeseed oil, JAOCS, 55: 303.

    Article  CAS  Google Scholar 

  • Farag, R. S. and Osman, S. A., 1978a, Cottonseed oil oxidation catalyzed by amino acids and albumin in aqueous and nonaqueous media, JAOCS, 55: 613.

    Article  CAS  Google Scholar 

  • Farag, R. S., Osman, S. A., Hallabo, S. A. S., and Naar, A. A., 1978b, Linoleic acid oxidation catalyzed by various amino acids and cupric ions in aqueous media, JAOCS, 55: 703.

    Article  CAS  Google Scholar 

  • Farag, R. S., Osman, S. A., Hallabo, S. A. S., and Naar, A. A., 1978c, Linoleic acid oxidation catalyzed by various amino acids and cupric ions in freeze-dried model systems, JAOCS, 55: 708.

    Article  CAS  Google Scholar 

  • Fiddler, W., Pensabene, J. W., Piotrowski, E. G., Doerr, R. C., and Wasserman, A. E., 1973, Use of sodium ascorbate or erythorbate to inhibit formation of N-nitroso dimethylamine in frankfurters, J. Food Sci., 38: 1084.

    Article  Google Scholar 

  • Fieser, L. F., 1930, Oxidation potentials of amines and phenols, JACS, 52: 5204.

    Article  CAS  Google Scholar 

  • Food Chemical News, 1978, A. M. I. asks FSQS to withdraw nitrite/sorbate bacon proposal, Food Chem. News, 20: 54 (November 20).

    Google Scholar 

  • Freeman, L. P., Padley, F. B., and Sheppard, W. L., 1973, Use of silicones in frying oils, JAOCS, 50: 101.

    Article  CAS  Google Scholar 

  • Friedlander, A. and Sklarz, B., 1971, Catecholic flavonoids from soybean flakes, Experientia, 27: 762.

    Article  Google Scholar 

  • Fujimoto, K., Kanno, Y., Kaneda, T., 1978, Antioxidant activity and pungency of capsaicin homologues, Abstract 10–09, Fifth Int. Congr. Food Sci. Technol., Kyoto, Japan, 17–22 Sep. 1978.

    Google Scholar 

  • Furia, T. E. and Bellanca, N., 1976, Development of new nonabsorbable polymeric antioxidants for use in foods, JAOCS, 53: 132.

    Article  CAS  Google Scholar 

  • Furia, T. E. and Bellanca, N., 1977, The properties and performance of Poly AOTM-79; a nonabsorbable polymeric antioxidant intended for use in foods, JAOCS, 54: 239.

    Article  CAS  Google Scholar 

  • Galliard, T., 1968, Identification and quantitative determination of the lipids in potato tubers, Photochem., 7: 1907.

    Article  CAS  Google Scholar 

  • Gehman, H. and Osman, E. M., 1954, Chemistry of the sugar sulphite reaction and its relation to food problems, Adv. Food Res., 5: 53.

    Article  CAS  Google Scholar 

  • Geyer, R. P., Saslaw, J., and Hare, F. J., 1955, Studies on the oxygen uptake of fat emulsions used in intravenous alimentation. JACS, 32: 528.

    Article  CAS  Google Scholar 

  • Goldblith, S. A., Karel, M., and Lusk, G., 1963, The role of food science and technology in the freeze-dehydration of foods. Food Technol., 17: 139.

    Google Scholar 

  • Graham, W. D. and Grice, H. C., 1955, Chronic toxicity of bread additives to rats, II, J. Pharm. Pharmacol., 7: 126.

    Article  CAS  Google Scholar 

  • Grams, G. W. and Eskins, K., 1972, Dye-sensitized photooxidation of tocopherols. Correlation between singlet oxygen reactivity and vitamin E activity, Biochem., 11: 606.

    CAS  Google Scholar 

  • Grams, G. W., Eskins, K., and Inglett, G. E., 1972, Dye-sensitized photooxidation of a-tocopherol, JACS, 94: 866.

    Article  CAS  Google Scholar 

  • Greene, B. E., 1969, Lipid oxidation and pigment changes in raw beef, J. Food Sci., 34: 110.

    Article  CAS  Google Scholar 

  • Greene, B. E., 1971, Retardation of oxidative color changes in raw ground beef, J. Food Sci., 36: 940.

    Article  CAS  Google Scholar 

  • Gregariadis, G., 1978, Liposomes in therapeutic and preventive medicine: The development of the drug-carrier concept, in: “Liposomes and Their Uses in Biology and Medicine,” D. Papahadjopoulis, ed., Annals of New York Academy of Sci., 308: 343, New York Acad. Sci., New York, NY.

    Google Scholar 

  • Griffith, W. C., 1954, Title unavailable, J. Soc. Cosmetic Chem., 5: 249.

    Google Scholar 

  • Gyorgy, P., Murata, K. and Ikehata, H., 1964, Antioxidants isolated from fermented soybeans (tempeh), Nature, 203: 870.

    Article  CAS  Google Scholar 

  • Gyorgy, P., Murata, K., and Sugimoto, Y., 1974, Studies on antioxidant activity of tempeh oil, JAOCS, 51: 377.

    Article  CAS  Google Scholar 

  • Haase, G. and Dunkley, W. L., 1969a, Ascorbic acid and copper in linoleate oxidation. 2. Ascorbic acid and copper as oxidation catalysts, J. Lipid Res., 10: 561.

    CAS  Google Scholar 

  • Haase, G. and Dunkley, W. L., 1969b, Ascorbic acid and copper in linoleate oxidation. 3. Catalysts in combination, J. Lipid Res., 10: 568.

    CAS  Google Scholar 

  • Hall, J. L. and Mackintosh, D. L., 1964, Chlorophyll catalysis of fat peroxidation, J. Food Sci., 29: 420.

    Article  CAS  Google Scholar 

  • Hall, R. L., 1975, GRAS: Concept and applications, Food Technol., 29: 48.

    Google Scholar 

  • Hamilton, J. W. and Tappel, A. L., 1963, Evaluation of antioxidants by a rapid polarographic method, JAOCS, 40: 52.

    Article  CAS  Google Scholar 

  • Hamm, D. L., Hammond, E. G., and Hotchkiss, D. K., 1967, Effect of temperature on rate of autoxidation of milk fat, J. Dairy Sci., 51: 483.

    Article  Google Scholar 

  • Hannan, R. S. and Shepherd, H. J., 1952, An after-effect in butterfat irradiated with high energy electrons, Nature, 170: 1021.

    Article  CAS  Google Scholar 

  • Hayes, R. E., Bookwalter, G. N., and Bagley, E. B., 1977, Antioxidant activity of soybean flour and derivatives - a review, J. Food Sci., 42: 1527.

    Article  CAS  Google Scholar 

  • Hodge, J. E., 1953, Browning reactions in model systems, J. Agr. Food Chem., 1: 928.

    Article  CAS  Google Scholar 

  • Hodge, J. E., 1967, Origin of flavor in foods. Non-enzymatic browning reactions, in: “Symposium on Foods: Chemistry and Physiology of Flavors. Non-enzymatic Browning Reactions,” H. W. Schultz

    Google Scholar 

  • E. A. Day, and L. M. Libbey, eds., Avi Publ. Co., Westport, CT, p. 465.

    Google Scholar 

  • Honn, F. J., Bezman, I. I., and Daubert, B. F., 1951, Autoxidation of drying oils adsorbed on porous solids, JAOCS, 28: 129.

    Article  CAS  Google Scholar 

  • Horn, L. R., Barker, M. O., Reed, G., and Brin, M., 1974, Studies on peroxidative hemolysis and erythrocyte fatty acids in the rabbit: Effect of dietary polyunsaturated fatty acids and vitamin E., J. Nutr., 104: 192.

    CAS  Google Scholar 

  • Ikeda, N. and Fukuzumi, K., 1977, Synergistic antioxidant effect of nucleic acids and tocopherols, JAOCS, 54: 360.

    Article  CAS  Google Scholar 

  • Ikeda, N. and Fukuzumi, K., 1976, Ion exchange resins and ethylenimine polymer as antioxidants. 1. Activity and mechanism, JAOCS, 53: 618.

    Article  CAS  Google Scholar 

  • Johnson, F. C., 1971, A critical review of the safety of phenolic antioxidants in foods, in: “Critical Reviews in Food Technology,” Vol. 2, T. Furia, ed., CRC Press, Cleveland, OH, p. 267.

    Google Scholar 

  • Jul, M., 1968, Title unavailable, in: “Low Temperature Biology of Foodstuffs,” Recent Advances in Food Science, Vol. 4, J. Hawthorn and E. J. Rolfe, eds., Pergamon Press, New York.

    Google Scholar 

  • Kamiya, S., 1960, Title unavailable, Nippon Nogeikagaku Kaishi, 34: 8.

    Article  CAS  Google Scholar 

  • Kamm, J. J., Dashman, T., Conney, A. H., and Burns, J. J., 1975, Effect of ascorbic acid on amine-nitrite toxicity, Annals of New York Academy Sci., 258:169, Second Conference on Vitamin C, September, New York Academy of Sciences, New York.

    Google Scholar 

  • Kanner, J., 1979, S-nitrosocysteine (RSNO), an effective antioxidant in cured meat, JAOCS, 56: 74.

    Article  CAS  Google Scholar 

  • Kanner, J., Mendel, H., and Budowski, P., 1977, Prooxidant and antioxidant effects of ascorbic acid and metal salts in a IS-carotene linoleate model system, J. Food Sci., 42: 60.

    Article  CAS  Google Scholar 

  • Karel, M., Schaich, K., and Roy, R. B., 1975, Interaction of peroxidizing methyl linoleate with some proteins and amino acids, J. Agr. Food Chem., 23: 159.

    Article  CAS  Google Scholar 

  • Karel, M., Tannenbaum, S. R., Wallace, D. H., and Maloney, H., 1966, Autoxidation of methyl linoleate in freeze-dried model systems. III. Effects of added amino acids, J. Food Sci., 31: 892.

    Article  CAS  Google Scholar 

  • Kendrick, J. and Watts, B. M., 1969, Acceleration and inhibition of lipid oxidation by heme compounds, Lipids, 4: 454.

    Article  CAS  Google Scholar 

  • Khan, T. M. M. and Martell, A. E., 1967, Metal ion and metal chelate catalyzed oxidation of ascorbic acid by molecular oxygen, JACS, 89: 4176.

    Article  CAS  Google Scholar 

  • Kirleis, A. W. and Stine, C. M., 1978, Retention of synthetic phenolic antioxidants in model freeze-dried systems, J. Food Sci., 43: 1457.

    Article  CAS  Google Scholar 

  • Koch, S. D., Hyatt, A. A., and Lopiekes, D. V., 1971, Basis of stability of amine salts of linoleic acid. 1. Generality of the oxidation protection and effect of physical state, J. Food Sci., 36: 477.

    Article  CAS  Google Scholar 

  • Kopelman, I. J., Mizrahi, S., and Schwab, R., 1975, Equilibrium vapor pressure of butylated hydroxyanisole and butylated hydroxytoluene in high temperature oil solution, JAOCS, 52: 103.

    Article  CAS  Google Scholar 

  • Labuza, T. P., 1971, Kinetics of lipid oxidation in foods, CRC Critical Review in Food Technol., 2: 355.

    Article  Google Scholar 

  • Labuza, T. P., Maloney, J. F., and Karel, M., 1966, Autoxidation of methyl linoleate in freeze-dried model systems. II. Effect of water on cobalt-catalyzed oxidation, J. Food Sci., 31: 885.

    Article  CAS  Google Scholar 

  • Labuza, T. P., Silver, M., Cohn, M., Heidelbaugh, N. D., and Karel, M., 1971, Metal-catalyzed oxidation in the presence of water in foods, JAOCS, 48: 527.

    Article  CAS  Google Scholar 

  • Lamola, A. A., Yamane, T., and Truzzolo, A. M., 1973, Cholesterol hydroperoxide formation in red cell membranes and photohemolysis in erythropoietic protoprophyria, Sci., 179: 1131.

    Article  CAS  Google Scholar 

  • Latimer, W. M., 1938, “The Oxidation States of the Elements and Their Potentials in Aqueous Solutions,” Prentice-Hall, Inc., New York.

    Google Scholar 

  • Lee, A. G., Birdsall, N. J. M., Metcalfe, J. C., Toon, P. A., and Warren, G. B., 1974, Clusters in lipid bilayers and interpretations of thermal effects in biological membranes, Biochem., 13: 3699.

    Article  CAS  Google Scholar 

  • Lee, S., 1973, “Studies on a Potato-Chip-Like Flavored Oil Generated by Deep Fat Frying of Methionine,” Rutgers Univ., University Microfilm, Ann Arbor, MI.

    Google Scholar 

  • Levandoski, N. G., Baker, E. M., and Canham, J. E., 1964, A monodehydro form of ascorbic acid in the autoxidation of ascorbic acid to dehydroascorbic acid, Biochem., 3: 1465.

    Article  CAS  Google Scholar 

  • Lin, J. S., Smith, V., and Olcott, H. S., 1974, Loss of free-radical signal during induction period of unsaturated lipids containing nitroxide antioxidants, J. Agr. Food Chem., 22: 682.

    Article  CAS  Google Scholar 

  • Lindsay, R. C., Lund, D. B., Branen, A. L., Chang, H. C., Dunnick, S. E., and Steinke, J. A., 1975, Investigation of methods for introducing antioxidants into foods, Technical Report TR 75100-FSL for U.S. Army Natick RD Command, Natick, MA 01760 (AD A022557), U.S. Dept. of Commerce, Natl. Tech. Infor. Service, Springfield, VA 22161, March 1975.

    Google Scholar 

  • List, G. R., Evans, C. D., and Moser, H. A., 1972, Flavor and oxidative stability of northern-grown sunflower seed oil, JAOCS, 49: 287.

    Article  CAS  Google Scholar 

  • Luckadoo, B. M. and Sherwin, E. R., 1972, Tertiary butylhydroquinone as antioxidant for crude sunflower seed oil, JAOCS, 49: 95.

    Article  CAS  Google Scholar 

  • Lundberg, W. O., 1961 and 1962, “Autoxidation and Antioxidants,” Vols. I and I I, W. O. Lundberg, ed., Interscience Publishers, John Wiley and Sons, New York.

    Google Scholar 

  • Lunde, G., Landmark, L. H., and Gether, J., 1976, Sequestering and exchange of metal ions in edible oils containing phospholipids JAOCS, 53: 207.

    Article  CAS  Google Scholar 

  • Lyon, C. K., 1972, Sesame: Current knowledge of composition and use, JAOCS, 49: 245.

    Article  CAS  Google Scholar 

  • McCay, P. B., Gibson, D. D., Fong, K. L., and Hornbrock, K. R., 1976, Effect of glutathione peroxidase activity on lipid peroxidation in biological membranes, Biochim. Biophys. Acta, 431: 459.

    Article  CAS  Google Scholar 

  • McWeeney, D. J., 1968, Reactions in food systems; negative temperature coefficients, J. Food Technol., 3: 15.

    Article  Google Scholar 

  • Maleki, M., 1973, The effect of non-enzymatic browning in the presence of glucose and glycine on the development of rancidity in corn oil, Fette Seifen Anstrichmittel, 75: 103.

    Article  CAS  Google Scholar 

  • Maloney, J. F., Labuza, T. P., Wallace, D. H., and Karel, M., 1966, Autoxidation of methyl linoleate in freeze-dried model systems. I. Effect of water on the autocatalyzed oxidation, J. Food Sci., 31: 878.

    Article  CAS  Google Scholar 

  • Manley, O. H. and Fagerson, I. S., 1970, Major volatile neutral and acid components of hydrolyzed soy protein, J. Food Sci., 35: 286.

    Google Scholar 

  • Marco, G. J., 1968, A rapid method for evaluation of antioxidants, JAOCS, 45: 594.

    Article  CAS  Google Scholar 

  • Marcuse, R., 1962, The effect of some amino acids on the oxidation of linoleic acid and its methyl ester, JAOCS, 39: 97.

    Article  CAS  Google Scholar 

  • Mead, J. F. and Wu, G.-S., 1976, The use of fatty acid monolayers as models for biomembranes autoxidation studies, in: “Lipids,” R. Paoletti, G. Porcellati, and G. Jacini, eds., Raven Press, New York, p. 197.

    Google Scholar 

  • Mergens, W. J., Keating, J. F., Osadca, M., Araujo, M., DeRitter, E., and Newmark, H. L., 1978, Stability of tocopherol in bacon, Food Technol., 32: 40 (November).

    Google Scholar 

  • Mirvish, S. S., 1975, Blocking the formation of N-nitroso compounds with ascorbic acid in vitro and in vivo, Second Conference on Vitamin C, Annals New York Acad. Sci., 258: 175.

    Article  CAS  Google Scholar 

  • Mitchell, J. H., Jr. and Henick, A. S., 1962, Rancidity in food products, in: “Autoxidation and Antioxidants,” Vol. II, W. O. Lundberg, ed., Interscience Publications, New York, p. 569.

    Google Scholar 

  • Moerck, K. E. and Ball, H. R., Jr., 1974, Lipid autoxidation in mechanically deboned chicken meat, J. Food Sci., 39: 876.

    Article  Google Scholar 

  • Morrison, W. H., III, Robertson, J. A., and Burdick, D., 1973, Effect of deep-fat frying on sunflower oils, JAOCS, 50: 440.

    Article  CAS  Google Scholar 

  • Nickerson, J. T. R., 1963, Preservatives and antioxidants, in: “Food Processing Operations,” Vol. II, J. Heid and M. Joslyn, eds., Avi Publishing Co., Westport, CT, p. 218.

    Google Scholar 

  • O’Brien, P. J. and Rahimtula, A., 1975, Involvement of cytochrome P-450 in the intracellular formation of lipid peroxides, J. Agr. Food Chem., 23: 154.

    Article  Google Scholar 

  • Olcott, H. S. and Mattill, H. A., 1936, Antioxidants and the autoxidation of fats. VII. Preliminary classification of inhibitors, JACS, 58: 2204.

    Google Scholar 

  • Olcott, H. S. and J. Van der Veen, 1963, Role of individual phospholipids as antioxidants, J. Food Sci., 28: 313.

    Article  CAS  Google Scholar 

  • Olson, D. G. and Rust, R. E., 1973, Oxidative rancidity in dry-cured hams: Effect of low pro-oxidant and antioxidant salt formulation, J. Food Sci., 38: 251.

    Article  CAS  Google Scholar 

  • Parkhurst, R. M., Skinner, W. A., and Strum, P. A., 1969, The effect of various concentrations of tocopherols and tocopherol mixtures on the oxidative stability of a sample of lard, JAOCS, 45: 641.

    Google Scholar 

  • Pearson, A. M., Love, J. D., and Shorland, F. B., 1977, “Warmed-over” flavor in meat, poultry, and fish, Adv. Food Res., 23:1.

    Google Scholar 

  • Porter, W. L., 1962, Molecular structure and auxin activity: the fourth specificity requirement for auxin action, Ph.D. Thesis, Harvard University, Cambridge, MA.

    Google Scholar 

  • Porter, W. L., Wetherby, A. M., and Kapsalis, J. G., 1979, unpublished data.

    Google Scholar 

  • Porter, W. L., Colgan, R., Paradis, A., and Porfert, G., 1976, Synthesis and testing of antioxidants designed for membrane protection, Abstract 67th Annual Spring Meeting, AOCS, 21–24 April, New Orleans, LA, JAOCS.

    Google Scholar 

  • Porter, W. L., Henick, A. S., Murphy, F., Colgan, R., and Porfert, G., 1978, Autoxidation and effects of pro-and antioxidants in lyophilized red blood cell membranes, Lipids, 13: 137.

    Article  CAS  Google Scholar 

  • Porter, W. L., Henick, A. S., Jeffers, J. I., and Levasseur, L. A., 1971b, A method of ultraviolet spectrophotometry of lipid mono-layers on silica gel, Lipids, 6: 9.

    Article  CAS  Google Scholar 

  • Porter, W. L., Henick, A. S., and Levasseur, L. A., 1973, Addition compounds of oxidizing tocopherol and soybean lecithin, Lipids, 8: 31.

    Article  CAS  Google Scholar 

  • Porter, W. L., Levasseur, L. A., and Henick, A. S., 1972, Effects of surface concentration, metals and acid synergists on autoxidation of linoleic acid monolayers on silica, Lipids, 7: 699.

    Article  CAS  Google Scholar 

  • Porter, W. L., Levasseur, L. A., and Henick, A. S., 1977, Evaluation of some natural and synthetic phenolic antioxidants in linoleic acid monolayers on silica, J. Food Sci., 42: 1533.

    Article  CAS  Google Scholar 

  • Porter, W. L., Levasseur, L. A., and Henick, A. S., 1971a, An addition compound of oxidized tocopherol and linoleic acid, Lipids, 6: 1.

    Article  Google Scholar 

  • Porter, W. L., Levasseur, L. A., Jeffers, J. I., and Henick, A. S., 1971c, Ultraviolet spectrophotometry of autoxidized lipid monolayers while on silica gel, Lipids 6: 16.

    Article  CAS  Google Scholar 

  • Pratt, D. E., 1972, Water soluble antioxidant activity in soybeans, J. Food Sci., 37: 322.

    Article  Google Scholar 

  • Rackis, J., 1974, Biological and physiological factors in soybeans, JAOCS, 51: 161A.

    Google Scholar 

  • Ragnarsson, J. 0., 1977, “Accelerated Temperature Shelf Life Testing of Antioxidants in Dehydrated and Intermediate Moisture Systems,” Ph.D. Thesis, Univ. of Minnesota, Minneapolis, MN, 1976, University Microfilms International, Ann Arbor, MI.

    Google Scholar 

  • Ragnarsson, J. O. and Labuza, T. P., 1977, Accelerated shelf-life testing for oxidative rancidity in foods - a review, Food Chem., 2: 291.

    Article  CAS  Google Scholar 

  • Ragnarsson, J. O., Leick, D., and Labuza, T. P., 1977, Accelerated temperature study of antioxidants, J. Food Sci., 42: 1536.

    Google Scholar 

  • Reeve, R. M., 1942, Facts of vegetable dehydration revealed by microscope, Food Industries, 14:51 and 14: 107.

    Google Scholar 

  • Reeve, R. M., 1943a, Microscopy of the oils and carotene bodies in dehydrated carrots, Food Res., 8: 137.

    Article  CAS  Google Scholar 

  • Reeve, R. M., 1943b, Change in tissue composition in dehydration of certain fleshy root vegetables, Food Res., 8: 146.

    Article  Google Scholar 

  • Riemenschneider, R. W., 1955, Oxidative rancidity and antioxidants, in: “Handbook of Food and Agriculture,” F. C. Blanck, ed., Reinhold Press, NY.

    Google Scholar 

  • Rock, S. P. and Roth, H., 1964, Factors affecting the rate of deterioration in the frying quality of fats. II. Type of heater and method of heating, JAOCS, 41: 531.

    Article  Google Scholar 

  • Rock, S. P., Fischer, L., and Roth, H., 1967, Methyl silicone in frying fats - Antioxidant or pro-oxidant, JAOCS, 44: 102A.

    Google Scholar 

  • Roth, H. and Rock, S. P., 1972, The chemistry and technology of frying fat. I. Chemistry, Bakers Digest, 46: 38 (August 1978).

    Google Scholar 

  • Roth, H. and Rock, S. P., 1972, The chemistry and technology of frying fat. II. Technology, Bakers Digest, 46: 38 (October 1978).

    Google Scholar 

  • Sato, K. and Hegarty, G. R., 1971, Warmed-over flavor in cooked meats, J. Food Sci., 36: 1098.

    Article  CAS  Google Scholar 

  • Sato, K., Hegarty, G. R., and Herring, H. K., 1973, The inhibition of warmed-over flavors in cooked meats, J. Food Sci., 38: 398.

    Article  Google Scholar 

  • Schultz, H. W., Day, E. A., and Sinnhuber, R. 0., 1962, “Lipids and Their Oxidation,” H. W. Schultz, E. A. Day, and R. O. Sinnhuber, eds., Symposium on Foods, Oregon State Univ., 1961, Avi Publishing Co., Inc. Scott, G., 1965, “Atmospheric Oxidation and Antioxidants,” Elsevier Publishing Co., New York.

    Google Scholar 

  • Scott, J. W., Cort, W. M., Harley, H., Parrish, D. R. and Saucy, G., 1974, 6-hydroxychroman-2-carboxylic acids: novel antioxidants, JAOCS, 51: 200.

    Google Scholar 

  • Shamberger, R. J., Baughman, F. F., Kalchert, S. L., Willis, C. E., and Hoffman, G. C., 1973, Carcinogen-induced chromosomal breakage decreased by antioxidants, Proc. Natl. Acad. Sci., 70: 1461.

    Article  CAS  Google Scholar 

  • Shelton, J. R. and Vincent, D., 1963, Retarded autoxidation and the chain-stopping action of inhibitors, JACS, 85: 2433.

    Article  CAS  Google Scholar 

  • Sherwin, E. R., 1972, Antioxidants for food fats and oils, JAOCS, 49: 4681.

    Google Scholar 

  • Sherwin, E. R., 1976, Antioxidants for vegetable oils, JAOCS, 53: 430.

    Article  CAS  Google Scholar 

  • Sherwin, E. R., 1978, Oxidation and antioxidants in fat and oil processing, JAOCS, 55: 809.

    Article  CAS  Google Scholar 

  • Sims, R. J. and Fioriti, J. A., 1977, Methional as an antioxidant for vegetable oils, JAOCS, 54: 4.

    Article  CAS  Google Scholar 

  • Sims, R. J., Fioriti, J. A., and Kanuk, M. J., 1972, Sterol additives as polymerization inhibitors for frying oils, JAOCS, 49: 298.

    Article  CAS  Google Scholar 

  • Siu, G. M. and Draper, H. H., 1978, A survey of the malonaldehyde content of retail meats and fish, J. Food Sci., 43: 1147.

    Article  CAS  Google Scholar 

  • Skinner, W. A. and Parkhurst, R. M., 1970, Antioxidant properties of a-tocopherol derivatives and relationship of antioxidant activity to biological activity, Lipids, 5: 184.

    Article  CAS  Google Scholar 

  • Slawson, V. and Mead, J. F., 1972, Stability of unsaturated methyl esters of fatty acids on surfaces, J. Lipid Res., 13: 143.

    CAS  Google Scholar 

  • Slawson, V., Adamson, A. W., and Mead, J. F., 1973, Autoxidation of polyunsatured fatty esters on silica, Lipids, 8: 129.

    Article  CAS  Google Scholar 

  • Soimajarvi, J. and Linko, R. R., 1973, Lipids in carrot roots. I. The purification of crude lipids and the composition of neutral lipids, Acta Chem. Scand., 27: 1053.

    Article  CAS  Google Scholar 

  • Song, P. S. and Chichester, C. O., 1967, Kinetic behavior and mechanism of inhibition in the Maillard reaction, J. Food Sci., 32: 98.

    Article  CAS  Google Scholar 

  • Sosulski, F. and Fleming, S. E., 1977, Chemical, functional, and nutritional properties of sunflower protein products, JAOCS, 54: 100A.

    Google Scholar 

  • Stuckey, B., 1968, Antioxidants as food stabilizers, in: “Handbook of Food Additives,” T. Furia, ed., Chem. Rubber Co., Cleveland, OH, p. 209.

    Google Scholar 

  • Symposium, 1979, Basic symposium on “Food Lipids,” Institute of Food Technologists, St. Louis, MO, June, 1979.

    Google Scholar 

  • Takasago, M., Horikawa, K., and Masuyama, S., 1976, Studies on derivatives of aromatic hydroxycarboxylic acids as antioxidants. I. The preparation of galloyl glycerol derivative and its antioxidant activity, Yukagaku, 25: 16.

    CAS  Google Scholar 

  • Tappel, A. L., Brown, W. D., Zalkin, H., and Maier, V. P., 1961, Unsaturated lipid peroxidation catalyzed by hematin compounds and its inhibition by Vitamin E, JAOCS, 38: 5.

    Article  CAS  Google Scholar 

  • Thompson, S. G., 1978, Effect of soy protein flakes and added water on microbial growth and rancidity in fresh ground beef, J. Food Sci., 43: 289.

    Article  Google Scholar 

  • Thompson, J. W. and Sherwin, E. R., 1966, Investigation of antioxidants for polyunsaturated edible oils, JAOCS, 43: 683.

    Article  CAS  Google Scholar 

  • Tjio, K. H., Labuza, T. P., and Karel, M., 1969, Effects of humidification and activity of catalysts and antioxidants in model systems, JAOCS, 46: 597.

    Article  Google Scholar 

  • Tompkin, R. B., Christiansen, L. N., and Shaparis, A. B., 1978, Antibotulinal role of isoascorbate in cured meat, J. Food Sci., 43: 1368.

    Article  CAS  Google Scholar 

  • Uri, N., 1958, The mechanism of the oxidation of linoleic acid with particular reference to metal catalysis. Fourth Internatl. Conference on the Biochemical Problems of Lipids, Butterworths Sci. Publications, London.

    Google Scholar 

  • Uri, N., 1961, Mechanism of antioxidation, in: “Autoxidation and Antioxidants,” W. O. Lundberg, ed., Vol. I., Interscience Publications, New York, p. 133.

    Google Scholar 

  • Uri, N., 1970, Some aspects of thermal and photochemical oxidation, Israel J. of Chem., 8: 125.

    CAS  Google Scholar 

  • Van Esch, G. J., 1955, Studies on the toxicity of propyl, octyl and dodecyl gallate, Voeding, 16: 683.

    Google Scholar 

  • Watts, B. M., 1961, The role of lipid oxidation in lean tissues in flavor deterioration of meat and fish, in: “Proceedings of Flavor Chemistry Symposium,” Campbell Soup Co., Camden, NJ, p. 83.

    Google Scholar 

  • Watts, B. M., 1962, Meat products, in: “Lipids and Their Oxidation,” H. W. Schultz, E. A. Day, and R. O. Sinnhuber, eds., Chapter 11, Avi Publishing Co., Westport, CT, p. 202.

    Google Scholar 

  • Weddle, C. C., Hornbrook, K. R., and McCay, P. B., 1976, Lipid peroxidation and alteration of membrane lipids in isolated hepatocytes exposed to carbon tetrachloride, J. Biol. Chem., 251: 4973.

    CAS  Google Scholar 

  • Wilson, B. R., Pearson, A. M., and Shorland, F. B., 1976, Effect of total lipids and phospholipids on warmed-over flavor in red and white muscle from several species as measured by thiobarbituric acid analysis, J. Agr. Food Chem., 24: 7.

    Article  CAS  Google Scholar 

  • Witting, L. A., 1975, Vitamin E as a food additive, JAOCS, 52: 64.

    CAS  Google Scholar 

  • Wu, G.-S. and Mead, J. F., 1977, Autoxidation of fatty acid monolayers adsorbed on silica gel: 1. Nature of adsorption sites, Lipids, 12: 965.

    Article  CAS  Google Scholar 

  • Wu, G.-S., Stein, R. A., and Mead, J. F., 1977, Autoxidation of fatty acid monolayers adsorbed on silica gel. II. Rates and products, Lipids, 12: 971.

    Article  CAS  Google Scholar 

  • Yong, S. H. and Karel, M., 1978, Reaction of histidine with methyl linoleate: Characterization of the histidine degradation products, JAOCS, 55: 352.

    Article  CAS  Google Scholar 

  • Yuki, E. and Ishikawa, Y., 1976, Tocopherol content of nine vegetable frying oils and their changes under simulated deep-fat frying conditions, JAOCS, 53: 673.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1980 Springer Science+Business Media New York

About this chapter

Cite this chapter

Porter, W.L. (1980). Recent Trends in Food Applications of Antioxidants. In: Simic, M.G., Karel, M. (eds) Autoxidation in Food and Biological Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9351-2_19

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-9351-2_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9353-6

  • Online ISBN: 978-1-4757-9351-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics