Skip to main content

Rapid Instrumental Analysis of Lipid Oxidation Products

  • Chapter

Abstract

The oxidation of unsaturated fatty acids initially involves the formation of their hydroperoxides. Once these products are formed, they can be decomposed or further oxidized to secondary products such as alcohols, acids, ketones, and aldehydes that are capable of reacting with other constituents of food such as amino acids, proteins, enzymes, and vitamins. These reactions can have an adverse affect on the nutritive value and quality of their respective foods. Additionally, as witnessed in other chapters of this book, the free radicals generated by the oxidative mechanisms have been implicated in reactions that can lead to pathological changes in animal and human tissue.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. R. G. Buttery and R. Teranishi, Gas-liquid chromatography of aroma of vegetables and fruit, Anal. Chem. 33:1439(1961).

    Google Scholar 

  2. R. Teranishi, R. G. Buttery, and R. E. Lundin, Gas chromatography. Direct vapor analyses of food products with dual flame ionization detectors, Ibid. 34: 1033 (1962).

    Google Scholar 

  3. W. Jennings, Foreword, in: “Analysis of Foods and Beverages, Headspace Techniques,” G. Charalambous, ed., Academic Press, Inc., New York (1978).

    Google Scholar 

  4. H. P. Dupuy, S. P. Fore, and L. A. Goldblatt, Elution and analysis of volatiles in vegetable oils by gas chromatography, J. Am. Oil Chem. Soc. 48: 876 (1971).

    Google Scholar 

  5. D. F. Brown, F. G. Dollear, and H. P. Dupuy, Direct gas chromatographic analysis of volatiles from raw and roasted peanuts, Ibid. 49: 81 (1972).

    Google Scholar 

  6. S. P. Fore and H. P. Dupuy, A rapid procedure for the determination of residual hexane in oilseed meals and flours, Ibid. 49: 129 (1972).

    Google Scholar 

  7. H. P. Dupuy, S. P. Fore, and L. A. Goldblatt, Direct gas chromatographic examination of volatiles in salad oils and shortenings, Ibid. 50: 340 (1973).

    Google Scholar 

  8. H. P. Dupuy, E. T. Rayner, and J. I. Wadsworth, Correlations of flavor score with volatiles of vegetable oils, Ibid. 53: 628 (1976).

    Google Scholar 

  9. S. P. Fore, H. P. Dupuy, and J. I. Wadsworth, Correlation of volatile components of peanut products with flavor score I. Shelf life studies on peanut butter, Peanut Sci. 3: 86 (1976).

    Article  CAS  Google Scholar 

  10. H. W. Jackson and D. J. Giacherio, Volatiles and oil quality, J. Am. Oil Chem. Soc. 54: 458 (1977).

    Google Scholar 

  11. J. L. Williams and T. H. Applewhite, Correlation of the flavor scores of vegetable oils with volatile profile data, Ibid. 54: 461 (1977).

    Google Scholar 

  12. M. L. Brown, J. I. Wadsworth, H. P. Dupuy, and R. W. Mozingo, Correlation of volatile components of raw peanuts with flavor score, Peanut Sci. 4: 54 (1977).

    Google Scholar 

  13. H. P. Dupuy, E. T. Rayner, J. I. Wadsworth, and M. G. Legendre, Analysis of vegetable oils for flavor quality by direct gas chromatography, J. Am. Oil Chem. Soc. 54: 445 (1977).

    Google Scholar 

  14. E. T. Rayner, J. I. Wadsworth, M. G. Legendre, and H. P. Dupuy, Analysis of flavor quality and residual solvent of soy protein products, Ibid. 55: 454 (1978).

    Google Scholar 

  15. H. P. Dupuy, M. G. Legendre, E. T. Raynei, R. M. Grodner, and A. F. Novak, Instrumental analysis of volatiles in seafood, in: “Proceedings of the Third Annual Tropical and Subtropical Fisheries Technological Conference of the Americas,” April(1978). p. 354.

    Google Scholar 

  16. M. G. Legendre, H. P. Dupuy, R. L. Ory, and W. O. Mcllrath, Instrumental analysis of volatiles from rice and corn products, J. Agric. Food Chem. 26:1035(1978).

    Google Scholar 

  17. H. P. Dupuy, M. L. Brown, M. G. Legendre, J. I. Wadsworth, and E. T. Rayner, Instrumental analysis of volatiles in food products, in: “Lipids as a Source of Flavor,” M. K. Supran, ed., ACS Symposium Series, Washington (1978). p. 60.

    Chapter  Google Scholar 

  18. M. G. Legendre, G. S. Fisher, W. H. Schuller, H. P. Dupuy, and E. T. Rayner, Novel technique for the analysis of volatiles in aqueous and nonaqueous systems, J. Am. Oil Chem. Soc. 56: 552 (1979).

    Google Scholar 

  19. A. J. St. Angelo, M. G. Legendre, and H. P. Dupuy, Identification of lipoxygenase-linoleate decomposition products by direct gas chromatography, Lipids in press.

    Google Scholar 

  20. Flavor nomenclature and standards subcommittee, J. Am. Oil Chem. Soc. 56: 658A (1979).

    Google Scholar 

  21. H. E. Pattee, J. S. Singleton, and E. B. Johns, Pentane production by peanut lipoxygenase, Lipids 9: 302 (1974).

    Google Scholar 

  22. B. O. de Lumen, E. J. Stone, S. J. Kazeniac, and R. H. Forsythe, Formation of volatile flavor compounds in green beans from linoleic and linolenic acids, J. Food Sci. 43: 698 (1978).

    Google Scholar 

  23. W. Grosch and J. M. Schwartz, Linoleic and linolenic acid as precursors of the cucumber flavor, Lipids 6: 351 (1971).

    Google Scholar 

  24. W. I. Kimoto and A. M. Gaddis, Precursors of Alk-2,4-dienals in autoxidized lard, J. Am. Oil Chem. Soc. 46: 403 (1969).

    Google Scholar 

  25. D. Arens, G. Laskawy, and W. Grosch, lipoxygenase aus erbsen bildung flüchtiger aldehyde aus linolsaüre, Z. Lebensm. Unters. Forsch. 151: 162 (1973).

    Google Scholar 

  26. R. J. Horvat, W. G. Lane, H. Ng, and A. D. Shepard, Saturated hydrocarbons from autoxidizing methyl linoleate, Nature (London) 203: 523 (1964).

    Google Scholar 

  27. T. H. Smouse and S. S. Chang, A systematic characterization of the reversion flavor of soybean oil, J. Am. Oil Chem. Soc. 44: 509 (1967).

    Google Scholar 

  28. D. J. Sessa and J. J. Rackis, Lipid-derived flavors of legume proteins products, Ibid. 54: 468 (1977).

    Google Scholar 

  29. N. A. Eskin, F. Grossman, and A. Pinsky, Biochemistry of lipoxygenase in relation to food quality, CRC Crit. Rev. Food Sci. Nutr. 9:1(1977).

    Google Scholar 

  30. C. D. Evans, G. R. List, R. L. Hoffman, and H. A. Moser, Edible oil quality as measured by thermal release of pentane, J. Am. Oil Chem. Soc. 46: 501 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1980 Springer Science+Business Media New York

About this chapter

Cite this chapter

Angelo, A.J.S., Legendre, M.G., Dupuy, H.P. (1980). Rapid Instrumental Analysis of Lipid Oxidation Products. In: Simic, M.G., Karel, M. (eds) Autoxidation in Food and Biological Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9351-2_10

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-9351-2_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9353-6

  • Online ISBN: 978-1-4757-9351-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics