Skip to main content

Alternating Copolymerization of Olefins and Diolefins

  • Chapter
  • 125 Accesses

Part of the book series: Speciality Polymers ((SPEPO))

Abstract

Olefins and diolefins possess differing coordination abilities towards transition metal catalysts and accordingly their copolymerization has been considered to be difficult. Indeed, no reactions were reported until Natta et al.(1) found the existence of a small amount of an alternating copolymer of ethylene and butadiene in a fraction of the product obtained using a vanadium catalyst.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G. Natta, A. Zambelli, I. Pasquon, and F. Ciampelli, MakromoL Chem. 79, 161–169 (1964).

    Article  CAS  Google Scholar 

  2. A. Kawasaki, I. Maruyama, M. Taniguchi, R. Hirai, and J. Furukawa, J. Polym. Sci. B 7, 613–620 (1969).

    Article  CAS  Google Scholar 

  3. J. Furukawa, R. Hirai, and H. Amano, J. Polym. Sci. Polym. Chem. 10, 681–688 (1972).

    Article  CAS  Google Scholar 

  4. J. Furukawa, Angew. MakromoL Chem. 23, 189–204 (1972).

    Article  CAS  Google Scholar 

  5. M. Taniguchi, Dissertation, Kyoto Univ. (1976).

    Google Scholar 

  6. J. Furukawa, Acc. Chem. Res. 13, 1–6 (1980).

    Article  CAS  Google Scholar 

  7. Maruzen Petrochem. Co., Ltd., Ger. Offen 1, 963, 780 (1970).

    Google Scholar 

  8. Bayer A-G., Ger. Offen 2,706, 118 (1978).

    Google Scholar 

  9. I. G. Zhuchikhina, E. N. Kropacheva, L. A. Yatsenko, K. V. Nel’son, N. N. Novikova, and A. S. Khachaturov, Vysokomol Soed. A 20, 2259–2263 (1978).

    CAS  Google Scholar 

  10. B. I. Lein, M. I. Astrakhanov, E. N. Kropacheva, and A. S. Khachaturov, Vysokomol. Soed. A 21, 406–412 (1979).

    CAS  Google Scholar 

  11. L. A. Yatsenko, A. G. Boldyrev, I. G. Zhuchikhina, and E. N. Kropacheva, Kinet. KataL 20, 1353–1356 (1979).

    CAS  Google Scholar 

  12. N. A. Venediktova, E. N. Kropacheva, L. V. Smimova, L. I. Vyshinskaya, and S. Ya. Timoshenko, Vysokomol. Soed. A 22, 977–981 (1980).

    CAS  Google Scholar 

  13. J. Furukawa, S. Tsuruki, and J. Kiji, J. Polym. Sci. Polym. Chem. 11, 2999–3004 (1973).

    Article  CAS  Google Scholar 

  14. A. Priola, C. Corno, G. Ferraris, and S. Cesca, Makromol. Chem. 180, 2859–2874 (1979).

    Article  CAS  Google Scholar 

  15. J. Furukawa, E. Kobayashi, and T. Kawagoe, J. Polym. Sci. B 11, 573–581 (1973).

    CAS  Google Scholar 

  16. J. Furukawa, T. Kawagoe, and E. Kobayashi, J. Polym. Sci. Polym. Chem. 14, 1213–1219 (1976).

    Article  CAS  Google Scholar 

  17. A. Matsumura, T. Kuwajima, T. Uchiyama, N. Furuno, and J. Furukawa, Chemical Society of Japan, spring meeting (1981), preprint I I, 1110.

    Google Scholar 

  18. Maruzen Petrochem. Co., Ltd., Japan Kokai 72, 42, 883.

    Google Scholar 

  19. Maruzen Petrochem. Co., Ltd., Japan Kokai 72, 43, 185.

    Google Scholar 

  20. T. Suzuki, Y. Takegami, J. Furukawa, and R. Hirai, J. Polym. Sci. B 9, 931–939 (1971).

    Article  CAS  Google Scholar 

  21. J. Furukawa, Plast. Rubber Appl. February 33–40 (1977).

    Google Scholar 

  22. I. Maruyama, Dissertation, Kyoto Univ. (1976).

    Google Scholar 

  23. G. Gatti and A. Carbonaro, Makromol. Chem. 175, 1627–1640 (1974).

    Article  CAS  Google Scholar 

  24. Maruzen Petrochem. Co., Ltd., Fr. 2,099, 056 (1970).

    Google Scholar 

  25. A. S. Khachaturov, Vysokomol. Soed. B 21, 576–579 (1979).

    CAS  Google Scholar 

  26. J. Furukawa and R. Hirai, J. Polymer Sci. A-I, 10, 2139–2148 (1972).

    Article  CAS  Google Scholar 

  27. Maruzen Petrochem. Co., Ltd., Ger. Offen 2, 020, 168 (1970).

    Google Scholar 

  28. Maruzen Petrochem. Co., Ltd., Ger. Offen 1, 964, 706 (1970).

    Google Scholar 

  29. Maruzen Petrochem. Co., Ltd., Japan Kokai 74 41, 115.

    Google Scholar 

  30. Maruzen Petrochem. Co., Ltd., Japan 73 2, 937.

    Google Scholar 

  31. Maruzen Petrochem. Co., Ltd., Japan 73 11, 232.

    Google Scholar 

  32. Maruzen Petrochem. Co., Ltd., Japan Kokai 73 25, 086.

    Google Scholar 

  33. Maruzen Petrochem. Co., Ltd., Japan Kokai 73 25, 085.

    Google Scholar 

  34. Maruzen Petrochem. Co., Ltd., Japan 71 43, 088.

    Google Scholar 

  35. Maruzen Petrochem. Co., Ltd., Japan 74 26, 304.

    Google Scholar 

  36. Maruzen Petrochem. Co., Ltd., Japan 72 19, 694.

    Google Scholar 

  37. Maruzen Petrochem. Co., Ltd., Japan Kokai 80 110, 107.

    Google Scholar 

  38. W. Wieder and J. Witte, J. Appl. Polym. Sci. 26, 2503–2508 (1981).

    Article  CAS  Google Scholar 

  39. Maruzen Petrochem. Co., Ltd., Ger. Offen 2, 023, 405 (1970).

    Google Scholar 

  40. Maruzen Petrochem. Co., Ltd., Ger. Offen 2, 113, 164 (1971).

    Google Scholar 

  41. Maruzen Petrochem. Co., Ltd., Japan 72 19, 695.

    Google Scholar 

  42. Maruzen Petrochem. Co., Ltd., Japan 74 26, 303.

    Google Scholar 

  43. Maruzen Petrochem. Co., Ltd., Japan 74 26, 071.

    Google Scholar 

  44. Maruzen Petrochem. Co., Ltd., Japan 74 26, 072.

    Google Scholar 

  45. A. Kawasaki, M. Taniguchi, I. Maruyama, M. Matsui, and K. Minomiya, unpublished work.

    Google Scholar 

  46. Maruzen Petrochem. Co., Ltd., Ger. Offen 2, 112, 839 (1971).

    Google Scholar 

  47. Maruzen Petrochem. Co., Ltd., US 3, 737, 417 (1973).

    Google Scholar 

  48. Maruzen Petrochem. Co., Ltd., Ger. Offen 2, 128, 804 (1971).

    Google Scholar 

  49. Maruzen Petrochem. Co., Ltd., Japan Kokai 73, 70, 791.

    Google Scholar 

  50. P. J. Peyroche, Y. Girard, R. Laputte, and A. Guyot, Makromol. Chem. 129, 215–233 (1969).

    Article  CAS  Google Scholar 

  51. D. C. Bradley and C. E. Holloway, J. Chem. Soc. A 1316–1319 (1968).

    Google Scholar 

  52. I. Maruyama and T. Neishiyama, unpublished work.

    Google Scholar 

  53. G. Fontana and S. Ferioli, Ital. 665, 277 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Springer Science+Business Media New York

About this chapter

Cite this chapter

Furukawa, J., Maruyama, I. (1985). Alternating Copolymerization of Olefins and Diolefins. In: Cowie, J.M.G. (eds) Alternating Copolymers. Speciality Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9139-6_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-9139-6_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9141-9

  • Online ISBN: 978-1-4757-9139-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics