Abstract
The use of homogeneous catalysts on an industrial scale leads to a number of practical problems, e.g., difficulties associated with corrosion, plating out on the reactor wall, and catalyst recovery from the reaction mixture. Chemically bonding metal complexes to an insoluble solid is one of the sufficient methods for conquering these difficulties.1–3 This method is achieved by the treatment of metal ions with organic or inorganic polymers containing ligand atoms having a coordinating ability to metals. The catalysts, prepared in such manner, are situated between those usually classified as “heterogeneous” and as “homogeneous”, and can be regarded as a new class of catalysts: “hybrid catalysts”.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
N. K. Mathur, C. K. Narung, and R. E. Williams, “Polymers as Aids in Organic Chemistry,” Academic Press, New York (1980).
C. U. Pittman, Jr., in G. Wilkinson, ed., “Comprehensive Organometallic Chemistry,” Vol. 8, Pergamon Press, Oxford (1982), p. 553.
N. L. Holy, in L. H. Pignolet, ed., “Homogeneous Catalysis with Metal Phosphine Complexes,” Plenum, New York (1983), p. 443.
J. P. Collman and L. S. Hegedus, “Principles and Applications of Organotransition Metal Chemistry,” University Science Books, California (1980).
J. Tuji, “Organic Synthesis with Palladium Compounds,” Springer-Verlag, Berlin (1980).
L. H. Pignolet, “Homogeneous Catalysis with Metal Phosphine Complexes,” Plenum, New York (1983).
M. Terasawa, K. Kaneda, T. Imanaka, and S. Teranishi, J. Catal., 51, 406 (1978).
M. Terasawa, K. Kaneda, H. Yamamoto, T. Imanaka, and S. Teranishi, J. Catal., 57, 315 (1979).
K. Kaneda, T. Uchiyama, M. Terasawa, T. Imanaka, and S. Teranishi, Chem. Lett., 449 (1976).
K. Kaneda, M. Terasawa, T. Imanaka, and S. Teranishi, Tetrahedron Lett., 2957 (1977).
M. Terasawa, K. Kaneda, T. Imanaka, and S. Teranishi, J. Organomet. Chem., 162, 403 (1978).
K. Kaneda, H. Kurosaki, M. Terasawa, T. Imanaka, and S. Teranishi, J. Org. Chem., 46, 2356 (1981).
K. Kaneda, M. Terasawa, T. Imanaka, and S. Teranishi, Chem. Lett., 995 (1976).
M. Terasawa, K. Sano, K. Kaneda, T. Imanaka, and S. Teranishi, J. Chem. Soc., Chem. Commun., 650 (1978).
K. Kaneda, M. Kobayashi, T. Imanaka, and S. Teranishi, Chem. Lett., 1483 (1984).
K. Kaneda, H. Yamamoto, T. Imanaka, and S. Teranishi, J. Molecular Catal., 29, 99 (1985).
D. Adams, “Metal-Ligand and Related Vibrations: A Critical Survey of the Infrared and Raman Spectra of Metallic and Organometallic Compounds,” 1st Ed., Edward Arnold, London (1967).
M. A. Bennet and P. A. Longstaff, J. Am. Chem. Soc., 91, 6266 (1969).
H. Itatani and J. C. Bailar, Jr., J. Am. Oil Chem. Soc., 44, 147 (1967).
H. Bruner and J. C. Bailar, Inorg. Chem., 12, 1465 (1973)
R. R. Schrock and J. A. Osborn, J. Am. Chem. Soc., 98, 2143 (1976).
For a review, see E. N. Marvell and T. Li, Synthesis, 457 (1973).
K. Kaneda, H. Kobayashi, Y. Fujiwara, T. Imanaka, and S. Teranishi, J. Org. Chem., 44, 55 (1979).
H. Nozima, N. Kawata, Y. Nakamura, K. Maruya, T. Mizoroki, and A. Ozaki, Chem. Lett., 1163 (1973).
T. Ito, K. Takahashi, and Y. Takami, Nippon Kagakukaishi, 1097 (1974).
M. G. Barlow, M. J. Bryant, R. M. Haszeldine, and A. G. Mackie, J. Organomet. Chem., 21, 215 (1970).
K. Kawamoto, A. Tatani, T. Imanaka, and S. Teranishi, Bull. Chem. Soc. Jpn., 44, 1239 (1971).
Catalysis of polymeric palladium(0) complexes has been also studied by other groups: a) B. M. Trost and E. J. Keinan, J. Am. Chem. Soc.. 100, 7779 (1978)
C. U. Pittman and Ng. Q., J. Organomet. Chem., 153, 85 (1978)
R. C. Card and D. C. Neckers, Inorg. Chem., 17, 2345 (1978).
R. F. Heck and J. P. Nolley, Jr., J. Org. Chem., 37, 2320 (1972).
H. A. Dieck and R. H. Heck, J. Organomet. Chem., 93, 259 (1975).
M. Yamamura, I. Moritani, and S. I. Murahashi, J. Organomet. Chem., 91, 259 (1975).
S. Takahashi, T. Shibano, and N. Hagiwara, Bull. Chem. Soc. Jpn., 41, 454 (1968).
M. Green, G. Scholes, and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 309 (1978).
S. Gardnev and D. Wright, Tetrahedron Lett., 163 (1972).
C. L. Thomas, “Catalytic Processes and Proven Catalysts,” Academic Press, New York (1970), p. 104.
K. Kaneda, H. Hiraki, T. Imanaka, and S. Teranishi, J. Molecular Catal., 9, 227 (1980).
K. Kaneda, M. Hiraki, T. Imanaka, and S. Teranishi, J. Molecular Catal., 12, 385 (1981)
K. Kaneda, M. Yasumura, M. Hiraki, T. Imanaka, and S. Teranishi, Chem. Lett., 1763 (1981)
K. Kaneda, T. Imanaka, and S. Teranishi, Chem. Lett., 1465 (1983)
K. Kaneda, M. Yasumura, T. Imanaka, and S. Teranishi, J. Chem. Soc., Chem. Commun., 935 (1982).
W. D. Bonds, Jr., C. H. Brubaker, Jr., E. S. Chandrasekaran, C. Gibbons, R. H. Grubbs, and L. C. Kroll, J. Am. Chem. Soc., 97, 2128 (1975).
J. P. Collman, L. S. Hegedus, M. P. Cooke, J. R. Norton, G. Doicetti, and D. N. Marquardt, J. Am. Chem. Soc., 94, 1789 (1972).
R. C. Ryan, G. M. Wilemon, M. P. Dalsanto, and C. U. Pittman, Jr., J. Molecular Catal., 5, 319 (1979).
S. Martinengo, G. Cianti, A. Sironi, and P. Chini, J. Am. Chem. Soc., 100, 7096 (1978).
G. Ciani and A. Sironi, J. Organomet. Chem., and S. Martinengo, J. Organomet. Chem., 192, C-42 (1980).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer Science+Business Media New York
About this paper
Cite this paper
Kaneda, K., Imanaka, T., Teranishi, S. (1987). Catalysts of Organic Polymer-Bound Pd and Rh Complexes. In: Seymour, R.B., Cheng, T. (eds) Advances in Polyolefins. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9095-5_16
Download citation
DOI: https://doi.org/10.1007/978-1-4757-9095-5_16
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-9097-9
Online ISBN: 978-1-4757-9095-5
eBook Packages: Springer Book Archive