Abstract
Devices which utilize high-Tc superconducting films require dielectric materials with low dielectric losses (tan δ), low dielectric constants, chemical inertness, and similar coefficients of thermal expansion to HTS materials. A major advance in the fabrication of such devices would be the deposition of high quality dielectric films by MOCVD (metal-organic chemical vapor deposition) which would enable the efficient, large-scale fabrication of multilayer superconductor-insulator structures. In this paper, we report the MOCVD deposition of epitaxial thin films of various pervoskite HTS lattice-matched dielectric materials: NdGaO3, PrGaO3, YA1O3, and Sr2AlTaO6. These pervoskite dielectric films were grown in situ on single crystal substrates in a horizontal reactor using volatile metal-organic b-diketonate complexes as precursors. Film morphology and microstructure are characterized by SEM and cross-sectional TEM. Energy dispersive x-ray analysis is used to verify the stoichiometry. The crystallinity and epitaxy of the dielectric films are characterized by x-ray diffraction.
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© 1994 Springer Science+Business Media New York
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Han, B., Neumayer, D.A., Goodreau, B.H., Marks, T.J. (1994). In Situ MOCVD of Dielectric Materials for High-Tc Superconducting Devices. In: Reed, R.P., Fickett, F.R., Summers, L.T., Stieg, M. (eds) Advances in Cryogenic Engineering Materials . An International Cryogenic Materials Conference Publication, vol 40. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9053-5_54
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DOI: https://doi.org/10.1007/978-1-4757-9053-5_54
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