Abstract
This chapter summarizes our present understanding of surface preparations for structural adhesive bonding of aluminum, titanium, and steel adherends. Both the initial bond strength and the subsequent bond durability depend critically on the interaction of the adhesive (and/or primer) with a pretreated adherend. There are two mechanisms of adhesion that are prominent in structural adhesive bonding: mechanical interlocking of the polymer adhesive with a microscopically rough adherend surface, and chemical bonding (with either covalent bonds or weaker van der Waals bonds) of adhesive molecules to the (intentional) adherend oxide. The magnitude and relative importance of both of these interactions depend greatly on the nature of the adherend surface prior to bonding and on the rheology and chemistry of the adhesive.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
J. I. Goldstein, in: Practical Scanning Electron Microscopy (J. I. Goldstein and H. Yahowitz, eds.), Plenum Press, New York (1975).
J. D. Minford, Adhes. Age, 21 (1974).
H. W. Eickner and W. E. Schowalter, Report No. 1813, Forest Products Laboratory, Madison, WI (1950).
G. S. Kabayashi and D. J. Donnelly, Boeing Co. Report No. DG-41517.
Mil Spec MIL-A-8625C.
W. Brockmann and O. D. Hennemann, in: Proc. 11th SAMPE Tech. Conf., pp. 804–816, SAMPE, Azusa, CA (1979).
W. Brockman, O. D. Hennemann, H. Kollek, and C. Matz, Int. J. Adhes. Adhes. 6, 115 (1986).
I. Olefjord and L. Kozma, Mater. Sci. Technol. 3, 860 (1987).
T. S. Sun, J. M. Chen, J. D. Venables, and R. Hopping, Appl. Surf. Sci. 1, 202 (1978).
Bell Helicopter Process Specification 4352, rev J (June 1980).
Fokker VFW B. V. Process Specification TH 6.7851 (August 1978).
J. D. Venables, D. K. McNamara, J. M. Chen, T. S. Sun, and R. L. Hopping, Appl. Surf. Sci. 3, 88 (1979).
J. D. Venables, J. Mater. Sci. 19, 2431 (1984).
G. D. Davis, J. S. Ahearn, L. J. Matienzo, and J. D. Venables, J. Mater. Sci. 20, 975 (1985).
J. M. Chen, T. S. Sun, J. D. Venables, D. K. McNamara, and R. Hopping, in: Proc. 24th Nat. SAMPE Symp., p. 1188, Azusa, CA (1979).
A. J. Kinloch, H. E. Bishop, and N. R. Smart, J. Adhes. 14, 105 (1982).
D. A. Hardwick, J. S. Ahearn, A. Desai, and J. D. Venables, J. Mater. Sci. 21, 179 (1986).
S. M. El-Mashri, R. G. Jones, and A. J. Forty, Philos. Mag. A 48, 665 (1983).
R. H. Olsen, Proc. 11thNat. SAMPE Tech. Conf., p. 770, SAMPE, Azusa, CA (1979).
H. E. Franz, Z. Werksofftech. 14, 164, 290 (1983).
H. Kollek, Int. J. Adhes. Adhes. 5, 75 (1985).
G. D. Davis, T. S. Sun, J. S. Ahearn, and J. D. Venables, J. Mater. Sci. 17, 1807 (1982).
A. J. Kinloch and N. R. Smart, J. Adhes. 12, 23 (1981).
J. S. Solomon and D. E. Hamlin, Appl. Suf. Sci. 4, 307 (1980).
P. Poole and J. F. Watts, Int. J. Adhes. Adhes. 5, 33 (1985).
A. J. Kinloch, H. E. Bishop, and N. R. Smart, J. Adhes. 14, 105 (1982).
M. F. Abd Rabbo, J. A. Richardson, and G. C. Wood, Corros. Sci. 16, 689 (1976).
V Singh, P. Rama, G. J. Cocks, and D. M. R. Taplin, J. Mater. Sci. Lett. 14, 745 (1979).
A. Csanady, I. Imre-Baan, E. Lichtenberger-Bajza, E. Szontagh, and F. Domolki, J. Mater. Sci. 15, 2761 (1980).
A. E. Yaniv, N. Fin, H. Dodiuk, and I. E. Klein, Appl. Surf. Sci. 20, 538 (1985).
D. J. Arrowsmith and A. W. Clifford, Int. J. Adhes. Adhes. 5, 40 (1985).
W. Brockmann and O. D. Hennemann, in: Adhesive Joints (K. L. Mittal, ed.), p. 469, Plenum Press, New York (1984).
K. W. Allen and M. G. Stevens, J. Adhes. 14, 137 (1982).
D. K. McNamara, J. D. Venables, R. L. Hopping, and L. Cottrell, Proc. 13th Natl. SAMPE Tech. Conf., p. 666, SAMPE, Azusa, CA (1981).
A. V. Pocius, in: Adhesion Aspects of Polymeric Coatings (K. L. Mittal, ed.), p. 173, Plenum Press, New York (1983).
A. V. Pocius, T. H. Wilson, Jr., S. H. Lunquist, and S. Sugii, in: Progress in Advanced Materials and Processes: Durability, Reliability, and Quality Control (G. Barteids and R. J. Schliekelmann, eds.), p. 71, Elsevier Science, Amsterdam (1985).
J. S. Ahearn, T. S. Sun, C. Froede, J. D. Venables, and R. Hopping, SAMPE Q. 12, 39 (1980).
T. P. Hoar and N. F. Mott, J. Phys. Chem. Solids 9, 97 (1959).
J. S. Ahearn and G. D. Davis, in Proc. Adhesion ’87, p. 291, York, England (1987).
J. D. Venables, D. K. McNamara, J. M. Chen, B. M. Ditchek, T. I. Morgenthaler, T. S. Sun, and R. L. Hopping, in Proc. 12th Nat. SAMPE Techn. Conf., p. 909, Azusa, CA (1980).
W. Brockmann, AGARD Lecture Series No. 102 (1979).
S. Naviroj, J. L. Koenig, and H. Ishida, J. Adhes. 18, 93 (1985).
P. Walker, J. Coat. Technol. 52, 29 (1980).
J. S. Ahearn, G. D. Davis, T. S. Sun, and J. D. Venables, in: Adhesion Aspects of Polymeric Coatings (K. L. Mittal, ed.), p. 281, Plenum Press, New York (1983).
J. D. Venables, M. E. Tadros, and B. M. Ditchek, US Patent 4,308,079 (Assigned to Martin Marietta, 1983).
D. A. Hardwick, J. S. Ahearn, and J. D. Venables, J. Mater. Sci. 19, 223 (1984).
D. K. Shaffer, H. M. Clearfield, and J. S. Ahearn, Martin Marietta Technical Report MML TR 86–76c, submitted to ONR under contract no. N00014–85-C-0804, 1986 (unpublished).
J. M. Chen, T. S. Sun, J. D. Venables, and R. Hopping, in: Proc. 22nd Natl. SAMPE Symp., p. 25, San Diego, CA (1977).
A. J. Kinloch, J. Adhes. 10, 193 (1979).
R. A. Gledhill and A. J. Kinloch, J. Adhes. 6, 315 (1974).
D. M. Brewis, in: Durability of Structural Adhesives, pp. 215–254, Applied Science Publishers, Essex, U.K. (1983).
D. J. Arrowsmith and A. W. Clifford, Int. J. Adhes. Adhes. 5, 40 (1985).
S. G. Hill, P. D. Peters, and C. L. Hendricks, NASA contractor report 177936, under contract no. NAS1–15605, 1985 (unpublished).
D. J. Progar and T. L. St. Clair, Int. J. Adhes. Adhes. 6, 25 (1986); D. J. Progar, NASA Tech. Mem. 87738, 1986 (unpublished).
S. R. Brown, in: Proc. 27th Natl. SAMPE Symp., p. 363, SAMPE, Azusa, CA (1982).
B. M. Ditchek, T. I. Morgenthaler, T. S. Sun, and R. L. Hopping, in: Proc. 25th Natl. SAMPE Symp., p. 909, SAMPE, Azusa, CA (1980).
M. Natan, J. D. Venables, and K. R. Breen, in: Proc. 27th Natl. SAMPE Symp., p. 178, SAMPE, Azusa, CA (1982).
H. M. Clearfield, D. K. Shaffer, and J. S. Ahearn, in: Proc. 18th Natl. SAMPE Tech. Conf., p. 921, SAMPE, Azusa, CA (1986);
H. M. Clearfield, D. K. Shaffer, J. S. Ahearn, and J. D. Venables, J. Adhes. 23, 83 (1987).
Y. Moji and J. A. Marceau, U.S. Patent No. 3959091 (assigned to the Boeing Company, 1976).
A. C. Kennedy, R. Köhler, and P. Poole, Int. J. Adhes. Adhes. 3, 133 (1983).
D. J. Progar, NASA Tech. Mem. 89045, 1986 (unpublished).
J. A. Filbey, J. P. Wightman, and D. J. Progar, J. Adhes. 20, 283 (1987).
K. W. Allen, H. S. Alsalim, and W. C. Wake, J. Adhes. 6, 153 (1974).
J. L. Cotter and A. Mahoon, Int. J. Adhes. Adhes. 2, 47 (1982) and references cited therein.
B. M. Ditchek, K. R. Breen, and J. D. Venables, Martin Marietta Technical Report MML TR 80–17c, 1980 (unpublished); M. Natan, K. R. Breen, and J. D. Venables, Martin Marietta Technical Report MML TR 81–42c, 1981 (unpublished); both submitted to NASC under contract No. N00019–80-C-0508.
R. F. Wegman and D. W. Levi, in: Proc. 27th Natl. SAMPE Symp., p. 440, SAMPE, Azusa, CA (1982).
H. M. Clearfield, D. K. Shaffer, C. P. Blankenship, Jr., and J. S. Ahearn, in: Proc. 5th Joint Military/Government/Industry Symposium on Structural Adhesive Bonding, p. 206, ADPA, Arlington, VA (1987).
H. M. Clearfield, G. O. Cote, K. A. Olver, D. K. Shaffer, and J. S. Ahearn, Surf. Interface Anal. 11, 347 (1988).
T. C. Ward and P. A. Konig, Private communication; presented at the 10th annual meeting of The Adhesion Society, Inc., Williamsburg, VA (1987).
A. Mahoon, in: Proc. 27th Natl. SAMPE Symp., p. 150, SAMPE, Azusa, CA (1982).
P. D. Peters, E. A. Ledbury, C. L. Hendricks, and A. G. Miller, in: Proc. 27th Natl. SAMPE Symp., p. 940, SAMPE, Azusa, CA (1982).
T. L. St. Clair, P. M. Hergenrother, and D. J. Progar, private communication; some lap-shear specimens failed at the oxide-metal interface during the course of these long-term exposures.
See, for example, Reference 14; G. D. Davis, J. S. Ahearn, L. J. Matienzo, and J. D. Venables, J. Mater. Sci. 20, 975 (1985).
D. K. Shaffer, H. M. Clearfield, C. P. Blankenship, Jr., and J. S. Ahearn, in: Proc. 19th SAMPE Tech. Conf., p. 291, SAMPE, Azusa, CA (1987).
Specimens from the study in Reference 54 were obtained for failure analysis and exhibited oxide failures.
A. J. Duke, J. Iron Steel Inst. 207, 570 (1969).
A. V. Pocius, D. A. Wangness, C.J. Aimer, and A. G. McKown, Presented at the 7th Annual Meeting of the Adhesion Society Meeting, Jacksonville, Florida (1984).
D. L. Trawinski, D. K. McNamara, and J. D. Venables, SAMPE Q. 15, 6 (1984).
Y. Gilibert and G. Verchery, in: Adhesive Joints: Formation, Characteristics and Testing (K. Mittal, ed.), Plenum Press, New York (1984).
J. F. Watts and J. E. Castle, J. Mater. Sci. 19, 2259 (1984).
E. H. Andrews and N. E. King, J. Mater. Sci. 11, 2004 (1976).
V. G. Zadorozhnyi, D. M. Rafalovich, and I. L. Roikh, Elektronnaya Obrab. Mater. 1, 43 (1977).
K. Ruhsland, in: Adhesive Joints: Formation, Characteristics and Testing (K. L. Mittal, ed.), p. 257, Plenum Press, New York (1984).
P. J. Hine, D. E. Packham, and S. El Muddarris, in: Proc. The International Adhesion Conference, pp. 10.1–10.4, Plastics and Rubber Institute, London, Nottingham, UK (September 1984).
W. Russell, R. Rosty, and D. W. Levi, Treatment of Steel Surfaces for Improving Adhesive Bonds, Technical Report ARSCD-TR-82005, U.S. Army Research and Development Center, Dover, New Jersey (June 1982).
W. J. Russell, R. Rosty, K. M. Adelson, M. J. Bodnar, R. F. Wegman, E. A. Garnis, and D. W. Levi, Use of Stressed Durability Testing to Evaluate Polyhydric Alcohol-Phosphoric Acid Pretreatment of Steel for Adhesive Bonding, Technical Report ARSCD-TR-83014, U.S. Army Research and Development Center, Dover, New Jersey (October 1983).
A. K. Mindyuk, V. I. Sholok, O. P. Savitskaya, A. O. Tkach, and Y. S. Kost, Science for Production, p. 560, Plenum Press, New York (1984).
V. Leroy, Mater. Sci. Eng. 42, 289 (1980).
N. N.-C. Hsu, J. S. Noland, J. S. Brinen, and S. W. Graham, Presented at the Seventh Annual Adhesion Society Meeting, Jacksonville, FL (1984).
E. A. Podoba, S. P. Kodali, R. C. Curley, D. K. McNamara, and J. D. Venables, Appl. Surf. Sci. 9, 359 (1981).
N. L. Bottrell, Sheet Metal Ind. 42(461), 667 (1965).
A. W. Henderson, in: Aspects of Adhesion, pp. 33–46, University of London Press, London (1965).
H. L. David, Met. Deform. 26, 45 (1974).
H. L. David, Met. Deform. 19, 27 (1973).
N. L. Rodgers, in: Proc. Conf. “Specialized Cleaning, Finishing and Coating Processes”, pp. 63–77, American Society for Metals, Los Angeles, CA (Feb. 1980).
K. W. Allen, J. Adhes. 8, 183 (1977).
L. G. Look, in: Proc. Conf. Technology Transfer SAMPE, p. 150, Azusa, CA (1981).
A. V. Pocius, C. J. Almer, R. D. Wald, T. H. Wilson, Jr., and B. E. Davidian, SAMPE J. 20, 11 (1984).
T. Smith, J. Adhes. 17, 1 (1984).
R. P. Haak and T. Smith, Int. J. Adhes. Adhes. 1, 5 (1983).
A. G. Hirko, in: Proc. Conf. Hi-Tech Review 1984, SAMPE, Azusa, CA (1984).
D. L. Trawinski, in: Proc. Conf. Advancing Technology in Materials and Processes, pp. 1065–1072, SAMPE, Azusa, CA (1985).
C. Bishof, A. Bauer, R. Kapelle, and W. Possart, Int. J. Adhes. Adhes. 5, 97 (1985).
D. L. Trawinski and R. D. Miles, in: Proc. Conf. Hi-Tech Review 1984, p. 633, SAMPE, Albuquerque, NM (1984).
H. E. Chandler, Met. Prog. 38 (1982).
T. Sugama, in: Proc. Conf. Structural Adhesives Needs Through the 1990s, p. 11, Army Research Office, Raleigh, North Carolina (1985).
F. J. Spaeth, in: Proc. Conf. Finishing ’83’, Dearborn, MI, pp. T-1-T-4, Society of Manufacturing Engineers, Warrendale, PA (February 1983).
M. Kronstein, in: Proc. SAE Congress Society of Automotive Engineers, paper 800444, Detroit MI (1980).
E. Janssen, Mater. Sci. Eng. 42, 309 (1980).
M. C. Ross, R. F. Wegman, M. J. Bodner, and W. C. Tanner, SAMPE J. 4, 11 (1976).
L. M. Gan, H. W. K. Ong, and T. L. Tan, J. Adhes. 16, 233 (1984).
H. W. K. Ong, L. M. Gan, and T. L. Tan, J. Adhes. 20, 117 (1986).
S. Aloru, P. Bartoli, M. Leoni, and M. Memmi, in: Proc. Conf. International Deep Drawing Research Group Conference, Paper 10, Hoogoven Ijmuiden BV, Amsterdam, Netherlands (1985).
D. K. McNamara and J. S. Ahearn, Int. Mater. Rev. 32, 292 (1987).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Springer Science+Business Media New York
About this chapter
Cite this chapter
Clearfield, H.M., McNamara, D.K., Davis, G.D. (1991). Adherend Surface Preparation for Structural Adhesive Bonding. In: Lee, LH. (eds) Adhesive Bonding. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9006-1_8
Download citation
DOI: https://doi.org/10.1007/978-1-4757-9006-1_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-9008-5
Online ISBN: 978-1-4757-9006-1
eBook Packages: Springer Book Archive