Abstract
Investigation of the high-resolution proton NMR spectra of water and aqueous solutions makes it possible to obtain additional information on their structure and on the nature of their intermolecular interactions. It is now thought that the displacement of the proton signal toward higher yield strengths when the temperature is raised is due principally to weakening or complete rupture of the hydrogen bonds [1, 2]. This affords new opportunities for selection of reliable models of the water structure [3–5]. It has been found that the best agreement with NMR data is achieved with the two-structure model [6–9].
Keywords
Proton Signal Water Structure Heavy Water High Field Strength High Yield Strength
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Literature Cited
- 1.Schneider, H. J. Bernstein, and J. A. Pople, J. Chem. Phys., 28: 601 (1958).CrossRefGoogle Scholar
- 2.H. G. Hertz and W. Spalthoff, Z. Electrochem., 63: 1096 (1959).Google Scholar
- 3.N. Muller, J. Chem. Phys., 43 (6): 2555 (1965).CrossRefGoogle Scholar
- 4.J. C. Hindman, J. Chem. Phys., 44 (12): 4582 (1966).CrossRefGoogle Scholar
- 5.H. Ruterjans and H. A. Scheraga, J. Chem. Phys., 45 (9): 3296 (1966).CrossRefGoogle Scholar
- 6.L. Hall, Phys. Rev., 73 (7): 775 (1948).CrossRefGoogle Scholar
- 7.C. M. Davies and T. A. Litovitz, J. Chem. Phys., 42(7):2563(1965).CrossRefGoogle Scholar
- 8.V. M. Vdovenko, Yu. V. Gurikov, and E. K. Legin, Zh. Strukt. Khim., 7: 819 (1966).Google Scholar
- 9.V. M. Vdovenko, Yu. V. Gurikov, and E. K. Legin, in: Structure and Role of Water in the Living Organism [in Russian], Vol. 1, Izd. LGU (1966).Google Scholar
- 10.G. Nemethy and H. A. Scheraga, J. Chem. Phys., Vol. 36, No. 12 (1962).CrossRefGoogle Scholar
- 11.R. P. Marchi and H.Eyring, J. Phys. Chem., 68 (2): 221 (1964).CrossRefGoogle Scholar
- 12.M. S. Bergquist and L. E. G. Eriksson, Acta. Chem. Scand., 16 (9): 2308 (1962).CrossRefGoogle Scholar
- 13.G. Nemethy and H. A. Scheraga, J. Chem. Phys., 43 (3): 680 (1964).CrossRefGoogle Scholar
- 14.V. M. Vdovenko, Yu. V. Gurikov, and E. K. Legin, Dokl. Akad. Nauk SSSR, 172: 126 (1967).Google Scholar
- 15.P. Kirschenbaum, Heavy Water [Russian translation], Izd. Inostr. Lit. (1953).Google Scholar
- 16.O. Ya. Samoilov and M. N. Buslaeva, Zh. Strukt. Khim., 4: 502 (1963).Google Scholar
- 17.A. Ben-Naim, Israel J. Chem., 2 (5): 278 (1964).Google Scholar
- 18.H. S. Frank, Proc. Roy. Soc., A247: 481 (1958).CrossRefGoogle Scholar
- 19.Yu. V. Gurikov, Zh. Strukt. Khim., 5: 188 (1964).Google Scholar
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