Abstract
An unequal molecular interaction energy of solute and solvent with the surfaces of a thin interlayer or film leads to a nonuniform distribution of concentration across the layer or film. For the same reason, the mean solution concentration in a thin interlayer or film may differ from that of the bulk solution in equilibrium with it.
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Derjaguin, B.V., Churaev, N.V., Muller, V.M. (1987). The Adsorption Component of Disjoining Pressure in Nonionic Solutions. In: Surface Forces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6639-4_5
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DOI: https://doi.org/10.1007/978-1-4757-6639-4_5
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