Forces Near Interfaces

  • B. V. Derjaguin
  • N. V. Churaev
  • V. M. Muller

Abstract

A monograph devoted to surface forces must begin with an explanation of what is meant by this term. We start by discussing the “micro-forces” acting on individual molecules and ions near interfaces. However, this notion remains vague unless micro-forces are averaged over a sufficiently long time for a certain fixed distance from the interface. In this way we obtain a macroscopic description of surface forces. Such a description forms the basis of the interpretation of surface tension and capillarity both in the older approach of Clairaut (1743) and Laplace (1806) and in the newer approach of Bakker (1928), based on introducing the pressure tensor in the interfacial region.

Keywords

Diffuse Layer Electrical Double Layer Colloid Interface Surface Force Faraday Trans 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1987

Authors and Affiliations

  • B. V. Derjaguin
    • 1
  • N. V. Churaev
    • 1
  • V. M. Muller
    • 1
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRMoscowUSSR

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