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Forces Near Interfaces

  • Chapter
Surface Forces

Abstract

A monograph devoted to surface forces must begin with an explanation of what is meant by this term. We start by discussing the “micro-forces” acting on individual molecules and ions near interfaces. However, this notion remains vague unless micro-forces are averaged over a sufficiently long time for a certain fixed distance from the interface. In this way we obtain a macroscopic description of surface forces. Such a description forms the basis of the interpretation of surface tension and capillarity both in the older approach of Clairaut (1743) and Laplace (1806) and in the newer approach of Bakker (1928), based on introducing the pressure tensor in the interfacial region.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow, USSR

    B. V. Derjaguin, N. V. Churaev & V. M. Muller

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  1. B. V. Derjaguin
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Derjaguin, B.V., Churaev, N.V., Muller, V.M. (1987). Forces Near Interfaces. In: Surface Forces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6639-4_1

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  • DOI: https://doi.org/10.1007/978-1-4757-6639-4_1

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