Photophysical and Photochemical Properties of Gold(l) Complexes

  • Jennifer M. Forward
  • John P. FacklerJr.
  • Zerihun Assefa
Chapter
Part of the Modern Inorganic Chemistry book series (MICE)

Abstract

Transition metal complexes with an open-shell configuration (d n , n < 10) have received considerable attention for their interesting photophysical properties. The binuclear metal-metal bonded complexes of RhI, IrI, and PtII display rich photochemistry.1 One example of particular interest is the PtII complex, [Pt2(H2P2O5)4]4−, which has an excited state that is better oxidant and reductant than its ground state,2 and undergoes facile atom-transfer reactions with a variety of organic substrates.3 However, perhaps the most extensively studied transition metal complexes in this area are based on [Ru(bpy)3]2+, bpy = bipyridine. The complexes have been used in the study of both electron and energy transfer reactions and contributed a great deal to the understanding of photochemistry in inorganic systems.4

Keywords

Gold Atom Dalton Trans Binuclear Complex Triplet Excited State Photochemical Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1999

Authors and Affiliations

  • Jennifer M. Forward
    • 1
  • John P. FacklerJr.
    • 1
  • Zerihun Assefa
    • 2
  1. 1.Department of ChemistryTexas A&M UniversityCollege StationUSA
  2. 2.Oak Ridge National LaboratoryChemical and Analytical Sciences DivisionOak RidgeUSA

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