Metal Hydrides pp 193-213 | Cite as

Hydride Formation at high Hydrogen Pressure

  • Bogdan Baranowski
Part of the NATO Advanced Study Institutes Series book series (NSSB, volume 76)

Abstract

The transition from low concentrated solutions of hydrogen in metals to hydride phases is treated from the point of view of the thermodynamic stability condition. The necessity for an increase of the hydrogen concentration in the metallic matrix is exposed. The available methods for creation of active hydrogen are reviewed. The simplicity of various kinetic procedures is outlined. The preference of the high pressure equilibrium method is clearly demonstrated. Recently used high pressure devices are shortly described whereby the limitations and difficulties are discussed. Properties possible to be directly investigated “in situ” conditions are enumerated. Examples of hydrides requiring high pressure of gaseous hydrogen for formation under equilibrium conditions are given. Transition metals like nickel, chromium, cobalt, manganese, molybdenium and rhodium as well as their alloys are mentioned. Some secondary properties possible to be measured are described. Conclusions and further perspectives of the high pressure technique are discussed.

Keywords

Gaseous Hydrogen Hydrogen Pressure Active Hydrogen Relative Electrical Resistance Metallic Matrix 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    B. Baranowski. “Nichtgleichgewichtsthermodynamik in der physikalischen Chemie,” VEB Deutscher Verlag für Grundstoffindustrie, Leipzig (1975).Google Scholar
  2. 2.
    B. Baranowski. Ber. Bunsenges. Physik. Chem. 76, 714 (1972).Google Scholar
  3. 3.
    B. Baranowski. Bull. Polon. Acad. Sci. 10, 451 (1962).Google Scholar
  4. 4.
    B. Baranowski, K. Bochenska. Z. Physik. Chem. (N.F.) 45, 140 (1965).CrossRefGoogle Scholar
  5. 5.
    B. Baranowski, R. Winiewski. Bull. Acad. Polon. Sci. 14, 273 (1965).Google Scholar
  6. 6.
    B. Baranowski, W. Bujnowski. Roczn. Chemii. 44, 2271 (1970).Google Scholar
  7. 7.
    B. Baranowski, W. Bujnowski, M. Tkacz. High Temperature - High Pressure 8, 656, (1976).Google Scholar
  8. 8.
    B. Baranowski. Plat. Met. Rev. 16, 10, (1972).Google Scholar
  9. 9.
    W. E. Antonov, F. T. Belash, W. F. Degtjareva, B. K. Ponomarev, E. G. Poniatowskij, W. G. Tissen. Solid State Physics 20, 2680, (1978).Google Scholar
  10. 10.
    B. Baranowski. “Metal-Hydrogen Systems at High Hydrogen Pressures” in “Hydrogen Metals II”, Ed. by G. Alefeld and J. Völkl ( Springer-Verlag, Berlin-Heidelberg-New York, 1978 ),pp. 157–200.Google Scholar
  11. 11.
    B. Baranowski, M. mialowski. J. Phys. Chem. Solids 12, 206 (1959).CrossRefGoogle Scholar
  12. 12.
    T. SkoAkiewicz. Phys. Stat. Sol. (a) 6, 29 (1971).CrossRefGoogle Scholar
  13. 13.
    A. W. Szafranski, B. B.ranowski. J. Phys. E. 8, 823 (1975).CrossRefGoogle Scholar
  14. 14.
    R. Wigniewski, A. J. Rostocki. Phys. Rev. B 3, 251 (1971).CrossRefGoogle Scholar
  15. 15.
    H. J. Bauer, B. Baranowski. Phys. Stat. Sol. (a) 40, K35 (1977).CrossRefGoogle Scholar
  16. 16.
    B. Baranowski. Z. Phys. Chem. (N.F.) 114 71 (1979).Google Scholar
  17. 17.
    S. Majchrzak, B. Baranowski, W. Bujnowski, M. Krukowski. Roczn. Chemii 46, 1173 (1972).Google Scholar
  18. 18.
    S. Majchrzak. Roczn. Chemii 51, 1549 (1977).Google Scholar
  19. 19.
    M. Tkacz, B. Baranowski. Roczn. Chemii 50, 2159 (1976).Google Scholar
  20. 20.
    T. Skoskiewicz. Phys. Stat. Sol. (a) 11, K123 (1972).CrossRefGoogle Scholar
  21. 21.
    B. Stritzker, H. Wühl. “Superconductivity in Metal-Hydrogen Systems” in “Hydrogen in Metals II”, edited by G. Alefeld and J. Volkl ( Springer-Verlag, Berlin-Heidelberg-New York, 1978 ), pp. 243–269.CrossRefGoogle Scholar
  22. 22.
    T. SkoAkiewicz, B. Baranowski. Phys. Stat. Sol. 30, K33 (1968).CrossRefGoogle Scholar
  23. 23.
    B. Baranowski, K. Bojarski. Roczn. Chemii 46, 525 (1972).Google Scholar
  24. 24.
    E. G. Poniatowskij, I. T. Belash. Dokl. Akad. Nauk SSSR, 229, 1171 (1976).Google Scholar
  25. 25.
    M. Krukowski, B. Baranowski. Roczn. Chemii 49, 1183 (1975).Google Scholar
  26. 26.
    E. G. Poniatowskij, I. T. Belash. Dokl. Akad-. Nauk SSSR 224 667 (1975).Google Scholar
  27. 27.
    M. Krukowski, B. B.ranowski. J. Less - Commn. Metals 49, 385 (1976).CrossRefGoogle Scholar
  28. 28.
    I. T. Belash, W. E. Antonov, E. G. Poniatowskij. Dokl. Akad. Nauk SSSR 235, 379 (1977).Google Scholar
  29. 29.
    W. E. Antonov, I. T. Belash, E. G. Poniatowskij. Dokl. Akad. Nauk SSSR 248 635 (1979).Google Scholar
  30. 30.
    B. Baranowski, M. Tkacz. Polish J. Chem. 54, 819 (1980).Google Scholar
  31. 31.
    B. Baranowski, K. BocheAka, S. Majchrzak. Roczn. Chemii 41, 2071 (1967).Google Scholar
  32. 32.
    E. O. Wollan, J. N. Cable, W. C. Koehler. J. Phys. Chem. Solids 24, 1141 (1963).Google Scholar
  33. 33.
    T. SkoAkiewicz. Phys. Stat. Solidi (a) 48, K165 (1978).CrossRefGoogle Scholar
  34. 34.
    B. Baranowski, T. Skoskiewicz. “High Hydrogen Pressures in Superconductivity”in “High-Pressure and Low Temperature Physics”, Edited by C. N. Chu and J. A. Woollam ( Plenum Press, New York and London, 1978 ),pp. 43–53.CrossRefGoogle Scholar
  35. 35.
    B. Baranowski, F. A. Lewis, S. Majchrzak, R. Winiewski. J. Chem. Soc. Faraday Trans. I 68, 653 (1972).Google Scholar
  36. 36.
    B. Baranowski, S. Majchrzak, T. B. Flanagan. J. Phys. Chem. 77, 35 (1973).CrossRefGoogle Scholar
  37. 37.
    W. E. Antonov, I. T. Belash, W. F. Degtjareva, E. G. Poniatowskij. Dokl._ Akad. Nauk SSSR 239 342 (1978).Google Scholar
  38. 38.
    B. Baranowski, S. Filipek: Roczn. Chemii 47, 2165 (1973).Google Scholar
  39. 39.
    S. Filipek, B. Baranowski. Roczn. Chemii 49, 1149 (1975).Google Scholar
  40. 40.
    S. Filipek. B. Baranowski. Polish J. Chem, 53, 951 (1979).Google Scholar
  41. 41.
    T. B. Flanagan, S. Majchrzak, B. Baranowski. Phil. Mag. 25, 257 (1972).CrossRefGoogle Scholar
  42. 42.
    S. Filipek, B. Baranowski, M. Yoneda. Roczn. Chemii 51, 2243 (1977).Google Scholar
  43. 43.
    I. T. Belash, W. E. Antonov, E. G. Poniatowskij. Dokl. Akad. Nauk SSSR 235, 128 (1977).Google Scholar
  44. 44.
    M. Kuballa, B. Baranowski. Ber. Bunsenges. Physik. Chem. 78, 335 (1974).Google Scholar
  45. 45.
    B. Baranowski, S. Majorowski. (in preparation)Google Scholar
  46. 46.
    B. Baranowski, T. Szymczyk. Polish J. Chem. (in press)Google Scholar

Copyright information

© Springer Science+Business Media New York 1981

Authors and Affiliations

  • Bogdan Baranowski
    • 1
  1. 1.Institute of Physical ChemistryPolish Academy of SciencesWarsawPoland

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