Abstract
The bonding in transition metal complexes has been described by three different theories: crystal field theory (CFT), valence bond theory (VBT), and molecular orbital theory (MOT). Detailed descriptions of these three approaches are given in the standard inorganic texts and are not repeated here. However, some general statements concerning the applicability of these various bonding descriptions for metal π-complexes are noted.
Keywords
- Electron Spin Resonance
- Transition Metal Complex
- Atomic Orbital
- Molecular Orbital Theory
- Effective Atomic Number
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Bibliography
C. J. Ballhausen and H. B. Gray, “Molecular Orbital Theory,” W. A. Benjamin, New York (1964).
F. Basolo and R. Johnson, “Coordination Chemistry,” W. A. Benjamin, New York (1964).
F. Basolo and R. G. Pearson, “Mechanisms of Inorganic Reactions,” 2nd ed., Interscience Publishers, New York (1967).
G. E. Coates, “Organometallic Compounds,” 2nd ed., Wiley-Methuen, London (1960).
F. A. Cotton, “Chemical Applications of Group Theory,” Interscience Publishers, New York (1963)
F. A. Cotton, J. Chem. Educ. 41:466.
F. A. Cotton and G. Wilkinson, “Advanced Inorganic Chemistry,” John Wiley & Sons, New York (1966).
F. A. Cotton and G. Wilkinson, “Progress in Inorganic Chemistry,” Vol. 1, p. 1, Interscience Publishers, New York (1959).
R. S. Drago, “Physical Methods in Inorganic Chemistry,” Reinhold Publishing, New York (1965).
H. B. Gray, “Electrons and Chemical Bonding,” W. A. Benjamin, New York (1964).
H. B. Gray, J. Chem. Educ. 41:2
H. H. Jaffe and M. Orchin, “Symmetry in Chemistry,” John Wiley & Sons, New York (1965).
S. F. A. Kettle, J. Chem. Educ. 43:21
E. M. Larson, “Transitional Elements,” W. A. Benjamin, New York (1964).
A. D. Liehr, J. Chem. Educ. 39:135 (1962).
J. N. Murrel, S. F. A. Kettle, and J. M. Tedder, “Valence Theory,” John Wiley & Sons, New York (1965).
L. F. Phillips, “Basic Quantum Chemistry,” John Wiley & Sons, New York (1965).
J. M. Richardson, in H. Zeiss (ed.), “Organometallic Chemistry,” p. 1, Reinhold Publishing, New York (1960).
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Tsutsui, M., Levy, M.N., Nakamura, A., Ichikawa, M., Mori, K. (1970). Nature of the π-Complex Bond. In: Introduction to Metal π-Complex Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5588-6_3
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DOI: https://doi.org/10.1007/978-1-4757-5588-6_3
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-5590-9
Online ISBN: 978-1-4757-5588-6
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