Review on Structural and Chemical Properties of Transition Metal Phosphorus Trisulfides MPS3

Part of the NATO ASI Series book series (NSSB, volume 148)


Layered phases are rather attractive compounds because they present many unusual physical and chemical properties that are not commonly encountered in three dimensional materials. Let us mention charge density waves occurrence, 2D anisotropic magnetic behaviour, strong anisotropy of conductivity for example. These specific properties are the consequence of space oriented and mainly covalent bondings taking place in the slabs that compose the structure. Transition metal dichalcogenides (T.M.D.C.) represent a significant and well known series of layered materials. In these, strongly bonded slabs composed of two anionic planes enclosing a cationic one, develop in infinite sheets. Stacking of such cation-chalcogen sandwiches leaves empty spaces between the layers otherwise weakly bonded to each other.


Octahedral Site Electronic Band Structure Cationic Radius Magnetic Chain Intercalation Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    M.C. Friedel: C.R.Acad.Sc. 119, 269 (1894)Google Scholar
  2. 2.
    M.C. Friedel: Bull. Soc. Chini. Fr. 11, 115 (1894)Google Scholar
  3. 3.
    L. Ferrand: Bull. Soc. Chie. Fr. 13, 115 (1895)Google Scholar
  4. 4.
    L. Ferrand: Ann. Chiai. Phys. 17, 388 (1895)Google Scholar
  5. 5.
    L. Ferrand: C.R. Hebd. Acad. 7. 122, 621 (1896)Google Scholar
  6. 6.
    W. Klingen: Thesis, Höhenheim (W.G.) (1969)Google Scholar
  7. 7.
    W. Klingen, R. Ott, H. Hahn: Z. anorg. allg. Chem. 396, 271 (1973)CrossRefGoogle Scholar
  8. 8.
    G. Ouvrard: Thesis, Plantes (France) (1980)Google Scholar
  9. 9.
    B.J. Curtis, F.P. Eromenenegger, R. Nitsche: R.C.A. Review 647 (1970)Google Scholar
  10. 10.
    R. Nitsche, P. Wild: Mat. Res. Bull. 5, 419 (1970)CrossRefGoogle Scholar
  11. 11.
    B.I. Taylor, J. Steger, A. Wold: J. Sólid State Chem. 7, 461 (1973)CrossRefGoogle Scholar
  12. 12.
    G. Ouvrard, R. Brec: unpublished results.Google Scholar
  13. 13.
    G. Ouvrard, R. Grec, J. Rouxel: C.R. Acad. Sc. 294II, 971 (1982)Google Scholar
  14. 14.
    E. Prouzet, G. Ouvrard, R. Brec: Mat. Res. Bull. 21, 195 (1986)CrossRefGoogle Scholar
  15. 15.
    G. Ouvrard, R. Fréour, R. Brec, J. Rouxel: Mat. Rés. Bull. 20, 1053 (1985)CrossRefGoogle Scholar
  16. 16.
    A.H. Thompson, M.S. Whittingham: Mat. Res. Bull. 12, 741 (1-977)Google Scholar
  17. 17.
    R. Brec, D. Schleich, A. Louisy, J. Rouxel: Ann. Œim. Fr. 3, 347 (1978)Google Scholar
  18. 18.
    J.P. Odile, J.J. Steger, A. Wold: Inorg. Chem. 14, 2400 (1975)CrossRefGoogle Scholar
  19. 19.
    H. Mercier, E. Canadell, Y. Mathey: Inorg. Chem. to be published (1986)Google Scholar
  20. 20.
    A. Leblanc-Soreau, J. Rouxel, C.R. Acad. Sc. 291C, 263 (1980)Google Scholar
  21. 21.
    P. Colombet, A. Leblanc, N. Danot, J. Rouxel:Nö v. J. Chie. 7, 333 (1983)Google Scholar
  22. 22.
    S. Lee, G. Ouvrard, P. Colombet, R. Grec: Mat. Res. Bull. to-be published (1986).Google Scholar
  23. 23.
    Z. Ouili, A. Leblanc, P. Colombet: J. Solid State Chem. to be published (1986).Google Scholar
  24. 24.
    Y. Mathey, R. Clément, J.P. Audière, O. Poizat, C. Sourisseau: Solid State Ionics 9amp;;;10, 459, (1983)Google Scholar
  25. 25.
    G. üuvrrd; R. Grec, J. Rouxel: C.R. Acad. Sc. 294C, 971 (1982)Google Scholar
  26. 26.
    G. Ouvrard, R. Brec, J. Rouxel: Mat. Res. Bull. 20, 1181 (1985)CrossRefGoogle Scholar
  27. 27.
    R. Grec, G. Ouvrard, J. Rouxel: Mat. Res. Bull. 76, 1257 (1985)Google Scholar
  28. 28.
    S. Soled, A. Wold: Mat. Res. Bull. 11, 657 (1976)CrossRefGoogle Scholar
  29. 29.
    P. Colombet, A. Leblanc, N. Danot, T Rouxel: J. Solid State Chem. 41, 174 (1982)CrossRefGoogle Scholar
  30. 30.
    Y. Hathey, H. Mercier, A. ilichalowicz, A. Leblanc: J. Phys. Chem. Solids 46, 1025 (1985)CrossRefGoogle Scholar
  31. 31.
    Hathey, A. ttichalowicz, P. Toffoli, G. Vlaic: Inorg. Chem. 23, 897 (1984)Google Scholar
  32. 32.
    O.Poizat, C. Sourisseau: J. Solid State Chem. 59, 371 (1985)Google Scholar
  33. 33.
    U. Poizat: Thesis, Paris (1985).Google Scholar
  34. 34.
    R. Grec, U.N. Schleich, G. Ouvrard, A. Louisy, J. Rouxel: Inorg. Chem. 18, 1814 (1979)CrossRefGoogle Scholar
  35. 35.
    Y. Chabre, P. Segransan, C. Berthier, G. Ouvrard: In Fast Ion Transport in Solids Ed. P. Vashishta, J.N. Mundy, G.K. Shenoy, 221 (North-Holland 1979 )Google Scholar
  36. 36.
    G. Le Flee, R. Brec, G. Ouvrard, A. Louisy, P. Segransan: J. Phys. Chem. Solids, 43, 455 (1982)CrossRefGoogle Scholar
  37. 37.
    K. Kurosawa, S. Saito, Y. Yamaguchi: J. Phys. Soc. Jap. 52, 3919 (1983)CrossRefGoogle Scholar
  38. 38.
    P. Jernberq, S. Bjarman, R. Wäppling: J. Hag. Mag. Mat. 46, 178 (1984)Google Scholar
  39. 39.
    F.S. Khumalo, H.P. Hugues: Phys. Rev. B23, 5375 (1981)CrossRefGoogle Scholar
  40. 4u.
    n. Piacentini, F.S. Khumalo, C.G. Olson, J.R. Anderegg, D.H. Lynch: Chem. Phys. 65, 289 (1982)CrossRefGoogle Scholar
  41. 41.
    Piacentini, F.S. Khumalo, G. Levêque, C.G. Olson, D.W. Lynch: Chem. Phys. 72, 61 (1982)CrossRefGoogle Scholar
  42. 42.
    N. Piacentini, V. Grasso, S. Santangelo, N. Fanfoni, 11. Modesti, A. Savoia: Solid State Comm. 51, 467 (1984)CrossRefGoogle Scholar
  43. 43.
    H. Piacentini, V. iârasso, H. Fanfoni, S. Modesti, A. Savoia: Nuov. Cim. 4D, 444 (1984)Google Scholar
  44. 44.
    H. ‘Whangbo, R. Brec, G. Ouvrard, J. Rouxel: Inorg. Chem. 24, 2459 (1985)CrossRefGoogle Scholar
  45. 45.
    R. Grec. G. Ouvrard, A. Louisy, A. Le Méhauté, J. RouxëT: Solid State Ionics, 6, 185 (1982)CrossRefGoogle Scholar
  46. 46.
    N. Hanggo, T. Noguchi, S. Nakashima, A. Mitsuishi: 9nth Int. Conf. Raman Spect. ( ICORS) Tokyo (1984)Google Scholar
  47. 47.
    S. Yamanaka, H. Kobayashi, T. Tanaka: Chem. Lett. 329 (1976)Google Scholar
  48. 40.
    P.J.S. Foot, N.G. Shaker: Hat. Res. Bull. 18, 173 (1983)CrossRefGoogle Scholar
  49. 49.
    R. Schöllhorn, H.D. Zagefka: Angew. Chem. 37, 193 (1977)CrossRefGoogle Scholar
  50. 50.
    R. Schöllhorn, H.D. Zagefka: Angew. Chem. Tnt. Ed Eng. 16, 199 (1977)CrossRefGoogle Scholar
  51. 51.
    R. Clément, i1.L.H. Green: J. Chem. Soc. Dalton Trans. 10, 1566 (1979)Google Scholar
  52. 52.
    R. Clément: J. Chem. Soc. Chem. Corr. 647 (1980)Google Scholar
  53. 53.
    J.P. Audière, R. Clément, Y. Ilathey, C. Nazière: Physica 99B, 133 (1980)Google Scholar
  54. 54.
    R. Clément, U. Garnier, J. Jegoudez: Inorg. Chem. to be pa-Fished (1986)Google Scholar
  55. 55.
    A.H. Thompson, H.S. Whittingham: Hat. Res. Bull. 12, 741 (1977)CrossRefGoogle Scholar
  56. 56.
    A. Le riéhauté, G. Ouvrard, R. Brec, J. Rouxel: Mat. Res. Bull. 12, 1191 (1977)CrossRefGoogle Scholar
  57. 57.
    il. Garj, C. Sourisseau, G. Ouvrard, R. Brec: Solid State Ionics 11, 179 (1983)CrossRefGoogle Scholar
  58. 58.
    A. Le Héhauté: C.R. Acad. Sci. 287C, 309 (1978)Google Scholar
  59. 59.
    A. Le Néhauté: Thesis, Nantes (77 3)Google Scholar
  60. 60.
    G.A. Fatseas, G. Ouvrard, 11.-H.Whangbo, R. Brec: Solid State Ionics, to be published (1986)Google Scholar
  61. 61.
    C. Berthier, Y. Chabre, M. Minier: Solid State Comm. 28, 327 (1978)CrossRefGoogle Scholar
  62. 62.
    G.A. Fatseas, M. Evain, G. Ouvrard, R. Brec, 11.-H. Viangbo: Phys. Rev. B to be published (1986)Google Scholar
  63. 63.
    Y. Chabre, G. Ouvrard, R. Brec: Solid State Ionics, to be published (1986)Google Scholar
  64. 64.
    A.H. Thompson, H.S. Whittingham: U.S. Patent 4, 049, 879 (1977)Google Scholar
  65. 65.
    R. Grec, A. Le Méhauté: Fr Patents 7, 704–518, 7, 704–519 (1977)Google Scholar
  66. 66.
    J. Rouxel, R. Grec: Ann. Rev. Mater. Sci. 16, 137 (1986)CrossRefGoogle Scholar
  67. 67.
    P. Grenouilleau, R. Grec, M. Evain, Rouxel: Rev. Chin. Hin. 20, 628 (1983)Google Scholar
  68. 68.
    k. Grec, P. Grenouilleau, M. Evain, J. Rouxel: Rev. Chin. Min. 20 295 (1983)Google Scholar
  69. 69.
    R. Grec, G. Ouvrard, H. Evain, P. Grenouilleau, J. Rouxel: J. Solid State Chem. 7, 174 (1983)Google Scholar
  70. 70.
    H. Evain, H. Queignec, R. Grec, J. Rouxel: J. Solid State Cheri. 56, 148 (1985)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1986

Authors and Affiliations

  • R. Brec
    • 1
  1. 1.Laboratoire de Chimie des SolidesNantes CedexFrance

Personalised recommendations