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Reactivity and Phase Transitions in Transition Metal Dichalcogenides Intercalation Chemistry

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Intercalation in Layered Materials

Part of the book series: NATO ASI Series ((NSSB,volume 148))

Abstract

When an intercalation compound forms, ions or molecules are accepted by a host lattice. This results primarily in geometrical effects directly manifested through lattice parameter variations. At the same time an electronic exchange takes place between host and guest species. In addition the intercalation reaction is a reversible one. It is possible to return to the initial state through appropriate electrical, chemical, or thermal actions. This means that no strong bonds have been created between guest and host, or broken in the host structure.

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Brec, R., Rouxel, J. (1986). Reactivity and Phase Transitions in Transition Metal Dichalcogenides Intercalation Chemistry. In: Dresselhaus, M.S. (eds) Intercalation in Layered Materials. NATO ASI Series, vol 148. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5556-5_3

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  • DOI: https://doi.org/10.1007/978-1-4757-5556-5_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-5558-9

  • Online ISBN: 978-1-4757-5556-5

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