Reactivity and Phase Transitions in Transition Metal Dichalcogenides Intercalation Chemistry

  • R. Brec
  • J. Rouxel
Part of the NATO ASI Series book series (NSSB, volume 148)


When an intercalation compound forms, ions or molecules are accepted by a host lattice. This results primarily in geometrical effects directly manifested through lattice parameter variations. At the same time an electronic exchange takes place between host and guest species. In addition the intercalation reaction is a reversible one. It is possible to return to the initial state through appropriate electrical, chemical, or thermal actions. This means that no strong bonds have been created between guest and host, or broken in the host structure.


Alkali Metal Parameter Expansion Knight Shift Host Structure Intercalation Process 
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Copyright information

© Springer Science+Business Media New York 1986

Authors and Affiliations

  • R. Brec
    • 1
  • J. Rouxel
    • 1
  1. 1.Laboratoire de Chimie des SolidesNantes CedexFrance

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