Abstract
Serious and systematic studies of the kinetics of intercalation of graphite intercalation compounds (GIC’s) were first carried out by Hooley [1,2] who investigated the bromination of various forms of graphite in the early 1960’s. He found that the rate of intercalation was dependant on not only the intercalating species, but also on the microstructural morphology and macroscopic form of the graphitic host material. In addition, Hooley related the intercalation rate to the partial pressure of the vapor of the intercalating species and found a threshold pressure below which no intercalation occurred [1,2]. He also discovered that for pressures above the threshold pressure, there existed a dwell time which retarded the onset of intercalation.
Keywords
- Highly Orient Pyrolytic Graphite
- Threshold Pressure
- Domain Formation
- Incommensurate Phase
- Graphite Intercalation Compound
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References
J.G. Hooley: Canad. J. Chem. 40, 749 (1962)
J.G. Hooley: Carbon 11, 225 (1973)
M.B. Dowell and D.S. Badorrek: Carbon 16, 241 (1978)
M.H. Jacobs: Diffusion Processes ( Springer, New York, 1967 )
J.G. Hooley and J.L. Smee: Carbon 2, 135 (1964)
N. Daumas and A. Hérold: C.R. Acad. Sci., Ser. C 268, 273 (1969)
H. Miyazaki and C. Horie: Syn. Met. 12, 149 (1985)
S.A. Safran: Phys. Rev. Lett. 46, 1581 (1981)
P. Hawrylak and K.R. Subasswamy: Phys. Rev. Lett. 53, 2098 (1984)
G. Kirczenow: Phys. Rev. Lett. 52, 437 (1984)
G. Kirczenow: to be published
S. Miyazima: Syn. Met. 12, 155 (1985)
H. Homma and R. Clarke: Phys. Rev. Lett. 52, 629 (1984)
M.E. Misenheimer and H. Zabel: Phys. Rev. B27, 1443 (1983)
R. Nishitani, Y. Uno, and H. Suematsu: Phys. Rev. B27, 6572 (1983)
Y.Y. Huang, D.R. Stump, S.A. Solin, and J. Heremans: to be published
B. Sundquist and J.E. Fischer: to be published
S.A. Solin: Adv. Chem. Phys. 49, 455 (1982)
R. Clarke, N. Wada, and S.A. Solin: Phys. Rev. Lett. 44, 1616 (1980)
R. Clarke and C. Uher: Adv. Phys. 33, 469 (1984)
M.J. Winokur and R. Clarke: Phys. Rev. Lett. 54, 811 (1985)
H. Homma and R. Clarke: Phys. Rev. B31, 5865 (1985)
I.M. Lifshitz: Zh. Eksp. Teor. Fiz 42, 1354 (1962) [Soy. Phys. JETP 15, 939 (1962)]
P.K. Wu, J.H. Perepezko, J.T. McKinney, and M.G. Lagally: Phys. Rev. Lett. 51, 1577 (1984)
P.S. Salmi, G.S. Grest, M.P. Anderson, and D.J. Srolovitz: Phys. Rev. Lett. 50, 263 (1983)
P.S. Sahni, G.S. Grest, M.P. Anderson, D.J. Srolovitz, and S.A. Safran: Phys. Rev. B28, 2693 (1983)
S.A. Safran and D. Hamann: Phys. Rev. B22, 606 (1980)
M.E. Misenheimer and H. Zabel, Phys. Rev. Lett. 54. 1271 (1985)
B.R. York and S.A. Solin: Phys. Rev. B31, 8206 (1985)
X.W. Qian, D.R. Stump, B.R. York, and S.A. Solin: Phys. Rev. Lett. 54. 1271 (1985)
H. Zabel, A. Magerl, A.J. Dianoux, and J.J. Rush: Phys. Rev. Lett. 50, 49 (1983)
C.P. Slichter: Principles of Magnetic Resonance ( Springer, Berlin, 1978 )
G.C. Chingas, J. Milliken, H.A. Resing, and T. Tsang: Syn. Metals 12, 131 (1985)
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Solin, S.A. (1986). Kinetics and Diffusion in Graphite Intercalation Compounds. In: Dresselhaus, M.S. (eds) Intercalation in Layered Materials. NATO ASI Series, vol 148. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5556-5_14
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DOI: https://doi.org/10.1007/978-1-4757-5556-5_14
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