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Alkali Metal Intercalation-Deintercalation Reactions in 2D Oxides

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Intercalation in Layered Materials

Part of the book series: NATO ASI Series ((NSSB,volume 148))

Abstract

While much work has been devoted to intercalation reactions in graphite, transition metal dichalcogenides (TMDC) and clays, only a few studies have been reported on AxMO2 layer oxides (A : alkali ion, M : transition element x < 1)1,2,3. Stoichiometric AMO2 oxides have been mainly studied from a crystal chemistry point of view4,5. Although AxMO2 layer oxides show close likeness with intercalated TMDC they cannot exist in the unintercalated form. This property comes from the large electronegativity difference between the oxygen and the M element.

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References

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Author information

Authors and Affiliations

  1. Laboratoire de Chimie du Solide du CNRS, Université de Bordeaux I, 351, cours de la Libération, 33405, Talence Cedex, France

    Claude Delmas

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  1. Claude Delmas
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Editors and Affiliations

  1. Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

    M. S. Dresselhaus

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© 1986 Springer Science+Business Media New York

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Delmas, C. (1986). Alkali Metal Intercalation-Deintercalation Reactions in 2D Oxides. In: Dresselhaus, M.S. (eds) Intercalation in Layered Materials. NATO ASI Series, vol 148. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5556-5_10

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  • DOI: https://doi.org/10.1007/978-1-4757-5556-5_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-5558-9

  • Online ISBN: 978-1-4757-5556-5

  • eBook Packages: Springer Book Archive

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