Kinetics of an Anhydride-Epoxy Polymerization as Determined by Differential Scanning Calorimetry

  • Paul Peyser
  • W. D. Bascom


The use of differential scanning calorimetry (DSC) to study the thermal behavior of polymers has developed to the point where it is now used to establish the kinetics of polymer phase transformations, including polymerization reactions. We will describe the use of DSC to determine the polymerization kinetics of the anhydride-epoxy system, bisphenol A diglycidyl ether (DGEBA)-”nadic” methyl anhydride (NMA). This polymerization reaction, catalyzed by benzyldimethyl amine (BDMA) is generally viewed as a very complex curing process but the data here were fitted to a two stage model utilizing a single reaction order of n=2 and (only) two activation energies. Namely, in dynamic scans, after the reaction had proceeded with an activation of about 15 kcal/mole for about 12% completion, the rate increased until completion but with a higher activation energy of about 38 kcal/mole. Such an increase in rate was verified qualitatively by an isothermal run. Other workers studying similar systems have reported the lower activation energy. However, scrutiny of their data indicates a similar increase in rate.


Differential Scanning Calorimetry Base Line Differential Scanning Calorimetry Data Polymerization Kinetic Fast Heating Rate 
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  1. 1.
    H. J. Borchardt and F. Daniels, J. Arno Chem. Soc. 79, 41 (1957).CrossRefGoogle Scholar
  2. 2.
    Joseph H. Flynn and Leo A. Wall, J. Research Natl. Bur. Standards 70A, 487 (1966).Google Scholar
  3. 3.
    William P. Brennan, Bernard Miller and John C. Whitwell, Ind. Eng. Chem. Fundam. 8, 314 (1969).CrossRefGoogle Scholar
  4. 4.
    H. M. Heuvel and K. C. J. B. Lind/ Anal. Chem. 42, 1044 (1970).CrossRefGoogle Scholar
  5. 5.
    R. A. Fava, Polymer (London) 9, 137 (1968).CrossRefGoogle Scholar
  6. 6.
    Yoshio Tanaka and Hiroshi Kakiuchi, J. Appl. Poly. Sci. 7, 1063 (1963).CrossRefGoogle Scholar
  7. 7.
    Yoshio Tanaka and Hiroshi Kakiuchi, J. Appl. Poly. Sci. 2, 3405 (1964).Google Scholar
  8. 8.
    R. Bruce Prime, “Analytical Calorimetry,” Vol. 2 (Eds. R. S. Porter and J. F. Johnson)in Plenum Press, New York, 1970, p. 201.CrossRefGoogle Scholar
  9. 9.
    V. M. Gorbatchev and V. A. Logvinenko, J. Ther; Anal. 4, 475 (1972).CrossRefGoogle Scholar
  10. 10.
    K. Horie, H. Hiura, M. Sawada, I. Mita, and H. Kambe, J. Poly. Sci. A-1, 8, 1357 (1970).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1974

Authors and Affiliations

  • Paul Peyser
    • 1
  • W. D. Bascom
    • 1
  1. 1.Naval Research LaboratoryUSA

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