Thermodynamics of Intermolecular Self-Association of Hydrogen Bonding Solutes by Titration Calorimetry

  • Earl M. Woolley
  • Noel S. Zaugg


The hydrogen bond has been the object of extensive interest in the past few decades. In particular, the study of dilute solutions of hydrogen bonding solutes has made possible an increased understanding of the nature of the hydrogen bond. The tendency of many such solutes to self-associate intermolecularly has permitted systematic investigations of the effects of solvents and substi-tuents on the strength of the self-association interaction, thereby contributing to the understanding of the theory of hydrogen bonding.


Benzoic Acid Thermodynamic Parameter Molar Enthalpy Polymer Model Apparent Relative Molar Enthalpy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    G.C. Pimentel and A.L. McClellan, “The Hydrogen Bond,” W.H. Freeman and Co., San Francisco-London, 1960.Google Scholar
  2. 2.
    E.J. King, “Acid-Base Equilibria,” Permagon, New York-London, 1965.Google Scholar
  3. 3.
    E.M. Woolley, J.G. Travers, B.P. Erno, and L.G. Hepler, J. Phys. Chem., 75, 3591 (1971).Google Scholar
  4. 4.
    E.M. Woolley and L.G. Hepler, J. Phys. Chem., 76, 3058 (1972).CrossRefGoogle Scholar
  5. 5.
    N.S. Zaugg, S.P. Steed, and E.M. Woolley, Thermochim. Acta, 3, 349 (1972).CrossRefGoogle Scholar
  6. 6.
    N.S. Zaugg, L.E. Trejo, and E.M. Woolley, Thermochim. Acta, 6, 293 (1973).CrossRefGoogle Scholar
  7. 7.
    E.M. Woolley and D.S. Rushforth, Can, J. Chem., 52 (1974), in press.Google Scholar
  8. 8.
    R.H. Stokes and C. Burfitt, J. Chem. Thermodynamics, 5, 623 (1973).CrossRefGoogle Scholar
  9. 9.
    R.H. Stokes and K.N. Marsh, Third International Conference on Chemical Thermodynamics, 5/5, Vienna, Austria (1973).Google Scholar
  10. 10.
    N.S. Zaugg, A.J. Kelley, and E.M. Woolley, in preparation.Google Scholar
  11. 11.
    E. Calvet and C. Paoli, Compt. Rend., 257, 3376 (1963).Google Scholar
  12. 12.
    C.C. Panichajakul and E.M. Woolley, in preparation.Google Scholar
  13. 13.
    N.S. Zaugg, N.W. Petty, E.A. Ballard, and E.M. Woolley, in preparation.Google Scholar
  14. 14.
    R.C. Graham, G.H. Henderson, E.M. Eyring, and E.M. Woolley, J. Chem. Eng. Data, 18, 277 (1973); at 15°C and 35°C in preparation.CrossRefGoogle Scholar
  15. 15.
    G. Olofsson and I. Wirbrant, Acta Chem. Scand., 25, 1408 (1971).CrossRefGoogle Scholar
  16. 16.
    J.H. Rytting, personal communication.Google Scholar
  17. 17.
    P.R. Stoesser and S.J. Gill, J. Phys. Chem., 71, 564 (1967).CrossRefGoogle Scholar
  18. 18.
    S.J. Gill and L. Noll, J. Phys. Chem., 76, 3065 (1972).CrossRefGoogle Scholar
  19. 19.
    R.H. Stokes, Aust. J. Chem., 20, 2087 (1967).CrossRefGoogle Scholar
  20. 20.
    G.C. Kresheck, J. Phys. Chem., 73, 2441 (1969).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1974

Authors and Affiliations

  • Earl M. Woolley
    • 1
  • Noel S. Zaugg
    • 1
  1. 1.Department of ChemistryBrigham Young UniversityProvoUSA

Personalised recommendations