Importance of Joint Knowledge of ΔH° and ΔS° Values for Interpreting Coordination Reactions in Solution

  • Guy Berthon

Abstract

In the study of proton ionization and complexing of amines with transition metal ions, the nature and properties of the bonds, and the influence of substituents are mostly discussed in terms only of the free energies (or stability constants) for the corresponding reactions (1)(2).

Keywords

Free Energy Coordination Reaction Reaction Enthalpy Proton Ionization Solvate Water Molecule 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Bibliography

  1. (1).
    Sillen, L.G.; Martell, A.E. Stability constants” Special publication n° 17, The Chemical Society, London (1964); Supplement n° 1, Special publication 25 (1971).Google Scholar
  2. (2).
    Perrin, D.D. “Dissociation constants of organic bases in aqueous solution” Butterworths, London (1965); Supplement (1972).Google Scholar
  3. (3).
    Paoletti, P. et al. J. Chem. Soc. (1961), 65, 1224; J. Phys. Chem. (1965), 69, 3759; Helv. Chim. Acta (1971), 54, 243; J. Chem. Soc. (1972), 736.Google Scholar
  4. (4).
    Christensen, J.J. et al. J. Phys. Chem. (1966), 70, 2003; (1968), 72, 1208; J. Chem. Soc., A (1969), 1212; Theraiochim. Acta (1972), 3, 219; 5, 35.CrossRefGoogle Scholar
  5. (5).
    Cabani, S.; Gianni, P. J. Chem. Soc. (1968), 547; Anal. Chem. (1972), 44, 253.Google Scholar
  6. (6).
    Williams, D.R. et al. J. Chem. Soc. (1968), 2965; (1970), 1550; (1972), 790.Google Scholar
  7. (7).
    Blais, M.J. , Enea, O.; Berthon, G. Thermochim. Acta (in press).Google Scholar
  8. (8).
    Dewar, M.J.S.; Grisdale, P.J. J. Amer. Chem. Soc. (1962), 84, 3548.CrossRefGoogle Scholar
  9. (9).
    Laidler, K.J. Trans. Farad. Soc. (1959), 55, 1725.CrossRefGoogle Scholar
  10. (10).
    Cabani, S.; Conti, G.; Lepori, L. Trans. Farad. Soc. (1971) 67, 1933.CrossRefGoogle Scholar
  11. (11).
    Berthon, G.; Enea, O. Thermochim. Acta (1973), 6, 57.CrossRefGoogle Scholar
  12. (12).
    Berthon, G.; Luca, C. Bull. Soc. Chim. (1969), 2, 432.Google Scholar
  13. (13).
    Uusitalo, E. Ann. Acad. Sc. Fennicae (1967), 6, 47.Google Scholar
  14. (14).
    Enea, O.; Berthon, G. Thermoch. Acta (1973), 6, 47.CrossRefGoogle Scholar
  15. (15).
    Ashcroft, S.F.; Mortimer, C.T. “Thermochemistry of transition metal complexes”, Academic Press, London (1970).Google Scholar
  16. (16).
    Christensen, J.J.; Izatt, R.M. “Handbook of metal ligand heats” M. Dekker, New-York (1970).Google Scholar
  17. (17).
    Enea, O.; Berthon, G. C.R. Acad. Sc., série C (1972), 274, 1968.Google Scholar
  18. (18).
    Enea, O.; Berthon, G.; Bokra, Y. Thermochim. Acta (1972), 4, 449.Google Scholar
  19. (19).
    Enea, O.; Houngbossa, K.; Berthon, G. Electrochim. Acta (1972), 17, 1585.CrossRefGoogle Scholar
  20. (20).
    Berthon, G.; Enea, O.; Houngbossa, K. C.R. Acad. Sc., sériec (1972), 273, 1140.Google Scholar
  21. (21).
    Houngbossa, K.; Berthon, G.; Enea, O. Thermochim. Acta (1973), 6, 215.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1974

Authors and Affiliations

  • Guy Berthon
    • 1
  1. 1.Laboratoire de Thermodynamique chimique et ElectrochimiePoitiersFrance

Personalised recommendations