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Examples of Reactions Catalysed by Acids and Bases

  • Chapter
The Proton in Chemistry

Abstract

Any comprehensive account of reactions catalysed by acids and bases would cover a large proportion of organic chemistry and biochemistry, and would demand at least a whole book; in fact, two excellent books giving a general coverage of the subject have recently appeared.1,2 This chapter will be devoted to a fairly detailed consideration of a small number of reactions, chosen so as to illustrate the variety of kinetic behaviour forecast by the general treatment in the last chapter. They will also show in small measure the variety of chemical change which can result from the removal or addition of a proton. Some of the work described involves a study of series of acidic or basic catalysts, and some mention will be made of the relation of catalytic activity to acid-base strength, though a full treatment of this topic will be deferred until Chapter 10. Similarly, hydrogen isotope effects will be mentioned when they throw light on the mechanism of the reaction, but will not be considered quantitatively until Chapter 12.

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    R. P. Bell (Professor of Chemistry)

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Bell, R.P. (1973). Examples of Reactions Catalysed by Acids and Bases. In: The Proton in Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1592-7_9

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