Abstract
The hydrogenation of various diene homopolymers and copolymers prepared with lanthanide coordination catalysts was investigated. The lanthanide-initiated polydienes which have been studied include: cis-1,4 polybutadiene, cis-1,4 polyisoprene, random and block cis-1,4 copolymers of butadiene and isoprene, cis-1,4 poly(2,3-dimethyl butadiene), and trans-1,4-poly(2,4-hexadiene). The hydrogenated products were characterized by 13C-NMR and infrared spectroscopy, melting temperature, glass transition temperature (Rheovibron), thermogravimetric analysis, density, intrinsic viscosity and gel permeation chromatography. The physical and mechanical properties of these hydrogenated polymers as well as the relationships between polymer structures and polymer properties are discussed.
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References
C. W. Moberly, in Encyclopedia of Polymer Science and Technology, Interscience Publ., N.Y. 1964, Vol 7, p. 557.
R. V. Jones, C. W. Moberly, and W. B. Reynolds, Ind. Eng. Chem., 45, 1117 (1953).
L. A. Mango and R. W. Lenz, Makromol. Chem., 163 13 (1973).
H. J. Harwood, D. B. Russell, J. A. Verthe, and J. Zymonas, Makromol. Chem., 163 1 (1973).
Y. Mahajer, G. L. Wilkes, I. C. Wang, and J. E. McGrath, Polymer Prep. Am. Chem. Soc., 22 (2), 138 (1981).
J. C. Falk and R. J. Schlott, Angew. Makromol. Chem., 21, 17 (1972).
Y. Mohajer, G. L. Wilkes, I. C. Wang, and J. E. McGrath, Polymer, 23, 1523 (1982).
W. P. Gergen, Kautsch. Gummi Kunstst., 37, 284 (1982).
H. C. Yeh, and H. L. Hsieh, Polymer Prepr. Am. Chem. Soc., 25 (2), 52 (1984).
H. L. Hsieh and H. C. Yeh, Rubber Chem. Technol., 58 (1), 117 (1985).
H. Rachapudy, G. G. Smith, V. R. Raju, and W. W. Graessley, J. Polym. Sci., Polym. Phys. Ed., 17, 1211 (1979).
M. Moller and H.-J. Cantow, Macromolecules, 17, 733 (1984).
Y. Tanaka, H. Sato, and A. Ogura, J. Polym. Sci. Polym. Chem., 14, 73 (1976).
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© 1986 Springer Science+Business Media New York
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Hsieh, H.L., Yeh, H.C. (1986). Polymers from Hydrogenated Polydienes Prepared with Neodymium Catalysts. In: Lal, J., Mark, J.E. (eds) Advances in Elastomers and Rubber Elasticity. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1436-4_12
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DOI: https://doi.org/10.1007/978-1-4757-1436-4_12
Publisher Name: Springer, Boston, MA
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