Abstract
The isotropic exchange interaction 2JSi Sjbetween a pair of spins i and j has several consequences as it forms the dominant “glue” of interaction which makes the system of 1022 or so spins a strongly coupled one rather than a collection of independent paramagnetic particles. One may roughly divide the effects of J into static and dynamic ones, as can be seen from a simple consideration of two spins only, each with S =1/2 For antiferromagnetic coupling (J > 0 in our notation) the antiparallel (singlet) arrangement is lower in energy than the parallel (triplet) alignment by an amount 2J(1/4) − 2J(-3/4) = 2J. As a consequence the spins will tend to align antiparallel at a sufficiently low temperature T ~ 2J/kB. This effect is the root of static properties such as the magnetic susceptibility which will be discussed by Professor Gerstein in subsequent lectures.
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Richards, P.M. (1975). Consequences of Exchange in Low-Dimensional Compounds: High Temperature Spin Dynamics as Sampled by Magnetic Resonance. In: Keller, H.J. (eds) Low-Dimensional Cooperative Phenomena. Nato Advanced Study Institutes Series, vol 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1399-2_8
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