Introductory Notes to Electron Spin Resonance Absorption Spectroscopy

  • S. A. Marshall
Part of the Optical Physics and Engineering book series (OPEG)

Abstract

Electron spin resonance (ESR) absorption spectroscopy is that branch of radio-frequency spectroscopy which deals with the lowest-lying terms of systems having some degree of electronic angular momentum. This momentum may originate from the intrinsic spin, orbital motion, or both, of electrons. In either case, terms possessing angular momentum must necessarily be degenerate [1], and it is the removal of this degeneracy that forms the basis for ESR spectroscopy. Examples of systems having this ground-term degeneracy are: (1) most free atoms; (2) free-radical molecules and molecule-ions; (3) ions of the three transition series as well as those of the lanthanide and actinide series, the last two being characterized by partially filled inner electronic shells; (4) various species trapped in solids of which the alkali halide F-centers are examples; and finally, (5) conduction electrons.

Keywords

Angular Momentum Electron Spin Resonance Orbital Angular Momentum Energy Operator Ground Term 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    J. H. Van Vleck, The Theory of Electric and Magnetic Susceptibilities, Oxford University Press (London and New York), 1932.Google Scholar
  2. 2.
    G. Herzberg, Atomic Spectra and Atomic Structure, Dover Publications (New York), 1944.Google Scholar
  3. 3.
    G. Breit and I. I. Rabi, Phys. Rev. 38: 2082 (1931).ADSCrossRefGoogle Scholar
  4. 4.
    A. G. Prodell and P. Kusch, Phys. Rev. 88: 184 (1952).ADSCrossRefGoogle Scholar
  5. 5.
    S. H. Koenig, A. G. Prodell, and P. Kusch, Phys. Rev. 88: 191 (1952).ADSCrossRefGoogle Scholar
  6. 6.
    P. Kusch, Phys. Rev. 100: 1188 (1955).ADSCrossRefGoogle Scholar
  7. 7.
    R. Beringer and M. A. Heald, Phys. Rev. 95: 1474 (1954).ADSCrossRefGoogle Scholar
  8. 8.
    P. Franken and S. Liebes, Phys. Rev. 104: 1197 (1956).ADSCrossRefGoogle Scholar
  9. 9.
    J. Schwinger, Phys. Rev. 73: 416 (1948).MathSciNetADSMATHCrossRefGoogle Scholar
  10. 10.
    J. Schwinger, Phys. Rev. 76: 790 (1949).MathSciNetADSMATHCrossRefGoogle Scholar
  11. 11.
    E. Fermi, Z. Physik 60: 320 (1930).ADSMATHCrossRefGoogle Scholar
  12. 12.
    E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra, Cambridge University Press (London and New York), 1953.Google Scholar
  13. 13.
    E. B. Rawson and R. Beringer, Phys. Rev. 88: 677 (1952).ADSCrossRefGoogle Scholar
  14. 14.
    A. Abragam and J. H. Van Vleck, Phys. Rev. 92: 1448 (1953).ADSCrossRefGoogle Scholar
  15. 15.
    S. Krongelb and M. W. P. Stransberg, J. Chem. Phys. 31: 1196 (1959).ADSCrossRefGoogle Scholar
  16. 16.
    H. A. Bethe, Ann. Physik 3 (5): 133 (1929).ADSMATHCrossRefGoogle Scholar
  17. 17.
    L. E. Orgel, Introduction to Transition Metal Chemistry, John Wiley and Sons, Inc. (New York and London), 1960.Google Scholar
  18. 18.
    T. M. MacRobert, Spherical Harmonics and Elementary Treatise on Harmonic Functions with Applications, second edition, Methuen and Co, Ltd. ( London ), 1947.Google Scholar
  19. 19.
    A. Unsóld, Ann. Physik 82: 355 (1927).CrossRefGoogle Scholar
  20. 20.
    C. Kittel and J. M. Luttinger, Phys. Rev. 73: 162 (1948).ADSCrossRefGoogle Scholar
  21. 21.
    E. P. Wigner, Group Theory and Its Application to the Quantum Mechanics of Atomic Spectra, Academic Press (New York and London), 1959.Google Scholar
  22. 22.
    M. Hamermesh, Group Theory and Its Application to Physical Problems„ Addison-Wesley Publishing Company ( Reading, Massachusetts ), 1962.Google Scholar
  23. 23.
    B. Bleaney and K. W. H. Stevens, Rept. Progr. Phys. 16: 180 (1953).CrossRefGoogle Scholar
  24. 24.
    K. D. Bowers and J. Owens, Rept. Progr. Phys. 18: 304 (1955).ADSCrossRefGoogle Scholar
  25. 25.
    M. H. L. Pryce, Proc. Phys. Soc. A 63: 25 (1950).MATHGoogle Scholar
  26. 26.
    A. Abragam and M. H. L. Pryce, Proc. Roy. Soc. A 205: 135 (1951).Google Scholar
  27. 27.
    J. H. Van Vleck and W. G. Penney, Phil. Mag. 19: 961 (1934).Google Scholar
  28. 28.
    M. H. L. Pryce, Phys. Rev. 80: 1107 (1950).ADSCrossRefGoogle Scholar
  29. 29.
    H. Watanabe, Progr. Theoret. Phys. (Kyoto) 18: 405 (1957).ADSCrossRefGoogle Scholar
  30. 30.
    M. J. D. Powell, J. R. Gabriel, and D. P. Johnston, Phys. Rev. Letters 5: 145 (1960).ADSCrossRefGoogle Scholar
  31. 31.
    C. Eckart, Rev. Mod. Phys. 2: 305 (1930).ADSMATHCrossRefGoogle Scholar
  32. 32.
    K. W. H. Stevens, Proc. Phys. Soc. A 65: 209 (1952).MATHCrossRefGoogle Scholar
  33. 33.
    B. R. Judd, Proc. Roy. Soc. A 227: 552 (1955).ADSCrossRefGoogle Scholar
  34. 34.
    G. Racah, Phys. Rev. 62: 438 (1942).ADSCrossRefGoogle Scholar
  35. 35.
    H. A. Kramers, Proc. Amsterdam Acad. Sci. 33: 959 (1930).MATHGoogle Scholar
  36. 36.
    A. S. Davydov, Quantum Mechanics, Pergamon Press (London and New York), 1965.Google Scholar
  37. 37.
    M. A. Preston, Physics of the Nucleus, Addison-Wesley Publishing Company ( Reading, Massachusetts ), 1962.Google Scholar
  38. 38.
    C. Kikuchi, AFOSR TM 59–220 (1959).Google Scholar
  39. 39.
    D. J. E. Ingram, Spectroscopy at Radio and Microwave Frequencies, Butterworth Scientific Publications (London), 1955.Google Scholar
  40. 40.
    W. Low, Paramagnetic Resonance in Solids, Academic Press (New York and London), 1960.Google Scholar
  41. 41.
    G. E. Pake, Paramagnetic Resonance, W. A. Benjamin, Inc. (New York), 1962.Google Scholar
  42. 42.
    J. S. Griffith, The Theory of Transition-Metal Ions, Cambridge University Press (London and New York), 1961.Google Scholar
  43. 43.
    W. Low, “Paramagnetic Resonance,” Proceedings of the First International Conference, Jerusalem, Vols. I and II, Academic Press (New York and London), 1963.Google Scholar
  44. 44.
    W. Low and E. L. Offenbacher, Solid State Physics, Advances in Research and Application, Vol. 17, F. Seitz and D. Turnbull (eds. ), Academic Press (New York and London ), 1965.Google Scholar

Copyright information

© Springer Science+Business Media New York 1969

Authors and Affiliations

  • S. A. Marshall
    • 1
  1. 1.Argonne National LaboratoryArgonneUSA

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