Microemulsions pp 233-255 | Cite as

Ultrasonic Relaxation Studies of Microemulsions

  • J. Lang
  • A. Djavanbakht
  • R. Zana

Abstract

The main purpose of the ultrasonic absorption studies of micro-emulsions reported in this paper, as well as in a previous one(1) (referred to as Part I in the following) was to reach a better understanding of the dynamic properties of microemulsions. Indeed, it has been put forward(2) that these properties may play an important role in determining the stability of microemulsions.

Keywords

Relaxation Process Representative Point Relaxation Frequency Relaxation Spectrum Interfacial Film 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J. Lang, A. Djavanbakht and R. Tana, J. Phys. Chem., 84, 1541 (1980).Google Scholar
  2. 2.
    A. Skoulios and D. Guillon, J. Phys. Lett., 38, L-137 (1977).Google Scholar
  3. 3.
    M. Dvolaitzky. M. Guyot, M. Lagu@s, J.-P. Le Pesant, R. Ober, C. Sauterey and C. Taupin, J. Chem. Phys., 69, 3279 (1978).Google Scholar
  4. 4.
    M. LaguAs, R. Ober and C. Taupin, J. Phys. Lett., 39, L-437 (1978).Google Scholar
  5. 5.
    S. Yiv and R. Zana, J. Colloid Interface Sci., 65, 286, (1978); S. Yiv, R. Zana, W. Ulbricht and H. Hoffmann, J. Colloid Interface Sci., 80, 224 (1981).Google Scholar
  6. 6.
    A..Djavanbakht, J. Lang and R. Zana, J. Phys. Chem., 81, 2620 and 2630, (1977).Google Scholar
  7. 7.
    M. Dinh-Cao and J. Lang, to be publishedGoogle Scholar
  8. 8.
    M. Fixman, J. Chem. Phys., 36, 1961, (1962).Google Scholar
  9. 9.
    M. Breazeale, J. Chem. Phys., 36, 2530, (1962); E. Bains and M. Breazeale, J. Chem. Phys., 61, 1238 (1974); Ibid., 62, 742 (1975).Google Scholar
  10. 10.
    A. Anantaraman, A. Walters, P. Edmonds and C. Pings, J. Chem. Phys., 44, 2651 (1966).Google Scholar
  11. 11.
    G. D’Arrigo and D. Sette, J. Chem. Phys., 48, 691 (1968).Google Scholar
  12. 12.
    E. Graber, J. Lang and R. Zana, Kolloid Z.Z. Polym., 237, 470 (1970).Google Scholar
  13. 13.
    E. Aniansson, S. Wall, M. Almgren, H. Hoffmann, I. Kielmann, W. Ulbricht, R. Zana, J. Lang and C. Tondre, J. Phys. Chem., 80, 905 (1976).Google Scholar
  14. 14.
    M. J. Blandamer, N. Hidden, M. Symons and N. Treloar, Trans. Faraday Soc., 64, 3242 (1968).Google Scholar
  15. 15.
    K. Tamura, M. Maekawa and T. Yasunaga, J. Phys. Chem., 81, 2122 (1977).Google Scholar
  16. 16.
    S. Nishikawa, M. Mashima and T. Yasunaga, Bull. Chem. Soc. Jap. 50,3047 (1977) and references therein.Google Scholar
  17. 17.
    A. Graciaa, J. Lachaise, A. Martinez, M. Bourrel and C. Chambu C. R. Hebd. Sean. Acad. Sci., B 282, 547 (1976).Google Scholar
  18. 18.
    G. Goset, Ph.D. Thesis, Université de Pau et des Pays de l’Adour, Académie de Bordeaux, (1978).Google Scholar
  19. 19.
    M. Eigen and L. De Maeyer “Investigation of Rates and Mechanisms of Reactions” in “Technique of Organic Chemistry” S. Friess,E. Lewis, A. Weissberger, Ed., Interscience: New York, 1959, vol. VIII, Part I I.Google Scholar
  20. 20.
    K. Hayase and S. Hayano, Bull. Chem. Soc. Jap., 50 83 (1977); N. Singh and S. Swarup, Bull. Chem. Soc. Jap., 51 1534 (1978).Google Scholar
  21. 21.
    A. M. Cazabat, D. Langevin and A. Pouchelon, J. Colloid Interface Sci., 73, 1 (1980), and references therein.Google Scholar
  22. 22.
    This volume change is assumed to be equal to that for the exchange of the surfactant between the micelles and the bulk solution in micellar solutions.Google Scholar
  23. 23.
    J. Corkill, J. Goodman and T. Walker, Trans. Faraday Soc., 63, 768 (1967); S. Kaneshima, M. Tanaka, T. Tomida and R. Matuura, J. Colloid Interface Sci., 48, 450 (1974).Google Scholar
  24. 24.
    E. A. G. Aniansson and S. Wall, J. Phys. Chem., 79, 857 (1975).Google Scholar
  25. 25.
    E. A. G. Aniansson, “Techniques and Applications of Fast Reactions in Solutions”, W. J. Gettins and E. Wyn-Jones Ed.,D. Reidel Publ. Co., 1979, p. 249.CrossRefGoogle Scholar
  26. 26.
    The number of surfactant molecules per microemulsion droplet is always much larger than that of pure surfactant micelles. See for instance ref. 3.Google Scholar
  27. 27.
    A. Bellocq and G. Fourche, J. Colloid Interface Sci., 78, 275 (1980)Google Scholar
  28. 28.
    L. E. Scriven, “Micellization, Solubilization and Microemulsions” K. L. Mittal Ed., Plenum Press, 1977, Vol. II, p. 877.Google Scholar
  29. 29.
    F. Larche, J. Rouriere, P. Delord, B. Brun and J. Dussossoy, J. Phys. Lett., 41, L-437 (1980).gaGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1982

Authors and Affiliations

  • J. Lang
    • 1
  • A. Djavanbakht
    • 1
  • R. Zana
    • 1
  1. 1.Centre de Recherches sur les MacromoleculesCNRSStrasbourg-CedexFrance

Personalised recommendations