Abstract
Now approaching its centenary, the Hall-Héroult electrolytic aluminum extraction cell1,2 still reigns supreme as the largest industrial application of molten salts. Although rivals are now reappearing,3 the most likely contender would merely involve a change from molten cryolite-alumina to a chloroaluminate, with a small reduction in temperature. Nevertheless, the rapid growth of molten salt technologies awaited the electrolytic separation of uranium from molten fluorides in the Manhattan project of the mid-1940s.
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References
P. Héroult, Fr. Pat. 175711 (April 23, 1886 ).
C. M. Hall, U.K. Pats. 5669, 5670 (April 2, 1889 ).
G. A. Wolstenholme, Chem. Ind. (London) 9, 383 (1975);
also N. E. Richards in Electrochemistry, the Past Thirty and the Next Thirty Years, Eds. H. Bloom and F. Gutmann, Plenum, New York (1977).
M. Galopin and J. S. Daniel, Electrodeposition Surf. Treat. 3. 1 (1975).
W. R. Grimes and S. Cantor, in The Chemistry of Fusion Technology, Ed. D. M. Gruen, Plenum, New York (1972).
G. Long, UKAEA, AERE Report M-1925 (1967).
D. A. J. Swinkels, in Advances in Molten Salt Chemistry, Vol. 1, Eds. J. Braunstein, G. Mamantov, and G. P. Smith, Plenum, New York (1971);
see also Extended Abstracts, 154th Meeting Electrochemical Society, Pittsburgh (1978).
K. V. Kordesch, J. Electrochem. Soc. 125, 77C (1978).
M. R. Edwards and D. G. Lovering, Int. Metals Rev., 123 (1976).
D. Inman and D. E. Williams, in Electrochemistry, the Past Thirty and the Next Thirty Years, Eds. H. Bloom and F. Gutmann, Plenum, New York (1977).
W. Sundermeyer, Angew. Chem. (Int. Ed.) 4, 222 (1965).
D. H. Kerridge, M.T.P. Int. Rec. Sci. Inorg. Chem. Series One, Vol. 2, Butterworths, New York (1972).
B. W. Hatt and W. D. Read, paper presented at a meeting of the Molten Salt Discussion Group, Southampton University (April 1978).
B. W. Hatt and M. J. Pitt, paper presented at a meeting of the Molten Salt Discussion Group, Southampton University (April 1978).
A. Bonomi, M. Lavaidy, and C. Gentaz, paper presented at EUCHEM Molten Salt Meeting, Noordwijkerhout, Holland (1976).
K. E. Johnson, in Metal-Slag-Gas Reactions and Processes, Eds. Z. A. Foroulis and W. W. Smeltzer, Electrochemical Society, New Jersey (1975), p. 581.
R. Battino and H. L. Clever, Chem. Rev. 66, 395 (1966).
M. S. Hull and A. G. Turnbull, J. Phys. Chem. 74, 1783 (1970).
E. R. Buckle and R. R. Finbow, Int. Metals Rec., 197 (1976).
J. Braunstein, Inorg. Chini. Acta. Rev. 2, 19 (1968).
W. J. Burkhard and J. D. Corbett, U.S. Atom Energy Comm. Report ISC-929 (1957);
W. J. Burkhard and J. D. Corbett, J. Am. Chem. Soc. 79, 6361 (1957).
F. Colom and A. Bodalo, Collect. Caech. Chem. Commun. 36, 674 (1971).
F. Colom and A. Bodalo, Corros. Sci. 12, 731 (1972).
Kubaschewski and B. E. Hopkins, Oxidation of Metals and Alloys, Butterworths, London (1953).
S. Cantor and W. R. Grimes, Nucl. Tech. 22, 120 (1974).
D. R. Holmes and G. M. W. Mann, Corrosion 21, 370 (1965).
D. Lewis, D. G. Lovering, and B. Svensson, AB Atomenergi Report AE-RKK-381 (1969).
D. G. Lovering, Final Contract Report to NRDC/Rolls-Royce Ltd. (1970), and Extended Abstracts 23rd I.S.E. Meeting, Stockholm (1972), p. 103.
A. J. Arvia, R. C. V. Piatti, and J. J. Podesta, Electrochim. Acta 17, 889 (1972).
A. J. Arvia, R. C. V. Piatti, and J. J. Podesta, Electrochim. Acta 16, 1797 (1971);
A. J. Arvia, R. C. V. Piatti, and J. J. Podesta, Electrochim. Acta 17, 901 (1972).
E. L. Krongauz, V. D. Kascheev, and V. B. Busse-Machukas, Soc. Electrochem. 8. 1219 (1972).
A. K. Turner, Ph.D. thesis, London (1978).
Encyclopaedia of Electrochemistry of the Elements,Vol X, Fused Salt Systems,by J. A. Plambeck, Series Ed. A. J. Bard, Marcel Dekker, New York (1976).
R. C. Howie and D. W. MacMillan J. Appl. Electrochem. 2, 217 (1972).
B. Nayak and M. M. Misra, J. Appl. Electrochem. 7, 45 (1977).
B. Nayak and M. M. Misra, J. Appl. Electrochem. 9, 699 (1979).
J. M. West, Electrodeposition and Corrosion Processes, VNR, London (1971).
K. Grjotheim, Can. Metall. Q. 11, 585 (1972).
W. E. Haupin, J. Electrochem. Soc. 107, 232 (1960).
J. K. Wright, Miner. Sci. Eng. 5, 119 (1973).
M. I. Brittan and R. R. Liebenberg, Trans. Inst. Min. Met. 80, C156, C262 (1971).
M. I. Brittan, J.S.A. Inst. Min. Met. 71, 87 (1970).
F. R. Duke, in Mechanisms of Inorganic Reactions, Advances in Chemistry Series No. 49, American Chemical Society, Washington, D.C. (1965), p. 220.
R. F. Bartholomew and H. M. Garfinkel, J. Inorg. Nucl. Chem. 31, 3655 (1969).
R. B. Temple and F. W. Thickett, Aust. J. Chem. 26, 667 (1973).
P. G. Zambonin, J. Electroanal. Chem. 32, App. 1 (1971).
H. S. Swofford and H. A. Laitinen, J. Electrochem. Soc. 110, 814 (1963).
T. E. Geckle, M.S. thesis, Pennsylvania State University (1964).
M. Peleg, J. Phys. Chem. 71, 4553 (1967).
G. J. Hills and P. D. Power, J. Polarog. Soc. 13, 71 (1967).
P. G. Zambonin, J. Electroanal. Chem. 24, 365 (1970).
M. Francini and S. Martini, Electrochim. Acta 13 851 (1968).
Yu. S. Lyalikov and R. M. Novik, Uch. Zap. Kishineusk. Gos. Unit. 27, 61 (1957).
P. G. Zambonin, F. Paniccia, and A. Bufo, J. Phys. Chem. 76, 422 (1972).
P. G. Zambonin, Anal. Chem. 43, 1571 (1971).
P. G. Zambonin, V. L. Cardetta, and G. Sio orile, J. Electroanal. Chem. 28, 237 (1970).
E. Desimoni, F. Paniccia, L. Sabbatini, and P. G. Zambonin, J. Appt. Electrochem. 6, 445 (1976).
E. Desimoni, F. Palmisano, and P. G. Zambonin, J. Electroanal. Chem. 84, 323 (1977).
E. Desimoni, F. Paniccia, and P. G. Zambonin, J. Chem. Soc. Faraday Trans. 169, 2014 (1973).
E. Desimoni, F. Paniccia, and P. G. Zambonin, J. Phys. Chem. 81, 1985 (1977).
A. K. Turner, private communication.
R. N. Kust and J. D. Burke, Inorg. Nucl. Chem. Lett. 6, 333 (1970).
A. F. J. Goeting and J. A. A. Ketelaar, Electrochim. Acta 19, 267 (1974).
J. Jordan, W. B. McCarty, and P. G. Zambonin in Molten Salts, Characterization and Analysis, Ed. G. Mamantov, Marcel Dekker, New York (1969).
J. Jordan, J. Electroanal. Chem. 29, 127 (1971).
A. Espinola, Ph.D. thesis, Pennsylvania State University (1974).
A. Espinola and J. Jordan, Proceedings A.C.S. Meeting, San Francisco (August 1976).
D. C. Walker, Q. Rev. 21, 79 (1967).
E. J. Hart and M. Ambar, The Hydrated Electron, Wiley-Interscience, New York (1970).
C. A. Angell and C. T. Moynihan, in Molten Salts: Characterization and Analysis, Ed. G. Mamantov, Marcel Dekker, New York (1969).
H. S. Swofford, Ph.D. thesis, Illinois University, Urbana (1972).
N. Hittorf, Poggendorfs Ann. Phys. 72, 481 (1847).
H. E. Bartlett and K. E. Johnson, Can. J. Chem. 44, 2119 (1966).
H. E. Bartlett and K. E. Johnson, J. Electrochem. Soc. 114, 64 (1967).
D. G. Lovering, R. M. Oblath, and A. K. Turner, J. Chem. Soc. Chem. Commun., 673 (1976).
G. J. Hills and K. E. Johnson, Proceedings of the 2nd International Conference on Polarography, Cambridge, England, 1959, Pergamon, London (1961). p. 974.
D. H. Kerridge and J. D. Burke, J. Inorg. Nucl. Chem. 38, 1307 (1976).
R. Pineaux, C. R. Acad. Soc. Paris Ser. C. 267, 1449 (1968).
R. Pineaux, C. R. Acad. Sci. Paris Ser. C. 268, 788 (1969).
V. Sh. Palanker, A. M. Skundin, and V. S. Bagotskii, Elektrokhimiya 2, 640 (1966).
J. E. B. Randles and W. White, Z. Electrochemie 59, 666 (1955).
G. J. Hills and P. D. Power, Trans. Faraday Soc. 64, 1629 (1968).
H. A. Laitinen, W. S. Ferguson, and R. A. Osteryoung, J. Electrochem. Soc. 104, 516 (1957).
R. Combes, J. Vedel, and B. Tremillon, C. R. Acad. Sci. Ser. C. 273, 1740 (1971);
R. Combes, J. Vedel, and B. Tremillon, Electrochim. Acta 20, 191 (1975);
R. Lysy and R. Combes, J. Electroanal. Chem. 83, 287 (1977).
R. Combes, J. Vedel, and B. Tremillon, C. R. Acad. Sci. Ser. C. 275, 199 (1972).
J. Goret and B. Tremillon, Bull. Soc. Chim. France, 67 (1966).
J. Goret and B. Tremillon, Electrochim. Acta 12, 1065 (1967).
H. J. Kruger, A. Rahmel, and W. Schwenk, Electrochim. Acta 13, 625 (1968).
G. G. Bombi, S. Zecchin, and G. Schiavon, J. Electroanal. Chem. 50, 261 (1974).
J. Goret and B. Tremillon, Bull. Soc. Chim. France, 2872 (1966).
P. Claes, paper presented at EUCHEM Molten Salt Meeting, Lysekil, Sweden (June 1978).
R. Marassi, V. Bartocci, and F. Pucciarelli, Talanta 19, 203 (1972).
R. Marassi, V. Bartocci, F. Pucciarelli. and P. Cescon, J. Electroanal. Chem. 47, 509 (1973).
J. Dandoy and L. Gierst, J. Electroanal. Chem. 2, 116 (1961).
D. G.Lovering, Collect. Czech. Chem. Commun. 37, 3697 (1972).
D. G. Lovering and R. M. Oblath, J. Electrochern. Soc. 127, 1997 (1980).
D. G. Lovering, J. Electroanal. Chem. 50, 91 (1974).
R. M. Oblath, Ph.D. thesis, CNAA (1978).
D. G. Lovering and R. M. Oblath, in preparation.
D. G. Lovering, private communication to D. Inman (1977).
D. Inman and J. Braunstein, Chem. Commun. 148 (1966).
I. Uchida and H. A. Laitinen, J. Electrochem. Soc. 123, 829 (1976).
H. A. Laitinen, Y. Yamamura, and I. Uchida, J. Electrochem. Soc. 125, 1450 (1978).
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Lovering, D.G., Oblath, R.M. (1981). Water in Molten Salts: Industrial and Electrochemical Consequences. In: Inman, D., Lovering, D.G. (eds) Ionic Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0920-9_11
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DOI: https://doi.org/10.1007/978-1-4757-0920-9_11
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