Photochemical Processes Induced with Enzyme-Generated Triplet Species

  • Giuseppe Cilento
Part of the NATO Advanced Science Institutes Series book series (NSSA, volume 68)

Abstract

Light may act as an energy source and, as such, may drive biosynthetic processes. Light may also act as a signal producing regulatory responses. Regarding the first of these two broad roles, it is certainly intriguing that there are several photochemical-like transformations which occur “in vivo” under conditions in which light is not available1–3. As for the second, if the regulatory role is environmentally dependent, it is obvious that there is no substitute for light; however, as we shall see, some sort of control is still potentially possible in the dark. The key point is that electronic energy can also be generated chemically and biochemically and can be transferred in such a manner as to induce photoprocesses. Chemiluminescent reactions have been known and studied for a long time, as have bioluminescent processes. However, in these processes, the excited species is generated in the singlet state, whereas excited species in the triplet state are potentially much more useful due to their longer lifetimes4.

Keywords

Triplet State Indoleacetic Acid Rose Bengal Excited Species Biological Generation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1983

Authors and Affiliations

  • Giuseppe Cilento
    • 1
  1. 1.Department of BiochemistryInstituto de Química Universidade de São PauloSão PauloBrazil

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