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Electron Paramagnetic Resonance in Nitroxides and Nitroxyls

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Free Nitroxyl Radicals

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Abstract

All stable individual nitroxyls possess a very simple EPR spectrum similar to that of 2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl (see Fig. 12). However, as already mentioned, when the substance is dissolved in a suitable solvent, the singlet curve is transformed into a group of three lines with a separation between the components of about 15 G (see, for example, Fig. 13).

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Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow, USSR

    E. G. Rozantsev (Chief, Stable Radicals Laboratory)

  2. Donald S. Gilmore Research Laboratories, The Upjohn Company, North Haven, Connecticut, USA

    H. Ulrich (Manager, Chemical Research)

Authors
  1. E. G. Rozantsev
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  2. H. Ulrich
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Editor information

Editors and Affiliations

  1. Donald S. Gilmore Research Laboratories, The Upjohn Company, North Haven, Connecticut, USA

    H. Ulrich (Manager, Chemical Research) (Manager, Chemical Research)

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Rozantsev, E.G., Ulrich, H. (1970). Electron Paramagnetic Resonance in Nitroxides and Nitroxyls. In: Ulrich, H. (eds) Free Nitroxyl Radicals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0710-6_7

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  • DOI: https://doi.org/10.1007/978-1-4757-0710-6_7

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