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The Effect of Alcohol on Surfactant Mass Transfer Across the Oil/Brine Interface and Related Phenomena

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Surface Phenomena in Enhanced Oil Recovery

Abstract

The effect of alcohol on surfactant mass transfer from bulk solution to the oil/dilute micellar solution interface was studied. Various interfacial properties of the surfactant solutions and their ability for displacing oil were determined. For the surfactant-oil-brine systems studied, the interfacial tension (IFT) and surfactant partition coefficient did not change when isobutanol was added to the following systems: 0.1% TRS 10-410 in 1.5% NaCl vs. n-dodecane and 0.05% TRS 10—80 in 1.0% NaCl vs. n-octane. On the other hand, the interfacial viscosity, oil drop flattening time (i.e. the time required for an oil droplet to flatten out after being deposited on the underside of a polished quartz plate submerged in the micellar solution) and oil displacement efficiency were influenced markedly by the addition of alcohol.

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References

  1. L. W. Holm, J. Pet. Tech., 1475 (Dec. 1971).

    Google Scholar 

  2. J. J. Taber, Soc. Pet. Eng. J., 3 (March, 1969).

    Google Scholar 

  3. R. N. Healy and R. L. Reed, in “Improved Oil Recovery by Surfactant and Polymer Flooding,” Vol. I, D. O. Shah and R. S. Schechter, eds., Academic Press, N.Y., 383, 1977.

    Google Scholar 

  4. R. L. Cash, Jr., J. L. Cayias, M. Hayes, D. J. MacAllister, T. Schares, R. S. Schechter, and W. H. Wade, SPE 5562 presented at Fall SPE Meeting, Dallas, Texas, Sept. 28–Oct. 1, 1975.

    Google Scholar 

  5. S. O. Trushenski, D. L. Dauben, and D. R. Parrish, Soc. Pet. Eng. J., 633 (Dec. 1974).

    Google Scholar 

  6. G. L. Stegemeier, in “Improved Oil Recovery by Surfactant and Polymer Flooding,” Vol. I, D. O. Shah and R. S. Schechter, eds., Academic Press, N.Y., 1977.

    Google Scholar 

  7. W. W. Gale and E. I. Sandvik, Soc. Pet. Eng. J., 191 (Aug. 1973).

    Google Scholar 

  8. W. B. Gogarty and W. C. Tosch, J. Pet. Tech., 1407 (Dec. 1968).

    Google Scholar 

  9. S. C. Jones and K. D. Dreher, SPE 5566 presented at Fall SPE Meeting, Dallas, Texas, Sept. 28–Oct. 1, 1975.

    Google Scholar 

  10. W. R. Foster, J. Pet. Tech., 205 (Feb. 1973).

    Google Scholar 

  11. W. C. Hsieh and D. O. Shah, SPE 6594 presented at SPE International Symposium on Oilfield and Geothermal Chemistry, La Jolla, CA, June 27–28, 1977.

    Google Scholar 

  12. R. L. Cash, J. L. Cayias, R. G. Fournier, J. K. Jacobson, T. Schares, R. S. Schechter, and W. H. Wade, SPE 5813 presented at SPE Improved Oil Recovery Symposium, Tulsa, OK, March 22–24, 1976.

    Google Scholar 

  13. D. R. Anderson, M. S. Binder, H. T. Davis, C. D. Manning, and L. E. Scriven, SPE 5811 presented at SPE Improved Oil Recovery Symposium, Tulsa, OK, March 22–24, 1976.

    Google Scholar 

  14. D. T. Wasan and V. Mohan, in “Improved Oil Recovery by Surfactant and Polymer Flooding,” Vol. I, D. O. Shah and R. S. Schechter, eds., Academic Press, N.Y., 161, 1977.

    Google Scholar 

  15. K. S. Chan, Ph.D. Dissertation, University of Florida, Gainesville, FL, 1978.

    Google Scholar 

  16. D. T. Wasan, L. Gupta, and M. K. Vora, AIChE J., 17, 1287 (Nov. 1971).

    Article  CAS  Google Scholar 

  17. V. W. Reid, G. F. Longman, and E. Heinerth, Tenside, 4, 292 (1967).

    CAS  Google Scholar 

  18. D. O. Shah, A. Tamjeedi, J. W. Falco, and R. D. Walker, AIChE J., 18, 1116 (Nov. 1972).

    Article  CAS  Google Scholar 

  19. K. S. Chan and D. O. Shah, J. Disp. Sci. & Tech., 1(1), 55 (1980).

    Article  Google Scholar 

  20. R. Zana, in “Surface Phenomena In Enhanced Oil Recovery,” D. O. Shah, ed., Plenum Press, N.Y. (in press).

    Google Scholar 

  21. J. C. Melrose and C. F. Brandner, J. Canadian Petr. Tech., 58 (Oct.–Dec. 1974).

    Google Scholar 

  22. S. I. Chou and D. O. Shah, in “Surface Phenomena In Enhanced Oil Recovery,” D. O. Shah, ed., Plenum Press, N.Y. (in press).

    Google Scholar 

  23. K. S. Chan and D. O. Shah, SPE 7896 presented at SPE International Symposium on Oilfield and Geothermal Chemistry, Houston, TX, Jan. 22–24, 1979.

    Google Scholar 

  24. V. K. Bansal and D. O. Shah, J. Coll. Interface Sci., 65, 451 (1978).

    Article  CAS  Google Scholar 

  25. V. K. Bansal and D. O. Shah, Soc. Pet. Eng. J., 167 (June 1978).

    Google Scholar 

  26. V. K. Bansal and D. O. Shah, J. Am. Oil Chem. Soc, 55, No. 3, 367 (1978).

    Article  CAS  Google Scholar 

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© 1981 Springer Science+Business Media New York

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Chiang, M.Y., Shah, D.O. (1981). The Effect of Alcohol on Surfactant Mass Transfer Across the Oil/Brine Interface and Related Phenomena. In: Shah, D.O. (eds) Surface Phenomena in Enhanced Oil Recovery. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0337-5_25

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  • DOI: https://doi.org/10.1007/978-1-4757-0337-5_25

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0339-9

  • Online ISBN: 978-1-4757-0337-5

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