Skip to main content

Measurement of the Kinetics of Dissociation of Dicyclopentadiene Derivatives with the Differential Scanning Calorimeter

  • Conference paper
Book cover Analytical Calorimetry

Abstract

In the course of studies of potential thermally reversible crosslinking agents for cotton cellulose, it became necessary to develop a method of measuring the kinetic parameters for the dissociation of dimers of methyl cyclopentadienecarboxylate. It has previously been reported that tetracyanoethylene and N-phenylmaleimide are suitable trapping agents for the products of these dissociations (1). A method capable of measuring the kinetics of such reactions, both in solution and in the cellulose fiber matrix, was required. The use of the differential scanning calorimeter for measuring the kinetics of these reactions in solution is discussed here.

A laboratory of the Southern Utilization Research and Development Division, Agricultural Research Service, United States Department of Agricultural.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. W. E. Franklin, S. P. Rowland, and C. H. Mack, J. Org. Chenu, in press.

    Google Scholar 

  2. W. W. Wendlandt, “Thermal Methods of Analysis,” John Wiley & Sons, Inc., New York, 1964, p. 174.

    Google Scholar 

  3. R. L. Reed, L. Weber, and B. S. Gottfried, Ind. Eng. Chenu, Fundamentals, 4, 38 (1965).

    Article  CAS  Google Scholar 

  4. E. S. Watson, M. J. O’Neill, J. Justin, and N. Brenner, Anal. Chem., 36, 1233 (1964).

    Article  CAS  Google Scholar 

  5. C. H. Mack and S. R. Hobart, Applied Polymer Symposia, 2, 133 (1966).

    Google Scholar 

  6. R. N. Rogers and E. D. Morris, Anal. Chem., 38, 412 (1966).

    Article  CAS  Google Scholar 

  7. M. J. Uricheck, Instrument News (Perkin-Elmer Corp.), Vol. 17, No. 2 (1966).

    Google Scholar 

  8. C. H. Mack and D. J. Donaldson, Textile Res. J., in press.

    Google Scholar 

  9. S. M. Ellerstein, J. Phys. Chem., 69, 2471 (1965).

    Article  CAS  Google Scholar 

  10. S. M. Ellerstein, Applied Polymer Symposia, 2, 111 (1966).

    Google Scholar 

  11. K. Alder, F. H. Flock, A. Hausweiler, and R. Reeber, Ber., 87, 1752 (1954).

    Article  CAS  Google Scholar 

  12. J. Sauer, H. Wiest, and A. Mielert, Ber., 97, 3183 (1964).

    Article  CAS  Google Scholar 

  13. B. S. Khambata and A. Wasserman, J. Chem. Soc., 375 (1939).

    Google Scholar 

  14. W. C. Herndon, C. R. Grayson, and J. M. Manion, J. Org. Chem., 32, 526 (1967).

    Article  CAS  Google Scholar 

  15. R. C. Peterson, J. H. Markgraff, and S. D. Ross, J. Am. Chem. Soc., 83, 3819 (1961).

    Article  Google Scholar 

  16. R. M. Fuoss, I. O. Salyer, and H. S. Wilson, J. Polymer Sci., Part A, 2, 3147 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1968 Plenum Press

About this paper

Cite this paper

Franklin, W.E., Mack, C.H., Rowland, S.P. (1968). Measurement of the Kinetics of Dissociation of Dicyclopentadiene Derivatives with the Differential Scanning Calorimeter. In: Porter, R.S., Johnson, J.F. (eds) Analytical Calorimetry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0001-5_23

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-0001-5_23

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0003-9

  • Online ISBN: 978-1-4757-0001-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics