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Thermal Properties of Inorganic Polymer Systems

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Analytical Calorimetry

Abstract

The liquid structures of S and Se have been proposed (Ref. 1, 2, 3) to be equilibrium mixtures of linear polymer molecules and eight-membered monomer rings. The experimental phenomena observed in S which stimulated Gee’s (1) proposal and its formulation by Tobolsky and Eisenberg (Ref. 2, 3) were the temperature dependence of the viscosity and heat capacity in the region of 159°C and the solubility or lack of solubility of various forms of S in solvents such as CS2. Further, the structures of the highly molecular crystalline phases of S and Se have strongly influenced thought on the possible molecular forms in the liquid.

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References

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Author information

Authors and Affiliations

  1. Research Laboratories, Xerox Corporation, Rochester, New York, USA

    Mark B. Myers

Authors
  1. Mark B. Myers
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Editor information

Editors and Affiliations

  1. Polymer Science and Engineering Program, University of Massachusetts, Amherst, Massachusetts, USA

    Roger S. Porter (Head) (Head)

  2. Department of Chemistry, University of Connecticut, Storrs, Connecticut, USA

    Julian F. Johnson

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© 1968 Plenum Press

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Myers, M.B. (1968). Thermal Properties of Inorganic Polymer Systems. In: Porter, R.S., Johnson, J.F. (eds) Analytical Calorimetry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0001-5_17

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  • DOI: https://doi.org/10.1007/978-1-4757-0001-5_17

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0003-9

  • Online ISBN: 978-1-4757-0001-5

  • eBook Packages: Springer Book Archive

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