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Haloformamidines

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Book cover The Chemistry of Imidoyl Halides

Abstract

Haloformamidines are derivatives of formic acid; the name haloformamidines is used by Chemical Abstracts, which numbers the center carbon atom 1, and lists the nitrogens as N and N’. However, this class of compounds is more closely related to carbamic acid, as evidenced by its synthesis from urea (carbamic acid amide) and cyanamide (carbamic acid nitrile). In a recent article(15) concerned with the synthesis and reactions of substituted chloroformamidine hydrochlorides, the term carbamido chlorides was used. Since chloroformamidine hydrochlorides I are the amido chlorides of carbamide, this generic name is not unreasonable. There is no evidence for the isomeric geminate chloride structure II, and the polar character of I is evidenced by the relatively high melting points of chloroformamidine hydrochlorides, and by their insolubility in nonpolar solvents(15).

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  1. Donald S. Gilmore Research Laboratories, The Upjohn Company, North Haven, Connecticut, USA

    Henri Ulrich

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Ulrich, H. (1968). Haloformamidines. In: The Chemistry of Imidoyl Halides. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8947-7_4

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  • DOI: https://doi.org/10.1007/978-1-4684-8947-7_4

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