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Analysis of Steric Conditions by NMR. The Environment Around Phosphorus in Some of Its Esters

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Developments in Applied Spectroscopy

Part of the book series: Developments in Applied Spectroscopy ((DAIS,volume 5))

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Abstract

Tri-tert-butyl phosphite and its derivatives and the analogous ethyl esters were characterized by NMR spectroscopy. Tri-tert-butyl phosphite proper, unlike the derivatives, did not show consistent shielding of phosphorus. Hybrid structures between triethyl and tritert-butyl phosphite were synthesized and analyzed. Analysis of the data showed a quantitative relationship between chemical shift and composition. A decrease in bond angle of trivalent phosphorus results in greater shielding of the phosphorus nucleus, and an increase results in deshielding.

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Author information

Authors and Affiliations

  1. Hooker Chemical Corporation, Niagara Falls, New York, USA

    Victor Mark

Authors
  1. Victor Mark
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Editor information

Editors and Affiliations

  1. Research Center, American Can Company, Barrington, Illinois, USA

    L. R. Pearson

  2. Illinois Institute of Technology, Research Laboratories, Chicago, Illinois, USA

    E. L. Grove

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© 1966 Chicago Section of the Society for Applied Spectroscopy

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Mark, V. (1966). Analysis of Steric Conditions by NMR. The Environment Around Phosphorus in Some of Its Esters. In: Pearson, L.R., Grove, E.L. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 5. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8694-0_20

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  • DOI: https://doi.org/10.1007/978-1-4684-8694-0_20

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8696-4

  • Online ISBN: 978-1-4684-8694-0

  • eBook Packages: Springer Book Archive

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