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C14-Labeling Using Carbene Insertion—Application to Saturated Hydrocarbons

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Abstract

Although the use of radioactive-tracer techniques is often an excellent way to study chemical reactions, follow process streams, etc., less use is made of them than would be expected. This is due chiefly to difficulties in obtaining radioactive tracers in their proper chemical forms. Labeled compounds that can be purchased are generally expensive, are sometimes of questionable purity, and the time for delivery may be excessive.

Presented at the Seventh Symposium on Advances in Tracer Methodology, March, 1963.

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References

  1. Brown, H.C., and Brown, C.A., J. Am. Chem. Soc. 84: 1494, 1495, 2827 (1962).

    Article  Google Scholar 

  2. Brown, H. C., and Brown, C.A., J. Am. Chem. Soc. 84: 2829 (1962).

    Article  CAS  Google Scholar 

  3. Chinoporos; E., Chem. Rev. 63: 235 (1963).

    Article  CAS  Google Scholar 

  4. De Boer, T.H., and Backer, H. J., Rec. Tray. Chim. 73: 229 (1954).

    Article  Google Scholar 

  5. Doering, W. von E., Buttery, R. C., Laughlin, R. G., and Chaudhuri, N., J. Am. Chem. Soc. 78: 3224 (1956).

    Article  CAS  Google Scholar 

  6. Dvoretzky, I., Richardson, D. B., and Durrett, L. R., Anal. Chem. 35: 545 (1963).

    Article  CAS  Google Scholar 

  7. Farley, F. F., and Gordon, B. E., 1959 Fifth World Petroleum Congress, New York, Section X, Paper 5.

    Google Scholar 

  8. International Atomic Energy Agency, Symposium on the Chemical Effects of Nuclear Transformations, Vol. II, Prague, October 1960, pp. 3–145.

    Google Scholar 

  9. Kirmse, W., Angew. Chem. 73: 161 (1961).

    Article  CAS  Google Scholar 

  10. Lange, N. A., Handbook of Chemistry, 6th Ed., Handbook Publishers, Sandusky, Ohio (1946).

    Google Scholar 

  11. Lemmon, R.M., and Strohmeier, W., J. Am. Chem. Soc. 81: 106 (1959).

    Article  CAS  Google Scholar 

  12. Meerwein, H., Disselnkötter, H., Rappean, F., von Rinteln, H., and van de Vloed, H., Ann. Chem. 604: 151 (1957).

    Article  CAS  Google Scholar 

  13. Meerwein, H., Rathjen, H., and Werner, H., Chem. Ber. 75: 1610 (1942).

    Article  Google Scholar 

  14. Moyer, J. D., and Isbell, H.S., Anal. Chem. 29: 393 (1957).

    Article  CAS  Google Scholar 

  15. Richardson, D. B., Simmons, M. C., and Dvoretzky, I., J. Am. Chem. Soc. 83:1934 (1961)

    Article  CAS  Google Scholar 

  16. Sixma, F. L. J., Hendricks, H., Helle, K., Hollenstein, V., and van Ling, R., Rec. Tray. Chim. 73: 161 (1954).

    Article  CAS  Google Scholar 

  17. Stoll, A., Rutschman, J., von Wartburg, A., and Renz, J., Hely. Chim. Acta. 39: 993 (1956).

    Article  CAS  Google Scholar 

  18. Wilzbach, K. E., J. Am, Chem. Soc. 79: 1013 (1957).

    Article  CAS  Google Scholar 

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© 1965 New England Nuclear Corporation

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Muhs, M.A., Bastin, E.L., Gordon, B.E. (1965). C14-Labeling Using Carbene Insertion—Application to Saturated Hydrocarbons. In: Rothchild, S. (eds) Advances in Tracer Methodology. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8622-3_3

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  • DOI: https://doi.org/10.1007/978-1-4684-8622-3_3

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-8624-7

  • Online ISBN: 978-1-4684-8622-3

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