Abstract
The number of complexes covered by the title of this chapter is vast and the spectroscopic literature is too large to be covered comprehensively in the space of a single chapter. We have therefore attempted to outline the main approaches and reasoning in the applications of vibrational spectroscopy (section 6.1.3) and, in the rest of the chapter, to illustrate the use of these approaches with selected examples from the literature. The contents of this latter part of the chapter have been organised according to the chemical species involved rather than according to bonding type as this forms a more natural classification of the subject matter. Some subjects cross the boundaries of our headings, belonging to more specialised classifications in addition to, say, periodic group classifications. Where this occurs more detailed discussion is reserved for the special categories.
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References
R. S. Mulliken and W. B. Person, Molecular Complexes, ( Wiley-Interscience, New York, 1969 )
S. G. W. Ginn, J. K. Kenney and J. Overend, J. Chem. Phys., 48, 1571 (1968)
F. A. Cotton and J. R. Leto, J. Chem. Phys., 30, 993 (1959)
B. Swanson, D. F. Shriver and J. A. Ibers, Inorg. Chem., 8, 2182 (1969)
J. L. Hoard and S. Geller, Acta Crystallogr, 4, 399 (1951)
C. T. Mortimer, Reaction Heats and Bond Strengths, ( Pergamon Press, London, 1962 )
G. A. Olah, Friedel Crafts and Related Reactions, ( Interscience, New York, 1963 )
B. Swanson and D. F. Shriver, Inorg. Chem., 9, 1406 (1970)
D. F. Shriver and B. Swanson, Inorg. Chem., 10, 1354 (1971)
E. B. Wilson, J. C. Decius and P. C. Cross, Molecular Vibrations, ( McGraw-Hill, New York, 1955 )
I. M. Mills (Ed. M. M. Davies) Infrared Spectroscopy and Molecular Structure, ( Elsevier, Amsterdam, 1963 ), p 166
M. J. Ware (Eds. H. A. O. Hill and P. Day) Physical Methods in Advanced Inorganic Chemistry, ( Interscience, 1968 ), p 214
D. Steele, Theory of Vibrational Spectroscopy, (W. B. Saunders and Co., Philadelphia, 1971 )
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, ( Wiley-Interscience, New York, 1970 ), p 9
E. R. Lippincott, R. Schroeder and D. Steele, J. Chem. Phys., 34, 1448 (1961)
D. Steele and E. R. Lippincott, J. Chem. Phys., 35, 2065 (1961)
I. Lindquist, Inorganic Adduct Molecules of Oxo-Compounds, ( Springer-Verlag, Berlin, 1963 )
M.-T. Forel, M. Fouassier and M. Tranquille, Spectrochim. Acta, 26A, 1761 (1971)
O. Hassel and K. O. Stramme, Acta. Chem. Scand., 13, 275 (1959)
H. Schibilla and M.-T. LeBihan, Acta. Crystallogr, 23, 332 (1967)
G. Stucky and R. E. Rundle, J. Amer. Chem. Soc., 86, 4825 (1964)
H. Wieser and P. J. Krueger, Spectrochim. Acta, 26A, 1349 (1970)
S. Hayes, Bull. Soc. Chim. France., 1963, 1404.
A. D. Vreugdenhil and C. Blomberg, Rec. Tray. Chim. Pays-Bas, 82, 453 (1963)
D. Cook, Can. J. Chem., 41, 522 (1963)
W. Gerrard, M. F. Lappert, H. Pyszora and J. W. Wallis, J. Chem. Soc., 2144 (1960)
W. Klemperer, M. W. Cronyn, A. G. Maki and G. C. Pimentel, J. Amer. Chem. Soc., 76, 5846 (1954)
B.-P. Susz and D. Cassimatis, Hely. Chim. Acta, 44, 395 (1961)
H. Gerding, J. A. Koningstein and E. R. van der Worm, Spectrochim. Acta, 16, 881 (1960)
T. C. Waddington and F. Klanberg, J. Chem. Soc., 2339 (1960)
W. Gerrard, E. F. Mooney and H. A. Willis, J. Chem. Soc., 4255 (1961)
M. E. Peach and T. C. Waddington, J. Chem. Soc., 3450 (1962)
E. W. Wartenberg and J. Goubeau, Z. Anorg. Allg. Chem., 329, 269 (1964)
M. E. Anthoney, Ph.D. Thesis, University of London (1970)
M. F. Lappert, J. Chem. Soc., 542 (1962)
D. Cook, Can. J. Chem., 41, 515 (1963)
P. N. Gates, E. J. McLauchlan and E. F. Mooney, Spectrochim. Acta., 21, 1445 (1965)
B. P. Susz and P. Chalandon, Heiv. Chim. Acta, 41, 1332 (1958)
G. W. Chantry, A. Finch, P. N. Gates and D. Steele, J. Chem. Soc., A, 896 (1966)
D. E. H. Jones and J. L. Wood, J. Chem. Soc., A, 1448 (1966)
P. N. Gates and E. F. Mooney, J. Inorg. Nucl. Chem., 30, 839 (1968)
M.-T. Forel, M. Tranquille and M. Fouassier, Spectrochim. Acta, 26A, 1777 (1970)
G. Michel and G. Duyckaerts, Spectrochim. Acta., 21, 279 (1965)
G. Roland and G. Duyckaerts, Spectrochim. Acta., 27A, 975 (1971)
R. W. Rudolph, R. W. Parry and C. F. Farran, Inorg. Chem., 5, 723 (1966)
E. R. Lory, R. F. Porter and S. H. Bauer, Inorg. Chem., 10, 1072 (1971)
R. M. Adams, (Editor), Boron, Metallo-Boron Compounds and Boranes, ( Interscience, New York, 1964 ), page 527
K. L. Lundberg, R. J. Rowatt and N. E. Miller, Inorg. Chem., 8, 1336 (1969)
J. T. Braunholtz, E. A. V. Ebsworth, F. G. Mann and N. Sheppard, J. Chem. Soc., 2780 (1958)
C. W. Heitsch and R. N. Kniseley, Spectrochim. Acta, 19, 1385 (1963)
D. R. Lide, R. W. Taft and P. Love, J. Chem. Phys., 31, 561 (1959)
A. M. Prokhorov and G. P. Shipulo, Opt. Specktrosk., 8, 218 (1960)
P. S. Bryan and R. L. Kuczkowski, Inorg. Chem., 10, 200 (1971)
H. G. Schirdewahn, Doctoral Thesis, University of Freiburg (1965)
R. L. Kuczkowski and D. R. Lide, J. Chem. Phys., 46, 357 (1967)
J. P. Pasinski and R. L. Kuczkowski, J. Chem. Phys., 54, 1903 (1971)
R. W. Rudolph and R. W. Parry, J. Amer. Chem. Soc., 89, 1621 (1967)
H. J. Coerver and C. Curran, J. Amer. Chem. Soc., 80, 3522 (1958)
W. Gerrard, M. F. Lappert, H. Pyszora and J. W. Wallis, J. Chem. Soc., 2182 (1960)
R. C. Taylor and C. L. Cluff, Nature, 182, 390 (1958)
R. C. Taylor, Advances in Chemistry Series, No. 42 (American Chem. Soc., Washington D.C. 1964 ), page 59
H. Gerding and H. Houtgraaf, Rec. Tray. Chim. Pays-Bas, 74, 15 (1955)
Von W. Sawodny and J. Goubeau, Z. Anorg. Allg. Chem., 356, 289 (1968)
I. H. Hillier and V. R. Saunders, J. Chem. Soc., A, 664 (1971)
E. L. McGandy, Doctoral Thesis, Boston University, Boston (1961)
K. F. Purcell and R. S. Drago, J. Amer. Chem. Soc., 88, 919 (1966)
E. Augdahl and P. Klaboe, Spectrochim. Acta, 19, 1665 (1963)
A. Terenin, B. Filiminov and D. Bystrow, Z. Elektrochem., 62, 180 (1958)
I. R. Beattie and T. Gilson, J. Chem. Soc., 2292 (1964)
C. C. Costain, J. Chem. Phys., 29, 864 (1958)
R. A. Walton, Quart. Rev., 19, 126 (1965)
P. H. Clippard, R. C. Taylor and J. C. Hanson, J. Cryst. Mol. Struct., 1, 363 (1971)
C. Friedel and J.-M. Crafts, Bull. Soc. Chim. France, 27, 530 (1877);
C. Friedel and J.-M. Crafts, C.R. Acad. Sci., 84, 1450 (1877)
H. H. Perkampus and E. Baumgarten, Angew. Chem., 76, 965 (1964);
H. H. Perkampus and E. Baumgarten,Int. Ed., 3, 776
G. A. Olah, J. Amer. Chem. Soc., 87, 1103 (1965)
H. M. Nelson, J. Phys. Chem., 66, 1380 (1962)
G. A. Olah, E. B. Baker, J. C. Evans, W. S. Tolgyesi, J. S. McIntyre and I. J. Bastien, J. Amer. Chem. Soc., 86, 1360 (1964)
W. Hüttner and W. Zeil, Spectrochim. Acta, 22, 1007 (1966)
G. A. Olah, J. R. de Member, A. Commeyras and J. L. Bribes, J. Amer. Chem. Soc., 93, 459 (1971)
J. C. Evans (see reference 77)
G. A. Olah and A. M. White, J. Amer. Chem. Soc., 91, 3954 (1969)
G. A. Olah and A. M. White, J. Amer. Chem. Soc., 91, 3956 (1969)
G. A. Olah, A. M. White, A. Commeyras, J. R. de Member and C. Y. Lui, J. Amer. Chem. Soc., 92, 4627 (1970)
G. A. Olah and C. U. Pittman, (Ed., V. Gold) Advances in Physical Organic Chemistry, Vol. 4 ( Academic Press, New York and London, 1966 ), p 305
G. R. Olah, G. D. Mateescu, L. A. Wilson and M. H. Gross, J. Amer. Chem. Soc., 92, 7231 (1970)
B. P. Susz and J.-J. Wuhrmann, Hely. Chim. Acta., 40, 722 (1957)
P. N. Gates and D. Steele, J. Mol. Struct., 1, 349 (1968)
I. Nakagawa and T. Shimanouchi, Spectrochim. Acta, 18, 513 (1962)
J. L. Duncan, Spectrochim. Acta, 20, 1197 (1964)
B. P. Susz and J.-J. Wuhrmann, Hely. Chim. Acta, 40, 971 (1957)
D. Cook, Can. J. Chem., 37, 48 (1959)
D. Cassimatis and B. P. Susz, Hely. Chim. Acta, 44, 943 (1961)
D. Cassimatis, P. Gagnaux and B. P. Susz, Hely. Chim. Acta., 43, 424 (1960)
D. Cook, Can. J. Chem., 40, 480 (1962)
F. P. Boer, J. Amer. Chem. Soc., 88, 1572 (1966)
E. Lindner and H. Kranz, Z. Naturforsch., 20b, 1305 (1965)
E Lindner, Angew Chem. Int. Ed., 9, 114 (1970)
E. Lindner and H. Kranz, Chem. Ber., 99, 3800 (1966)
I. Cooke, B. P. Susz and C. Herschmann, Hely. Chim. Acta, 37, 1280 (1954)
B. P. Susz and D. Cassimatis, Hely. Chim. Acta, 44, 395 (1961)
H.-H. Perkampus and W. Weiss, Angew. Chem., Int. Ed., 7, 70 (1968)
E. Lindner and H.-G. Karmann, Angew. Chem., 80, 567 (1968)
E. Lindner and H.-G. Karmann,Angew. Chem. Int. Ed., 7, 548 (1968)
E. Lindner and K. M. Matejcek, Z. Anorg. Allg. Chem., in press
E. Lindner and H. Schless, Chem. Ber., 99, 3331 (1966)
E. Lindner and H. Weber, Chem. Ber., 101, 2832 (1968)
G. A. Olah and J. R. de Member, J. Amer. Chem. Soc., 92, 718 (1970)
H. C. Brown and H. W. Pearsall, J. Amer. Chem. Soc., 74, 191 (1952)
M. J. S. Dewar, The Electronic Theory of Organic Chemistry, (Oxford University Press, 1949 )
V. Gold and F. L. Tye, J. Chem. Soc., 2173, 2181, 2184 (1952)
C. MacLean, J. H. van der Waals and E. L. Mackor, Mol. Phys., 1, 247 (1958)
C. MacLean and E. L. Mackor, Mol. Phys., 4, 241 (1961)
C. MacLean and E. L. Mackor, Disc. Faraday Soc., 34, 165 (1962)
E. L. Mackor and C. MacLean, Pure Appl. Chem., 8, 393 (1964)
D. M. Brouwer, E. L. Mackor and C. MacLean, Rec. Tray. Chim. Pays-Bas, 84, 1564 (1965)
C. S. Johnson, Jr., (Ed. J. S. Waugh) Advances in Magnetic Resonance, Volume 1, ( Academic Press, New York and London 1965 )
D. M. Brouwer, Rec. Tray. Chim. Pays-Bas, 87, 335 (1968)
D. M. Brouwer, Rec. Tray. Chim. Pays-Bas, 87, 342 (1968)
T. Birchall, A. N. Boums, R. J. Gillespie and P. J. Smith, Can. J. Chem., 42, 1433 (1964)
E. M. Arnett and C. Y. Wu, J. Amer. Chem. Soc., 82, 5660 (1960)
D. M. Brouwer, E. L. Mackor and C. MacLean, Rec. Tray. Chim., Pay-Bas, 85, 109 (1966)
G. A. Olah, R. H. Schlosberg, D. P. Kelly and Gh. D. Mateescu, J. Amer. Chem. Soc., 92, 2546 (1970)
H. H. Perkampus and E. Baumgarten, Z. Elektrochem., 67, 16 (1963)
H. H. Perkampus and E. Baumgarten, Z. Elektrochem., 68, 70 (1964)
H. H. Perkampus, (Ed. V. Gold) Advances in Physical Organic Chemistry, Vol. 4, ( Academic Press, New York and London, 1966 ), p 195
D. H. Whiffen, P. Torkington and H. W. Thompson, Trans. Faraday Soc., 41, 200 (1945)
R. R. Randle and D. H. Whiffen, Proceedings of a Conference on Molecular Spectroscopy, ( Institute of Petroleum, London, 1955 ), p 111
L. J. Bellamy, The Infrared Spectra of Complex Molecules, 2nd edition, ( Methuen & Co. Ltd., London, 1968 ), p 75
A. Commeyras and G. A. Olah, J. Amer. Chem. Soc., 91, 2929 (1969)
R. C. Thompson, J. Barr, R. J. Gillespie, J. B. Milne and R. A. Rothenbury, Inorg. Chem., 4, 1641 (1965)
R. J. Gillespie and E. A. Robinson, Can. J. Chem., 40, 675 (1962)
R. J. Gillespie and K. C. Moss, J. Chem. Soc., A, 1170 (1966)
W. v. E. Doering, M. Saunders, H. G. Boyton, H. W. Earhart, E. F. Wadley, W. R. Edwards and G. Laber Tetrahedron, 4, 178 (1958)
C. A. Coulson, Valence, 2nd edition, (Oxford University Press, 1961 ), page 313
H. P. Fritz and L. Schäfer, Chem. Ber., 97, 1829 (1964)
G. O. Jones, D. H. Martin, P. A. Mawer and C. H. Perry, Proc. Roy. Soc., 261A, 10 (1961)
R. Janoschek, G. Diercksen, H. Preuss, Int. J. Quantum Chem., Symp. (No. 1 ) 205 (1967)
E. R. Lippincott, J. Xavier and D. Steele, J. Amer. Chem. Soc., 83, 2262 (1961)
A. Almenningen, O. Bastiansen and A. Haaland, J. Chem. Phys., 40, 3434 (1964)
E. O. Fischer and S. Schreiner, Chem. Ber., 92, 938 (1959)
G. B. McVicker and G. L. Morgan, Spectrochim. Acta, 26A, 23 (1970)
H. P. Fritz and D. Seilmann, J. Organometal. Chem., 5, 501 (1966)
G. L. Morgan and G. B. McVicker, J. Amer. Chem. Soc., 90, 2789 (1968)
H. P. Fritz, (Eds. F. G. A. Stone and R. West) Advances in Organometallic Chemistry, Vol. 1 (Academic Press, New York, 1964), p. 239ff
E. Weiss and E. O. Fischer, Z. Anorg. Allg. Chem., 278, 219 (1955)
L. Friedman, A. P. Irsa and G. Wilkinson, J. Amer. Chem. Soc., 77, 3689 (1955)
G. Wilkinson, F. A. Cotton and J. M. Birmingham, J. Inorg. Nucl. Chem., 2, 95 (1956)
F. A. Cotton and L. T. Reynolds, J. Amer. Chem. Soc., 80, 269 (1958)
S. Shibata, L. S. Bartell and R. M. Gavin Jr., J. Chem. Phys., 41, 717 (1964)
A. P. Cox and C. Roberts—to be published; private communication to authors
C. Roberts, A. P. Cox and M. J. Whittle, J. Mol. Spectrosc., 35, 476 (1970)
R. T. Bailey and R. H. Curran, J. Mol. Struct., 6, 391 (1970)
E. Frasson, F. Menegus and C. Panattoni, Nature, 199, 1087 (1963)
J. K. Tyler, A. P. Cox and J. Sheridan, Nature, 183, 1182 (1959)
A. Almenningen, A. Haaland and T. Motzfeldt., J. Organometal. Chem., 7, 97 (1967)
E. O. Fischer and H. Grubert, Z. Anorg. Allg. Chem., 286, 237 (1956)
H. H. Dearman, W. W. Porterfield and H. M. McConnell, J. Chem. Phys., 34, 696 (1961)
G. Wilkinson and T. S. Piper, J. Inorg. Nucl. Chem., 2, 32 (1956)
E. Maslowsky and K. Nakamoto, Chem. Comm., 257 (1968)
R. Hüttel, U. Raffay and H. Reinheimer, Angew. Chem., Int. Ed., 6, 862 (1967)
G. M. Whitesides and J. S. Fleming, J. Amer. Chem. Soc., 89, 2855 (1967)
A. N. Nesmeyanov, N. S. Sazonova, V. A. Sazonova and L. M. Meskhi, Izvest. Akad. Nauk. S.S.S.R., Ser. Khim., 1827 (1969)
A. Finch, P. N. Gates and D. Steele, Trans. Faraday Soc., 61, 2623 (1965)
H. B. Friedrich and W. B. Person, J. Chem. Phys., 44, 2161 (1966)
M. A. Rollier, Gazz Chim. Ital., 77, 372 (1947)
L. W. Reeves and W. G. Schneider, Can. J. Chem., 35, 251 (1957)
J. Pople, J. Chem. Phys., 24, 1111 (1956)
E. M. Engler and P. Laszlo, J. Amer. Chem. Soc., 93, 1317 (1971)
D. D. Eley, J. H. Taylor and S. C. Wallwork, J. Chem. Soc., 3867 (1961)
H. H. Perkampus and G. Orth, Z. Phys. Chem., 58, 327 (1968)
M. S. Ashkinazi, P. V. Kumosova and V. S. Finkel’stein, J. Phys. Chem. (USSR), 7, 438 (1936)
Sh. Sh. Raskin, Dokl. Acad. Nauk., S.S.S.R., 100, 485 (1955)
Sh. Sh. Raskin, Opt. Specktrosk., 1, 516 (1956)
L. W. Daasch, Spectrochim. Acta, 15, 726 (1559)
H.-H. Perkampus and E. Baumgarten, Z. Phys. Chem., 39, 1 (1963)
A. N. Terenin, V. N. Filimonov and D. S. Bystrov, Isvest. Akad. Nauk. SSSR., Ser Fiz., 22, 1100 (1958) (Chem. Abs., 53, 860 (1959))
C. D. Schmulbach and I. Y. Ahmed, Inorg. Chem., 8, 1414 (1969)
a) D. A. Long and R. T. Bailey, Unpublished material, private communication;
R. T. Bailey, Ph.D. thesis, University College, Swansea (1962)
A. A. Woolf, J. Chem. Soc., 252 (1954)
A. E. Douglas and P. M. Routby, J. Astrophys., 119, 303 (1954)
K. Kawai and I. Kanesaka, Spectrochim. Acta, 25A, 263 (1969)
J. S. Coleman, H. Petersen and R. A. Penneman, Inorg. Chem., 4, 135 (1965)
D. N. Waters, (Eds. A. J. Downs, D. A. Long and L. A. K. Staveley) Essays in Structural Chemistry, (Macmillan and Co. Ltd, London, 1971 ), Chapter 13
J. H. B. George, J. A. Rolfe and L. A. Woodward, Trans. Faraday Soc., 49, 375 (1953)
D. E. Irish and A. R. Davis, Can. J. Chem., 46, 943 (1968)
D. E. Irish, A. R. Davis and R. A. Plane, J. Chem. Phys., 50, 2262 (1969)
R. E. Hester and W. E. L. Grossman, Inorg. Chem., 5, 1308 (1966)
R. E. Hester, Ann. Rep. Chem. Soc., 66A, 79 (1969)
D. W. James and W. H. Leong, J. Chem. Phys., 51, 640 (1969)
R. Bonn, G. H. Wegdam and J. Van Der Eisken, J. Chem. Phys., 50, 1901 (1969)
R. G. Gordon, J. Chem. Phys., 42, 3658 (1965); ibid., 43, 1307 (1965)
R. G. Gordon, (Ed., J. S. Waugh) Advances in Magnetic Resonance, Vol. 3 ( Academic Press, New York and London, 1968 )
G. A. Olah and A. M. White, J. Amer. Chem. Soc., 91, 5801 (1969)
G. A. Olah, J. R. de Member, R. H. Schlosberg and Y. Halpern, J. Amer. Chem. Soc., 94, 156 (1972)
G. A. Olah, R. H. Schlosberg, R. D. Porter, Y. K. Mo, D. P. Kelly and G. D. Mateescu, J. Amer. Chem. Soc., 94, 2034 (1972)
M. E. Baur, D. A. Horsma, C. M. Knobler and P. Perez, J. Phys. Chem., 73, 641 (1969)
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Gates, P.N., Steele, D. (1973). Complexes of n and π Donors with Main Group Metal Compounds and Other Vacant Orbital Acceptors. In: Yarwood, J. (eds) Spectroscopy and Structure of Molecular Complexes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8471-7_6
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