Abstract
Surface morphologies of SiC deposits obtained via chemical vapor deposition (CVD) were studied as functions of substrate surface temperature and the concentration of the silicon and carbon source material, methyltrichlorosilane (MTS).Substrates of graphite and α-SiC crystals were used. Explanations of the observed morphologies on graphite substrates and their marked changes with temperature are given in terms of chemical kinetics and mass transport arguments. The results of thermodynamic calculations were used to help explain the observed morphologies of the deposits on α-SiC substrates.
This research was supported by the NASA Lewis Research Center, Grant No. NAG3-177.
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References
J. R. Weiss and R. J. Diefendorf, pp. 488–97 in Fourth International CVD Conference Proceedings, edited by G. F. Wakefield and J. M. Blocher, The Electrochemical Society, Princeton, NJ, 1973.
J. Chin, P. K. Gantzel, and R. G. Hudson, Thin Solid Films, 40, 57–72 (1977).
F. Christin, R. Naslain, and C. Bernard, pp. 499–514 in Seventh International CVD Conference Proceedings, edited by T. O. Sedgwick and H. Lydtin, The Electrochemical Society, Princeton, NJ, 1979.
V. J. Jennings, A. Sommer, and H. C. Chang, J. Electrochem. Soc., 113, 728–31 (1966).
W. V. Muench and I. Pfaffeneder, Thin Solid Films, 31, 39–51 (1976).
G. Eriksson, Acta Chim. Scand., 25, 2651–58 (1971).
G. Eriksson, Chemica Scripta, 4, 193–94 (1973).
G. Eriksson, Chemica Scripta, 8 100–03 (1975).
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© 1984 Plenum Press, New York
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Tsui, P., Spear, K.E. (1984). A Morphological Study of Silicon Carbide Prepared by Chemical Vapor Deposition. In: Davis, R.F., Palmour, H., Porter, R.L. (eds) Emergent Process Methods for High-Technology Ceramics. Materials Science Research, vol 17. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8205-8_28
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DOI: https://doi.org/10.1007/978-1-4684-8205-8_28
Publisher Name: Springer, Boston, MA
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