Abstract
For a sample to absorb radiofrequency power due to nuclear quadrupole resonance, the following basic criteria must be satisfied:
-
1.
The sample must contain nuclei with an electric quadrupole moment.
-
2.
These quadrupolar nuclei must be situated in an electric field gradient—usually the result of neighboring atoms in a molecule.
-
3.
The sample must be in the solid state—liquids or gases must be frozen.
-
4.
For a signal to be observed in practice, the sample must be at least partly crystalline.
The author would like to thank Mr. D. Thompson for many illuminating discussions of NQR instrumentation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
H. G. Dehmelt and H. Kruger, Naturwiss. 37, 111 (1950).
Volke Heine, “Group Theory in Quantum Mechanics,” Pergamon Press, London (1964), p. 192.
T. P. Das and E. L. Hahn, “Solid State Physics,” Supplement 1, “Nuclear Quadrupole Resonance Spectroscopy,” Academic Press, New York (1958).
G. K. Semin and E. I. Fedin, “Use of Nuclear Quadrupole Resonance in Chemical Crystallography.” Included in “Mossbauer Effect and Its Applications in Chemistry” by V. I. Goldanskii, Consultants Bureau, New York (1964).
C. T. O’Konski, in: “Determination of Organic Structures,” ( F. C. Nachod and W. D. Phillips, eds.), Academic Press, New York (1962), Chapter 11.
L. Guibé, Ann. Phys. 7, 177 (1962).
W. J. Orville-Thomas, Quart. Rev. 11, 162 (1957).
E. A. C. Lucken, “Nuclear Quadrupole Coupling Constants,” Academic Press, New York (1969).
Y. Ting, E. Manring, and D. Williams, Phys. Rev. 96, 408 (1954).
G. K. Semin, Dokl. Akad. Nauk SSSR 158 (5), 1169 (1964).
T. A. Babushkina, V. I. Robas, and G. K. Semin, Dokl. Akad. Nauk SSSR 159, 164 (1964).
G. E. Peterson and P. M. Bridenbaugh, Rev. Sci. Instr. 35, 698 (1964).
C. Dean and M. Pollak, Rev. Sci. Instr. 31, 204 (1960).
J. A. S. Smith and D. A. Tong, J. Sci. Instr., Series 21, 8 (1968).
G. E. Peterson and P. M. Bridenbaugh, Rev. Sci. Instr. 37, 1081 (1966).
G. D. Watkins and R. V. Pound, Phys. Rev. 85, 1062 (1952).
G. D. Watkins and R. V. Pound, Prog. Nucl. Phys. 2, 21 (1952).
F. N. H. Robinson, J. Sci. Instr. 36, 481 (1959).
C. H. Townes and B. P. Dailey, J. Chem. Phys. 17, 782 (1949).
E. G. Brame, Jr., Anal. Chem. 39, 918 (1967).
R. M. Smith and R. West, to be published.
A. Roedig, R. Helm, R. West, and R. M. Smith, Tetrahedron Letters, in press.
R. M. Smith and R. West, Tetrahedron Letters, in press.
W. L. Truett and D. K. Wilks, “NQR Bibliography,” Wilks Scientific Corp., South Norwalk, Connecticut (1967).
H. Meal, J. Am. Chem. Soc. 74, 6121 (1952).
P. Biryokov and M. G. Voronkov, Coll. Czech Chem. Commun. 32, 830 (1967).
P. J. Bray and R. G. Barnes, J. Chem. Phys. 27, 551 (1957).
D. Beidenkapp and A. Weiss, J. Chem. Phys. 49, 3933 (1968).
H. D. Schultz and C. Karr, Jr., Anal. Chem. 41, 661 (1969).
S. Kojima, S. Ogawa, M. Minematsu, and M. Tanaka, J. Phys. Soc. Japan 13, 446 (1955).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1970 Plenum Press, New York
About this chapter
Cite this chapter
Gilby, A.C. (1970). Nuclear Quadrupole Resonance Spectroscopy and Its Application to Chemistry. In: Friedel, R.A. (eds) Spectrometry of Fuels. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8121-1_11
Download citation
DOI: https://doi.org/10.1007/978-1-4684-8121-1_11
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-8123-5
Online ISBN: 978-1-4684-8121-1
eBook Packages: Springer Book Archive