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Mössbauer Spectroscopy of Rare-Gas Matrix Isolated 125Te Compounds

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Mössbauer Effect Methodology

Abstract

Rare-gas-matrix isolated (RGMI) atoms and molecules have been studied in the last twenty years by different experimental methods: These experiments indicate that the atoms and molecules trapped in the rare-gas-matrix have properties very similar to those of the free species, demonstrating that the weak binding in these solids does not change appreciably the atomic and molecular configuration. Matrix isolation techniques have been applied recently to Mössbauer spectroscopy. The first successful rare-gas-matrix isolation Mössbauer experiment was carried out with iodine molecules (I2) imbedded in solid argon at 22K1. Since then this technique has been extended to 57Fe,2 119Sn 3, and 125Te 4.

Supported by the National Science Foundation.

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References

  1. S. Bukshpan, C. Goldstein, and T. Sonnino, J. Chem. Phys. 49, 5477 (1968).

    Article  Google Scholar 

  2. P. H. Barrett and T. K. McNab, Phys. Rev. Lett. 25, 1601 (1970).

    Article  CAS  Google Scholar 

  3. H. Micklitz and P. H. Barrett, Phys. Rev. B5, 1704 (1972).

    Article  Google Scholar 

  4. P.H. Barrett, P. A. Montano, H. Micklitz and J. B. Mann, Phys. Rev. B12, 1676 (1975).

    Article  CAS  Google Scholar 

  5. Beat Mayer, Low Temperature Spectroscopy, American Elsevier Publishing Company, Inc., New York (1971).

    Google Scholar 

  6. P. H. Kasai, Phys. Rev. Letters 21, 67 (1968).

    Article  CAS  Google Scholar 

  7. Gmelins Handbuch Der Anorganischen Chemie, Tellur, edited by Erich Pietsch, Verlag Chemie G.M.B.H., Berlin (1940).

    Google Scholar 

  8. Tellurium, edited by W. Charles Cooper, Van Nostrand Reinhold Company, New York, Cincinnati, Toronto, London, Melbourne (1971).

    Google Scholar 

  9. D. P. Stevenson and Verner Schomaker, J. Am. Chem. Soc. 62, 1267 (1940).

    Article  CAS  Google Scholar 

  10. N. N. Greenwood, B.P. Stranghan, and Anne E. Wilson, J. Chem. Soc. A, 1479 (1966).

    Google Scholar 

  11. Nikolaos Katsaros and John W. George, Chem. Commun. 21, 613 (1965).

    Google Scholar 

  12. R. N. Kuzmin, A. A. Opalenko, V. S. Shpinel, and I. A. Avenarius, Zh. Eksp. Teor. Fiz. 56, 167 (1969). (Sov. Phys. - Jetp 29, 94 (1969)).

    Google Scholar 

  13. Yu Kagan, Dokl. Akad. Navk. SSSR 140, 794 (1961) (Sov. Phys. - Dokl. 6, 881 (1962)).

    Google Scholar 

  14. S. V. Karyagin, Dokl. Akad. Nauk. SSSR 148, 1102 (1963).

    CAS  Google Scholar 

  15. P. A. Flinn, S. L. Ruby, and W. L. Kehl, Science 143, 1434 (1964).

    Article  CAS  Google Scholar 

  16. R. N. Kuzmin, A. A. Opalenko and V. S. Shpinel, in Proceedings of the Conference on the Application of the Mössbauer Effect Tihany, 1969, edited by I. Dersi ( Akademiai Kiado, Budapest, 1971 ).

    Google Scholar 

  17. R. G. Barnes and W. V. Smith, Phys. Rev. 93, 95 (1954).

    Article  CAS  Google Scholar 

  18. C. E. Violet, R. Booth and F. Wooten, Phys. Lett. 5, 230 (1963).

    Article  CAS  Google Scholar 

  19. K. Rossman and J. W. Straley, J. Chem. Phys. 24, 1276 (1956).

    Article  Google Scholar 

  20. W. Gordy, W. V. Smith and R. F. Trambarulo, Microwave Spectroscopy, John Wiley and Sons, Inc., New York (1953).

    Google Scholar 

  21. Charles A. Burrus, Jr. and Walter Gordy, Phys. Rev. 92, 274 (1953).

    Article  CAS  Google Scholar 

  22. Linus Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca, New York (1960).

    Google Scholar 

  23. P. Jung and W. Trifthäuser, Phys. Rev. 175, 512 (1968).

    Article  CAS  Google Scholar 

  24. M. L. Unland, J. Chem. Phys. 49, 4514 (1968).

    Article  CAS  Google Scholar 

  25. G. M. Kalvius, in Hyperfine Interaction in Excited Nuclei, edited by G. Goldring and R. Kalish (Gordon and Breach, New York, 1971 ), Vol. 2, p. 523.

    Google Scholar 

  26. G. M. Kalvius and G. K. Shenoy, Atomic Data and Nuclear Data Tables 14, 639 (1975).

    Article  Google Scholar 

  27. S. L. Ruby and G. K. Shenoy, Phys. Rev. 186, 326 (1969).

    Article  CAS  Google Scholar 

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Montano, P.A., Barrett, P.H., Micklitz, H. (1976). Mössbauer Spectroscopy of Rare-Gas Matrix Isolated 125Te Compounds. In: Gruverman, I.J., Seidel, C.W. (eds) Mössbauer Effect Methodology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8073-3_13

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  • DOI: https://doi.org/10.1007/978-1-4684-8073-3_13

  • Publisher Name: Springer, Boston, MA

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