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The Effect of Chemical Combination on X-Ray Spectra: Open Discussion

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Advances in X-Ray Analysis

Abstract

J. Merritt (Shell Development): This is quite a minor point, but it may get some discussion started. There has been reference several times during this afternoon to the self-absorption effect. We were intrigued by the work that Baun and Fischer did on the L 2/L 3 ratio, and their study showed that this varied for the iron transition elements with accelerating voltage. We said this is the L 3 edge in between these two lines, and so Chet Muller of our laboratories prepared a very thin sample (he estimates it was about 1000 ± 500 Å) and found that the L 2/L 3 ratio did not vary with accelerating voltage, which I think confirms the idea that it is an absorption effect, and I presume it was due to the L 3 edge.

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Gavin R. Mallett Marie J. Fay William M. Mueller

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© 1966 Springer Science+Business Media New York

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Mallett, G.R., Fay, M.J., Mueller, W.M. (1966). The Effect of Chemical Combination on X-Ray Spectra: Open Discussion. In: Mallett, G.R., Fay, M.J., Mueller, W.M. (eds) Advances in X-Ray Analysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-7633-0_35

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  • DOI: https://doi.org/10.1007/978-1-4684-7633-0_35

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-7635-4

  • Online ISBN: 978-1-4684-7633-0

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