Skip to main content

An X-Ray Diffraction Study of the Phase Transformation Temperature of MnO

  • Conference paper
Advances in X-Ray Analysis

Abstract

X-ray diffraction measurements of MnO confirm the hypothesis that the structural temperature and the magnetic transition temperature, or Néel temperature, are the same. The usefulness of X-ray diffraction intensity data of MnO, with respect to an atomic structural refinement problem involving α-Mn powders, is discussed. Lattice constant values of MnO are listed between 100 and 310°K.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. L. Roth, “Magnetic Structures of MnO, FeO, CoO, and NiO,”Phys. Rev. 110: 1333–1341, 1958.

    Article  CAS  Google Scholar 

  2. A. H. Jay and K. W. Andrews, “Note on Oxide Systems Pertaining to Steel Making Furnace Slags FeO—MnO, FeO—MgO, CaO—MnO, MgO—MnO, ”J. Iron and Steel Inst. (London) 152 1945.

    Google Scholar 

  3. C. G. Shull and J. S. Smart, “Detection of Antiferromagnetism by Neutron Diffraction,” Phys. Rev. 76: 1256, 1949.

    Article  Google Scholar 

  4. C. G. Shull, W. A. Strauser and E. O. Wollan, “Neutron Diffraction by Paramagnetic and Antiferromagnetic Substances,” Phys. Rev. 83: 333, 1951.

    Article  CAS  Google Scholar 

  5. B. S. Ellefson and N. W. Taylor, “Crystal Structures and Expansion Anomalies of MnO, MnS, FeO, Fes04 between 100 and 200°K,” J. Chem. Phys. 2: 58, 1934.

    Article  CAS  Google Scholar 

  6. F. Ruhemann, “Temperaturabhängigkeit der Gitterkonstanten von Manganoxyd,” Physik. Ber. 16: 2337, 1935.

    Google Scholar 

  7. N. C. Toombs and H. P. Rooksby, “Structure of Some Transition Elements at Low Temperatures,” Nature 165: 442, 1950.

    Article  Google Scholar 

  8. S. Greenwald and J. S. Smart, “Deformations in the Crystal Structures of Anti-ferromagnetic Compounds,” Nature 166: 523–524, 1950.

    Article  CAS  Google Scholar 

  9. C. P. Gazzara, “The Debye Temperature of Carbonyl Iron,” in: W. M. Mueller, G. R. Mallett, and M. J. Fay (eds.), Advances in X-Ray Analysis, Vol. 4, Plenum Press (New York), 1960, pp. 93–107.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Gavin R. Mallett Marie J. Fay William M. Mueller

Rights and permissions

Reprints and permissions

Copyright information

© 1966 Springer Science+Business Media New York

About this paper

Cite this paper

Gazzara, C.P., Middleton, R.M. (1966). An X-Ray Diffraction Study of the Phase Transformation Temperature of MnO. In: Mallett, G.R., Fay, M.J., Mueller, W.M. (eds) Advances in X-Ray Analysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-7633-0_13

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-7633-0_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-7635-4

  • Online ISBN: 978-1-4684-7633-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics