Abstract
In previous chapters, the three-centre two-electron hydrogen bridge has been shown to be a common structural feature of all the neutral boron hydrides and of many of their derivatives, and a source of many of their characteristic reactions, particularly those in which the bridge is cleaved by nucleophiles (Lewis bases). Similar electron deficient hydrogen bridges linking atoms of many other elements than boron are now known, and it is the object of the present chapter to indicate briefly in what types of compound they occur. These types are too numerous to allow also detailed discussion of their reactions, many of which can, however, be inferred by analogy with those of the boron hydrides described in Chapter 4.
Keywords
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Mackay, K. M., Hydrogen Compounds of the Metallic Elements, E. and F. N. Spon Ltd., London, 1966.
Turley, J. W., and H. W. Rinn, Inorg. Chem., 1969, 8, 18.
Breisacher, P., and B. Siegel, J. Amer. Chem. Soc., 1964, 86, 5053;
Breisacher, P., and B. Siegel, J. Amer. Chem. Soc., 1965, 87, 4255.
Young, A. R. jun., and R. Ehrlich, J. Amer. Chem. Soc., 1964, 86, 5359.
Greenwood, N. N., Gallium hydride and its derivatives, ch. 3 (pp. 37–64) of New Pathways in Inorganic Chemistry, Ebsworth, E. A. V., A. G. Maddock, and A. G. Sharpe (eds.), Cambridge Univ. Press, Cambridge, 1968.
Coates, G. E., and F. Glockling, J. Chem. Soc., 1954, 22;
Banford, L., and G. E. Coates, J. Chem. Soc. (A), 1966, 274.
James, B. D., and M. G. H. Wallbridge, Metal tetrahydroborates, pp. 99–231 of Progress in Inorganic Chem., vol. II (ed.), S. J. Lippard, Wiley, London, 1970.
Cook, T. H., and G. L. Morgan, J. Amer. Chem. Soc., 1969, 91, 774.
Sklar, N., and B. Post, Inorg. Chem., 1967, 6, 669.
Churchill, M. R., and R. Mason, The structural chemistry of organotransition metal complexes: some recent developments. Advances in Organometal. Chem., 1967, 5, 93–135.
Churchill, M. R., J. Wormwald, J. Knight, and M. J. Mays, Chem. Comm., 1970, 458.
Vranka, R. G., and E. L. Amma, J. Amer. Chem. Soc., 1967, 89, 3121.
Byram, S. K., J. K. Fawcett, S. C. Nyburg, and R. J. O’Brien, Chem. Comm., 1970, 16.
Dewar, M. J. S., and D. B. Patterson, Chem. Comm., 1970, 544.
Magnuson, V. R., and G. D. Stucky, J. Amer. Chem. Soc., 1969, 91, 2544.
Malone, J. F., and W. S. McDonald, Chem. Comm., 1967, 444; 1970, 280.
Interatomic distances, Special Publication No. 11, The Chemical Society, London, 1958.
See, for example, Jeffery, E. A., T. Mole, and J. K. Saunders, Austral. J. Chem., 1968, 21, 137, 649;
Fishwick, M., C. A. Smith, and M. G. H. Wallbridge, J. Organo-metal Chem., 1970, 21, P9.
Cotton, F. A., and J. R. Leto, J. Chem. Phys., 1959, 30, 993.
Almenningen, A., S. Halvorsen, and A. Haaland, Chem. Comm., 1969, 644.
Wagman, D. D., W. H. Evans, V. B. Parker, I. Halow, S. M. Bailey, and R. M. Schumm, Selected values of chemical thermodynamic properties, U.S. National Bureau of standards Technical Note 270–3, Jan. 1968.
Köster, R., and P. Binger, Organo-aluminium compounds, Adv. Inorg. Chem. Radiochem., 1965, 7, 263–348.
Reinheckel, H., K. Haage, and D Jahnke, Organo-aluminium compounds in organic chemical reactions, Organometal Chem. Reviews A, 1969, 4, 47–136.
Coates, G. E., and K. Wade, Organometallic Compounds; 3rd Edn. Vol I; The Main Group Elements, Methuen, London, 1967;
Coates, G. E., M. L. H. Green, P. Powell, and K. Wade, Principles of organometallic chemistry, Methuen, London, 1968.
Ashby, E. C., J. Laemmle, and H. M. Neumann, J. Amer. Chem. Soc., 1968, 90, 5179.
Oliver, J. P., Fast exchange reactions of Group 1, II, and III organometallic compounds, Advances in organometal Chem., 1970, 8, 167–209.
Ham, N. S., E. A. Jeffery, and T. Mole, Austral. J. Chem., 1968, 21, 2687.
Hata, G., Chem. Comm., 1968, 7.
Amma, E. L., and R. E. Rundle, J. Amer. Chem. Soc., 1958, 80, 4141.
Sheldrick, G. M., and W. S. Sheldrick, J. Chem. Soc. (A), 1970, 28.
Malone, J. F., and W. S. McDonald, J. Chem. Soc. (A), 1970, 3362.
Snow, A. I., and R. E. Rundle, Acta Cryst., 1951, 4, 348.
Weiss, E., J. Organometal Chem., 1964, 2, 314.
Atwood, J. L., and G. D. Stucky, J. Amer. Chem. Soc., 1969, 91, 2538.
Brown, T. L., The structures of organo-lithium compounds, Advances in Organo-metal Chem., 1965, 3, 365–395.
Weiss, E., and E. A. C. Lucken, J. Organometal Chem., 1964, 2, 197;
Weiss, E., and G. Hencken, ibid., 1970, 21, 265.
Weiss, E., and G. Sauermann, J Organometal Chem., 1970, 21, 1.
Weiss, E., and G. Sauermann, Angew. Chem., Internat. Edn., 1968, 7, 133.
Braye, E. H., L. F. Dahl, W. Hiibel, and D. L. Wampler, J. Amer. Chem. Soc., 1962, 84, 4633.
Sirigu, A., M. Bianchi, and E. Benedetti, Chem. Comm., 1969, 596.
Jeffrey, G. A., and V. Y. Wu, Acta Cryst., 1966, 20, 538.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1971 K. Wade
About this chapter
Cite this chapter
Wade, K. (1971). Associated metal hydrides, alkyls, and aryls. In: Electron Deficient Compounds. Studies in Modern Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-6054-4_5
Download citation
DOI: https://doi.org/10.1007/978-1-4684-6054-4_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-6056-8
Online ISBN: 978-1-4684-6054-4
eBook Packages: Springer Book Archive