Skip to main content
SpringerLink
Log in

Hydrogen Abstraction by Thiyl Radicals from Activated C-H-Bonds of Alcohols, Ethers and Polyunsaturated Fatty Acids

  • Chapter
Sulfur-Centered Reactive Intermediates in Chemistry and Biology

Part of the book series: NATO ASI Series ((NSSA,volume 197))

Abstract

Owing to their reducing properties thiols and thiolates, RSH/RS−, participate in many cellular redox processes serving as an electron donor according to the general reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. P. Wardman, in: “Glutathione Conjugation”, H. Sies and B. Ketterer, eds., Academic Press, New York, p. 43–72 (1988).

    Google Scholar 

  2. C von Sonntag, “The Chemical Basis of Radiation Biology”, Taylor and Francis, London (1987).

    Google Scholar 

  3. L. G. Forni and R. L. Willson, Biochem. J., 240: 897 (1986).

    CAS  Google Scholar 

  4. L. G. Forni, J. Mönig, V O. Mora-Arellano, and R. L. Willson, J. Chem. Soc. Perkin Trans. 2, 961 (1983).

    Google Scholar 

  5. J. Mönig, K.-D. Asmus, L. G. Forni, and R. L. Willson, Int. J. Radiat. Biol., 52: 589 (1987).

    Article  Google Scholar 

  6. M. Tamba, G. Simone, M. Quintiliani, Int. J. Radiat. Biol., 50: 595 (1986).

    Article  CAS  Google Scholar 

  7. K. -D. Asmus, in “Methods Enzymology”, vol. 186, L Packer and A.N. Glazer, eds., Academic Press, San Diego, p. 168–180 (1990)

    Google Scholar 

  8. D. Schulte-Frohlinde, Free Rad. Res. Comm., 6: 181 (1989).

    Article  CAS  Google Scholar 

  9. H. Glatt, M. Protic-Sabljic, and F. Oesch, Science, 220: 961 (1983).

    Article  CAS  Google Scholar 

  10. M. H. Carter and P. D. Josephy, Biochem. Pharmacol., 35: 3847 (1986).

    Article  CAS  Google Scholar 

  11. A.-A. Stark, A. Arad, S. Siskindovich, D. A. Pagano, and E. Zeiger, Mutation Res., 224: 89 (1989).

    Article  CAS  Google Scholar 

  12. M. Z. Baker, R. Badiello, M. Tamba, M. Quintiliani, and G. Gorin, Int. J. Radiat. Biol., 41: 595 (1982).

    Article  CAS  Google Scholar 

  13. M. Tamba and M. Quintiliani, Radiat. Phys. Chem., 23: 259 (1984).

    CAS  Google Scholar 

  14. M. S. Akhlaq, H. P. Schuchmann, and C. von Sonntag, Int. J. Radiat. Biol., 51: 91 (1987).

    Article  CAS  Google Scholar 

  15. W. A. Pryor, G. Gojon, and D. F. Church, J. Org. Chem., 43: 793 (1978).

    Article  CAS  Google Scholar 

  16. Ch. Schöneich, M. Bonifacic, and K.-D. Asmus, Free Rad. Res. Commun., 6: 393 (1989).

    Article  Google Scholar 

  17. B. S. Wolfenden and R. L. Willson, J. Chem. Soc Perkin Trans. 2, 805 (1982).

    Google Scholar 

  18. M. Z. Hoffman and E. Hayon, J. Phys. Chem., 77: 990 (1973).

    Article  CAS  Google Scholar 

  19. Ch. Schöneich, M. Bonifacic, and K.-D. Asmus, unpublished results.

    Google Scholar 

  20. J. Lilie, A. Henglein, and G. Beck, Ber. Bunsenges. Phys. Chem., 75: 458 (1971).

    CAS  Google Scholar 

  21. H. A. Schwarz and R. W. Dodson, J. Phys. Chem., 93: 409 (1989).

    Article  CAS  Google Scholar 

  22. see articles by M. Quintiliani, and Ch. Chatgilialoglu and M. Guerra in this NATOASI book.

    Google Scholar 

  23. K.-D. Asmus and M. Bonifacic, in: “Landolt-Börnstein. Zahlenwerte und Funktionen”, H. Fischer, ed., New Series, Springer Verlag, Berlin, vol. 13b (1984).

    Google Scholar 

  24. W. A. Priitz and H. Mönig, Int. J. Radiat. Biol., 52: 677 (1987).

    Article  Google Scholar 

  25. D. C. A. John and K. T. Douglas, Biochem. Biophys. Res. Commun., 165: 1235 (1989).

    Article  CAS  Google Scholar 

  26. A. A. Horton and S. Fairhurst, CRC Critical. Rev. Toxicol., 18: 27 (1987).

    Article  CAS  Google Scholar 

  27. N. A. Porter and D. G. Wujek, in: “Reactive Species in Chemistry, Biology, and Medicine”, A. Quintanilha, ed., NATO ASI Series A: Life Sciences, vol. 146, Plenum Press (1988).

    Google Scholar 

  28. A. J. F. Searle and R. L. Willson, Biochem. J., 212: 549 (1983).

    CAS  Google Scholar 

  29. M. Tien, J. R. Bucher, and S. D. Aust, Biochem. Biophys. Res. Commun., 107: 279 (1982).

    Article  CAS  Google Scholar 

  30. Ch. Schöneich, K.-D. Asmus, U. Dillinger, and F. von Bruchhausen, Biochem. Biophys. Res. Commun., 161: 113 (1989).

    Article  Google Scholar 

  31. K. Hasegawa and L. K. Patterson, Photochem. Photobiol., 28: 817 (1978).

    Article  CAS  Google Scholar 

  32. M. Erben-Russ, Ch. Michel, W. Bors, and M. Saran, J. Phys. Chem., 91: 2362 (1987).

    Article  CAS  Google Scholar 

  33. M. Erben-Russ, W. Bors, R. Winter, and M. Saran, Radiat. Phys. Chem., 27: 419 (1986).

    CAS  Google Scholar 

  34. Ch. Schöneich, K.-D. Asmus, U. Dillinger, and F. von Bruchhausen, unpublished results.

    Google Scholar 

  35. R. P. Scott and P. Kucera, J. Chromatogr., 142: 213 (1977).

    Article  CAS  Google Scholar 

  36. G. A. Russell, in: “Free Radicals”, vol. 1, J. K. Kochi, ed., Wiley and Sons, New York, P. 275–331 (1973).

    Google Scholar 

  37. B. H. Bielski, R. L. Arudi, and M. W. Sutherland, J. Biol. Chem., 258: 4759 (1983).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Abteilung Strahlenchemie, Hahn-Meitner-Institut Berlin, Bereich S, Postfach 39 01 28, 1000, Berlin 39, F.R. Germany

    Christian Schöneich & Klaus-Dieter Asmus

  2. Department of Physical Chemistry, Ruder Boskovic Institut, P.O.B. 1016, 41001, Zagreb, Croatia, Yugoslavia

    Marija Bonifačić

  3. Universitätsklinikum Rudolf Virchow, Abteilung für Anaesthesiologie und operative Intensivmedizin, Freie Universität Berlin, 1000, Berlin 19, F.R. Germany

    Uwe Dillinger

Authors
  1. Christian Schöneich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Marija Bonifačić
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Uwe Dillinger
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Klaus-Dieter Asmus
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Consiglio Nazionale delle Richerche, Ozzano Emilia (Bologna), Italy

    Chryssostomos Chatgilialoglu

  2. Hahn-Meitner-Institut, Berlin, Federal Republic of Germany

    Klaus-Dieter Asmus

Rights and permissions

Reprints and permissions

Copyright information

© 1990 Plenum Press, New York

About this chapter

Cite this chapter

Schöneich, C., Bonifačić, M., Dillinger, U., Asmus, KD. (1990). Hydrogen Abstraction by Thiyl Radicals from Activated C-H-Bonds of Alcohols, Ethers and Polyunsaturated Fatty Acids. In: Chatgilialoglu, C., Asmus, KD. (eds) Sulfur-Centered Reactive Intermediates in Chemistry and Biology. NATO ASI Series, vol 197. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5874-9_32

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-5874-9_32

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5876-3

  • Online ISBN: 978-1-4684-5874-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation