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New Mobilizing and Templating Agents in the Synthesis of Crystalline Microporous Solids

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Guidelines for Mastering the Properties of Molecular Sieves

Part of the book series: NATO ASI Series ((NSSB,volume 221))

Abstract

The structure of crystalline microporous solids, such as zeolites1 and molecular sieves2, consists of:

  • a framework TO2 (T = Si, Al, P…), each T04 tetrahedron being linked to four others through T-O-T bridges

  • regular micropores of molecular size (containing species such as cations, water, ionic pairs) which communicate with the environment.

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References

  1. D. H. Breck, “Zeolite Molecular Sieves”, John Riley and Sons, New-York (1974)

    Google Scholar 

  2. A. Dyer, “An introduction to Zeolite Molecular Sieves”, John Hiley and Sons, Chichester (1988)

    Google Scholar 

  3. P. Caullet, J. L. Guth and R. Hey, Solubilité et grandeurs thermodynamiques de dissolution des zeolites 4A et 13X dans des solutions aqueuses basiques, Bull. Minéral., 103: 330 (1980)

    CAS  Google Scholar 

  4. P. Caullet, J. L. Guth and R. Hey, Solubilité de la zéolite Y et de 1’ analcite dans des solutions aqueuses basiques. Grandeurs thermodynamiques de dissolution, C. R. Acad. Se. Paris, Série D, 291: 117 (1980)

    CAS  Google Scholar 

  5. G. T. Kerr, Chemistry of crystalline aluminosilicates. I. Factors affecting the formation of zeolite A, J. Phys. Chem., 70: 1047 (1966)

    Article  CAS  Google Scholar 

  6. S. P. Zhdanov, Some problems of zeolite crystallization, in “Molecular Sieve Zeolites. I. Advances in chemistry series N°101”, E. M. Flanigen and L. B. Sand, ed., American Chemical Society, Hashington (1971)

    Google Scholar 

  7. P. Henqin, S. Ueda and M. Koizumi, The synthesis of zeolite Na A from homogeneous solutions and studies of its properties, in “New developments in zeolite science and technology”, Y. Murakami, A. Iijima, J. R. Hard, ed., Kodansha-Elsevier, Tokyo (1986)

    Google Scholar 

  8. P. Caullet, J. L. Guth, G. Hurtrez and R. Hey, Contribution à l’étude du mécanisme de formation des zéolites. V. Cristallisation de zéoli-tes à partir de solutions d’aluminosilicates caractérisées par un rapport Si/Al égal à 1, Bull. Soc. Chim. Fr., 7–8: 253 (1981)

    Google Scholar 

  9. P. Caullet and J. L. Guth, Contribution à 1’ étude du mécanisme de formation des zéolites: les équilibres solutions-zéolites; les espèces et structures des solutions, Thesis, Mulhouse, France (1983)

    Google Scholar 

  10. G. Engelhardt and D. Michel, “High-resolution solid-state NMR of silicates and zeolites”, John Hiley and Sons, Chichester (1987)

    Google Scholar 

  11. P. Caullet and J. L. Guth, 1989, Observed and calculated silicate and aluminosilicate concentrations in alkaline aqueous solutions, in “Zeolite synthesis”, ACS Symposium Series n°398, M. L. Occelli and H. E. Robson, eds., American Chemical Society, Hashington(1989)

    Google Scholar 

  12. R. M. Barrer, “Hydrothermal chemistry of zeolites”, Academic Press, London (1982)

    Google Scholar 

  13. J. L. Casci and B. M. Lone, Use of pH-measurements to monitor zeolite crystallization, Zeolites, 3: 186 (1983)

    Article  CAS  Google Scholar 

  14. J. L. Guth, P. Caullet and R. Hey, Variation du paramètre cristallin df une zeolite Y au cours de sa cristallisation à partir d’un gel. Mise en évidence d’une hétérogénéité de composition, Bull. Soc. Fr. Minér. Cristall., 99: 21 (1976)

    CAS  Google Scholar 

  15. P. Bodart, J. B Nagy, E. 6. Oerouane and Z. Gabelica, Study of mordenite crystallization III: Factors governing mordenite synthesis, in “Structure and reactivity of modified zeolites” (Studies in surface science and catalysis 18), P. A. Jacobs, H. I. Jaeger, P. Jiru, V. B. Kazansky and G. Schulz-Ekloff, ed., Elsevier, Amsterdam (1984)

    Google Scholar 

  16. R. H. Grose and E. M. Flanigen, Crystalline silica, U. S. Patent n°4061724 (1977)

    Google Scholar 

  17. G. L. Hoolery, L. B. Alemany, R. M. Dessan and A. H. Chester, Spectroscopic evidence for the presence of internal silanols in highly siliceous ZSM5, Zeolites, 6: 14 (1986)

    Article  Google Scholar 

  18. R. H. Busey, E. Schwartz and R. E. Mesmer, Fluorosilicate equilibria in sodium chloride solutions from 0 to 60°C, Inorq. Chem., 19: 758 (1980)

    Article  CAS  Google Scholar 

  19. N. A. Hatiriyoff and H. E. Hageman, Nuclear magnetic resonance studies of aluminium(III) fluoride ion complexes in aqueous solutions, Inorq. Chem., 9: 1031 (1970)

    Article  Google Scholar 

  20. D. Hass, S. P. Tetrosyants, Yu. A. Buslaev and I. Hartlab, Characteristics of the formation of aluminum and gallium fluoride complexes in solution, Doklady Akademii Nauk SSSR, 269: 380 (1983)

    CAS  Google Scholar 

  21. A. M. Bond and G. T. Hefter, Critical survey of stability constants and related thermodynamic data of fluoride complexes in aqueous solution, Pergamon Press, Oxford (1980)

    Google Scholar 

  22. J. L. Guth, H. Kessler, J. M. Higel, J. M. Lamblin, J. Patarin, A. Seive, J. H. Chezeau and R. Hey, 1989, Zeolite synthesis in presence of fluoride ions. Comparison with conventional synthesis methods, in “Zeolite synthesis, ACS Symposium Series n° 398”, M. L. Occelli and H. E. Robson, eds., American Chemical Society, Hashington.

    Google Scholar 

  23. Z. Gabelica and J. L. Guth, A silicogermanate with Si: Ge ratio ≥ an HFI zeolite of novel composition, Anqew. Chem. Int. Ed. Engl., 28: 81 (1989)

    Article  Google Scholar 

  24. E. W. Valyocsik, Improved method of preparing crystalline zeolite ZSM20, Eur. Pat. Appl. 0012522 (1980)

    Google Scholar 

  25. G. T. Kokotailo and J. Ciric, Synthesis and structural features of zeolite ZSH3, in “Molecular Sieve Zeolites. II. Advances in chemistry series n°102”, E. M. Flanigen and L. B. Sand, ed., American Chemical Society, Hashington (1971)

    Google Scholar 

  26. Z. Gabelica, N. Dewaele, L. Maistriau, J. B Nagy and E. C. Derouane, 1989, Directing parameters in the synthesis of zeolites ZSM-20 and Beta, in “Zeolite synthesis, ACS Symposium Series n° 398”, M. L. Occelli and H. E. Robson, eds., American Chemical Society, Hashington.

    Google Scholar 

  27. H. D. Durst, M. Milano, E. J. Kikta, Jr, S. A. Connelly and Eli Grushka, Phenacylesters of fatty acids via crown-ether catalysts for enhanced ultraviolet detection in liquid chromatography, Anal. Chem. 47: 1797 (1975)

    Article  CAS  Google Scholar 

  28. C. J. Pedersen, Cyclic polyethers and their complexes with metal salts, J. Am. Chem. Soc., 89: 7017 (1967)

    Article  CAS  Google Scholar 

  29. A. Delville, H. D. H. Stover and C. Detellier, Crown ether-cation decomplexation mechanics. 23Na NMR studies of sodium cation complexes with dibenzo-24-crown-8 and Dibenzo-18-Crown-6 in nitromethane and aceto-nitrile, J. Am. Chem. Soc. 109: 7293 (1987)

    Article  CAS  Google Scholar 

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© 1990 Plenum Press, New York

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Guth, J.L., Caullet, P., Seive, A., Patarin, J., Delprato, F. (1990). New Mobilizing and Templating Agents in the Synthesis of Crystalline Microporous Solids. In: Barthomeuf, D., Derouane, E.G., Hölderich, W. (eds) Guidelines for Mastering the Properties of Molecular Sieves. NATO ASI Series, vol 221. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5787-2_3

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  • DOI: https://doi.org/10.1007/978-1-4684-5787-2_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5789-6

  • Online ISBN: 978-1-4684-5787-2

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