Abstract
The structure of crystalline microporous solids, such as zeolites1 and molecular sieves2, consists of:
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a framework TO2 (T = Si, Al, P…), each T04 tetrahedron being linked to four others through T-O-T bridges
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regular micropores of molecular size (containing species such as cations, water, ionic pairs) which communicate with the environment.
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Guth, J.L., Caullet, P., Seive, A., Patarin, J., Delprato, F. (1990). New Mobilizing and Templating Agents in the Synthesis of Crystalline Microporous Solids. In: Barthomeuf, D., Derouane, E.G., Hölderich, W. (eds) Guidelines for Mastering the Properties of Molecular Sieves. NATO ASI Series, vol 221. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5787-2_3
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