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Time-Resolved Kinetics of Organometallic Reactions in the Gas Phase by Transient Infrared Absorption Spectrometry

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Gas Phase Inorganic Chemistry

Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Chemical change is a science of intermediates. Reactive molecules and fragments guide the chemistry of multicomponent systems and determine the stereospecific outcomes of individual reactions. Organometallic chemistry is among the richest of all for its transient species. Metal-centered intermediates variously appear and disappear via oxidative addition, insertion, metallocyclization, and their reverse reactions.(1) Progress in stoichiometric synthesis as well as catalysis depends on the accurate knowledge of the intermediate forms at work in these and other organometallic transformations.

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Author information

Author notes

  1. Bruce H. Weiller

    Present address: Department of Chemistry, University of California, Berkeley, California, 94720, USA

Authors and Affiliations

  1. Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907, USA

    Bruce H. Weiller & Edward R. Grant

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  1. Bruce H. Weiller
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  2. Edward R. Grant
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    David H. Russell

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© 1989 Plenum Press, New York

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Weiller, B.H., Grant, E.R. (1989). Time-Resolved Kinetics of Organometallic Reactions in the Gas Phase by Transient Infrared Absorption Spectrometry. In: Russell, D.H. (eds) Gas Phase Inorganic Chemistry. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5529-8_7

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  • DOI: https://doi.org/10.1007/978-1-4684-5529-8_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5531-1

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