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Statistical Thermodynamics of Alloys pp 149–193Cite as

Interstitial Solutions

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Abstract

It was stated in Chapter 2 that when the atomic diameter of a metalloid is about 59% or less than that of a solvent metal, then the metalloid may form an interstitial solid solution. Such metalloids are hydrogen, boron, carbon, nitrogen, and oxygen, but silicon, phosphorus, and sulfur may also form interstitial solid solutions in certain favorable cases. The interstitial solid solutions of hydrogen and carbon in metals have received particular attention because they form some of the most interesting alloy systems. Metalhydrogen systems are very useful in hydrogen storage, hydrogen purification, and isotope separation, and metal-carbon systems have unusual structural and mechanical properties. We shall present and discuss the Pd-H and Fe-C systems and then the Wagner theory on the solutions of interstitials in binary metal solutions.

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Authors and Affiliations

  1. Bureau of Mines, U.S. Department of the Interior, Albany Research Center, Albany, Oregon, USA

    N. A. Gokcen

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© 1986 Plenum Press, New York

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Gokcen, N.A. (1986). Interstitial Solutions. In: Statistical Thermodynamics of Alloys. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5053-8_6

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  • DOI: https://doi.org/10.1007/978-1-4684-5053-8_6

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