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Synthesis and Properties of Acetylene Terminated Aryl-Ether Oligomers

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New Monomers and Polymers

Part of the book series: Polymer Science and Technology ((POLS,volume 25))

Abstract

A substantial effort in this laboratory has been directed toward the synthesis and characterization of acetylene terminated oligomers for use as addition-curable, moisture-resistant, thermoset systems. Early work on the acetylene-terminated phenylquinoxalines1’2 demonstrated the moisture insensitivity of the product generated from the thermal cure. Studies of various difunctional acetylene-terminated monomers has demonstrated3 that the polymerization is a free radical propogation of the acetylene moiety to a linear conjugated polyene. The kinetic chain length of this reaction is unusually short (6–8 acetylene units) and termination is first order.

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References

  1. R. F. Kovar, G. F. L. Ehlers, and F. E. Arnold, “Thermosetting Acetylene Terminated Polyphenylquinoxalines,” J. Polym. Sci., Polym. Chem. Ed., 15:1081 (1977).

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  2. F. L. Hedberg and F. E. Arnold, “New Acetylene Terminated Phenylquinoxaline Oligomers,” J. of Appl. Polym. Sci., 24: 763 (1979).

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  3. J. M. Pickard, E. G. Jones and I. J. Goldfarb, “The Kinetics and Mechanism of the Bulk Thermal Polymerization of Bis-4(3-ethynylphenoxy)phenylsulfone,” Macromol., 12: 895 (1979).

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  4. G. A. Loughran and F. E. Arnold, “Synthesis and Properties of an Acetylene Containing Aryl-Sulfone Resin,” Polym. Prepr., 21: 199 (1980).

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  5. J. J. Harrision, E. T. Sabourin, C. M. Selwitz, W. A. Feld, M. R. Unroe and F. L. Hedberg, “A Novel Low-Cost Route to Acetylene Terminated Resins,” Polym. Prepr., 23: 189 (1982).

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Author information

Authors and Affiliations

  1. Air Force Wright Aeronautical Laboratories, Materials Laboratory, Wright-Patterson AFB, OH, 45433, USA

    B. A. Reinhardt, G. A. Loughran & F. E. Arnold

  2. University of Dayton Research Institute, Dayton, OH, 45469, USA

    E. J. Soloski

Authors
  1. B. A. Reinhardt
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  2. G. A. Loughran
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  3. F. E. Arnold
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  4. E. J. Soloski
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Editor information

Editors and Affiliations

  1. Ashland Chemical Company, Columbus, Ohio, USA

    Bill M. Culbertson

  2. Mississippi State University, Mississippi, Mississippi State, USA

    Charles U. Pittman Jr.

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© 1984 Plenum Press, New York

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Reinhardt, B.A., Loughran, G.A., Arnold, F.E., Soloski, E.J. (1984). Synthesis and Properties of Acetylene Terminated Aryl-Ether Oligomers. In: Culbertson, B.M., Pittman, C.U. (eds) New Monomers and Polymers. Polymer Science and Technology, vol 25. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4619-7_2

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  • DOI: https://doi.org/10.1007/978-1-4684-4619-7_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4621-0

  • Online ISBN: 978-1-4684-4619-7

  • eBook Packages: Springer Book Archive

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