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New Monomers and Polymers pp 201–222Cite as

Quaternization of Condensation Polymers

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Part of the book series: Polymer Science and Technology ((POLS,volume 25))

Abstract

Although the preparation of quaternary ammonium containing resins from appropriately substituted vinyl monomers has been studied extensively1 elaboration of condensation polymers has not received comparable attention. Condensation polymers cannot be prepared with sufficiently high molecular weights or satisfactory chemical stability for most applications involving flocculation or viscosity enhancement. However, the excellent mechanical properties exhibited by many aromatic condensation polymers suggest that speciality applications, in particular, permselective membranes, could be served by suitably modified resins. We have observed that polymers containing oxy-phenylene repeat units are subject to facile electrophilic substitution including chloromethylation; the reactive derivatives can be cast into tough flexible films.2

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Author information

Authors and Affiliations

  1. Department of Chemistry, Louisiana State University, Baton Rouge, LA, 70803, USA

    William H. Daly & Shih-Jen Wu

Authors
  1. William H. Daly
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  2. Shih-Jen Wu
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Editor information

Editors and Affiliations

  1. Ashland Chemical Company, Columbus, Ohio, USA

    Bill M. Culbertson

  2. Mississippi State University, Mississippi, Mississippi State, USA

    Charles U. Pittman Jr.

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© 1984 Plenum Press, New York

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Daly, W.H., Wu, SJ. (1984). Quaternization of Condensation Polymers. In: Culbertson, B.M., Pittman, C.U. (eds) New Monomers and Polymers. Polymer Science and Technology, vol 25. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4619-7_13

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  • DOI: https://doi.org/10.1007/978-1-4684-4619-7_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4621-0

  • Online ISBN: 978-1-4684-4619-7

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