Abstract
Practical flames are normally produced starting from hydrocarbons mixtures often poorly defined from a chemical point of view; they are introduced into the system in the form of liquid and/or solid particles. The presence of regions where the fuel pyrolysis takes place are almost unavoidable given the intrisic times of the vaporization and devolatilization processes. Consequently lighter compounds like C2H2, C2H4 are generated together with heavier ones like Polynuclear Aromatic Hydrocarbons (PAH) and eventually soot particles. In such systems, the development of optical diagnostics for simultaneous presence of different classes of particles and for the greater variety of the hydrocarbon species presents problems different from those in the lean or stoichiometrc combustion of gaseous fuels. Furthermore the flames show intense luminosity, space inhomogeneity and time fluctuations, due to turbulence or massive recirculation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. D’Alessio, A. Cavaliere and P. Menna, Theoretical Models for Interpretation of Light Scattering by Particles Present in Combustion Systems, presented at the workshop “Soot in Combustion Systems and Its Toxic Properties” sponsored by N.A.T.O. and the University of Haute-Alsace, Le Bischenberg, France September 1981.
H. C. van de Hulst, “Light Scattering by Small Particles”, J. Wiley, New York (1957)
F. Beretta, A. Cavalere, and A. D’Alessio, “Experimental and Theoretical Analysis of the Angular Pattern Distribution and Polarization State of the Light Scattered by Isothermal Sprays and Oil Flames”, ASME Winter Annual Meeting, November 15–20, 1981, Washington, D.C., ASME paper 81-WA/HT-49
A. D’Alessio, Laser Light Scattering and Fluorescence Diagnostics of Rich Flames Produced by Gaseous and Liquid Fuels, in: “Particulate Carbon: Formation during Combustion”, D. C. Siegla and G. W. Smith, Eds, Plenum Press, New York (1981)
G. Gouesbet and G. Grehan, The Quasi-Elastic Scattering of Light: A Lecture with Emphasis on Particulate Diagnosis, presented at the workshop “Soot in Combustion Systems and Its Toxic Properties” sponsored by N.A.T.O. and the University of Haute Alsace, Le Bischenberg, France, September 1981
M. Lapp and C. M. Penney, Eds., “Laser Raman Gas Diagnostics”, Plenum Press, New York (1974)
R. Goulard, Ed., “Combustion Measurements”, Part II, Session 6, Academic Press, New York (1976)
A. C. Eckbreth, P. A. Boneziek and S. F. Verdieck, Combustion Diagnostics by Laser Raman and Fluorescence Techniques, Prog. Energy Combustion Sci. 5: 253 (1979)
R. S. Hall and A. C. Eckbreth, Coherent Anti-Stokes Raman Spectroscopy (CARS): Application to Combustion Diagnostics, to be published in Laser Applications, Vol. 5
D. A. Stephenson, Raman Cross Sections of Selected Hydrocarbons and Freon, S. Quant. Spectrosc. Radiat. Transfer 14: 1291 (1974)
I. B. Berlman, “Fluorescence Spectra of Aromatic Molecules”, Academic Press, New York (1971)
H. N. Jaffè and M. Orchin, “Theory and Application of Ultraviolet Spectroscopy, J. Wiley, New York (1962)
E. Clar, “Polycyclic Hydrocarbons”, Vol. 1 and 2, Academic Press, London (1974)
J. D. Winefordner, S. G. Schulman and T. C. O’Have r, “Luminescence Spectrometry in Analytical Chemistry”, J. Wiley, New York (1972)
A. Di Lorenzo, A. D’Alessio, V. Cincotti, S. Masi, P. Menna and C. Venitozzi, “U.V. Absorption, Laser Excited Fluorescence and Direct Sampling in Rich CH4/02 Flames’;, Eighteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1981)
R. Barbella, F. Beretta, A. Ciajolo and A. D’Alessio, “Laser Excited Fluorescence and Chromatographic Techniques for the Determination of PAH on a Spray Oil Flame”, paper presented at the Sixth International Symposium on Polynuclear Aromatic Hydrocarbons, Battelle Laboratories, Columbus,Ohio, October 1981
G. P. Prado, M. L. Lee, R. A. Hites, D. P. Hoult and J. B. Howard, “Soot and Hydrocarbon Formation in a Turbulent Diffusion Flame”, Sixteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1981)
A. D’Alessio, A. Di Lorenzo, A. F. Sarofim, F. Beretta, S. Masi and C. Venitozzi, “Soot Formation in Methane-Oxygen Flames”, Fifteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1975)
T. Deinum, D. J. Werkhoven, J. Langelaer, R. P. H. Rettschuick and J. D. W. Van Voorst, Sequence Congestion and Temperature Effects on the Fluorescence of Isolated Pyrene Molecules, Chem. Phys. Lett. 27: 206 (1974)
D. S. Coe, B. S. Haynes and J. I. Steinfeld, Identification of a Source of Argon-Ion-Laser Excited Fluorescence in Sooting Flames, Combustion and Flame 43: 211 (1981)
F. Beretta, A. D’Alessio and C. Noviello, in the Research Report “Sugli studi di Fiamme con Metodi Chimico-Fisici” conducted by the Istituto di Ricerche sulla Combustione - C.N.R., Naples under ENEL/CRTN contract (1975)
F. Beretta, A. Cavaliere, A. D’Alessio and C. Noviello, Visible and U.V. Spectral Emission and Extinction Measurements in Oil Spray Flames, Comb. Sci. Techn. 22: 1 (1980)
K. Sassen, Infrared (10.6 nm) Scattering and Extinction in Laboratory Water and Ice Clouds, Applied Optics 1: 185 (1981)
P.A.R. Tech. Publ. T - 198A
B. S. Haynes and H. Gg. Wagner, Soot Formation, Progr. Energy Comb. Sci. 7: 229 (1981)
A. D’Alessio, A. Di Lorenzo, A. Borghese, F. Beretta and S. Masi, “Study of the Soot Nucleation Zone of Rich Methane-Oxygen Flames”, Sixteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1977)
B. S. Haynes, H. Jander and H. Gg. Wagner, “The Effects of Metal Additives on the Formation of Soot in Premixed Flames”, Seventeenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1979)
G. Prado, J. Jagoda, K. Neoh and J. Lahaye, “A Study of Soot Formation in Premixed Propane/Oxygen Flames by In-Situ Optical Techniques and Sampling Probes”, Eighteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1981)
K. Müller-Dethlefs, ph. D. Thesis, Imperial College, London (1979)
P. Henna, unpublished results
E. A. Taft, private communication (1969)
D. S. Coe and J. I. Steinfeld, Fluorescence Excitation and Emission Spectra of Polycyclic Aromatic Hydrocarbons in an Atmospheric Flame, Chem. Phys. Lett. 76: 485 (1980)
F. Beretta, A. Cavaliere and A. D’Alessio, Laser Excited Fluorescence Measurements in Spray Oil Flames for the Detection of Polycyclic Aromatic Hydrocarbons and Soot, Comb. Sci. Techn. 27: 113 (1982)
F. Beretta, A. Cavaliere, A. Ciajolo, A. D’Alessio, C. Langella, A. Di Lorenzo and C. Noviello, “Laser Light Scattering, Emission/Extinction Spectroscopy and Thermogravimetric Analysis in the Study of Soot Behaviour in Oil Spray Flames”, Eighteenth Symposium (Intern’l) on Combustion, The Combustion Institute, Pittsburgh (1981).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Plenum Press, New York
About this chapter
Cite this chapter
D’Alessio, A., Beretta, F., Cavaliere, A., Menna, P. (1983). Laser Light Scattering and Fluorescence in Fuel Rich Flames: Techniques and Selected Results. In: Lahaye, J., Prado, G. (eds) Soot in Combustion Systems and Its Toxic Properties. NATO Conference Series, vol 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4463-6_18
Download citation
DOI: https://doi.org/10.1007/978-1-4684-4463-6_18
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-4465-0
Online ISBN: 978-1-4684-4463-6
eBook Packages: Springer Book Archive