Abstract
Solvent extraction is a classical technique for the isolation and separation of organic and inorganic compounds from more or less complicated mixtures. In the traditional approach, organic substances are separated in uncharged form and the extraction degree is then regulated only by the character of the organic phase and, if the analytes are protolytes, by the pH of the aqueous phase. An important increase in the flexibility of both the efficiency and selectivity of an extraction can be achieved when complex-forming agents participate in the distribution equilibria. Such an approach is furthermore the only possibility for charged compounds and for very hydrophilic compounds. In metal extraction work this principle is necessary and has a rather long tradition.(1) It has, however, frequently, especially in later years, also been applied to the extraction of organic compounds and this is the main subject for the present review.
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Schill, G., Westerlund, D. (1982). Ion-Pairing Reactions in Analytical Chemistry. In: Frei, R.W., Lawrence, J.F. (eds) Chemical Derivatization in Analytical Chemistry. Modern Analytical Chemistry, vol 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4202-1_2
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