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Structural, Magnetic, and Charge-Transport Properties of Stacked Metal Chelate Complexes

  • Chapter
Extended Linear Chain Compounds

Abstract

Intense effort devoted to the synthesis and physical characterization of crystals containing stacked, planar, transition-metal chelate complexes has yielded many materials of widely divergent properties. Some are primarily of structural interest. Others have unusual magnetic properties; for example, the first well-documented instance of a spin Peierls transition (a solid state analogue of the Jahn-Teller effect) was observed in such a material.1 Yet others exhibit high or unusual electrical conductivities, and the greatest effort is currently being expended toward the understanding and control of charge-transport properties in molecular crystals. Here compounds prepared from metallomacrocycles are of particular interest and challenge. For example, with phthalocyaninatonickel iodide, Ni(pc)I,† a high, metallike conductivity along the stacking axis is achieved,2,3 whereas bis(diphenylglyoximato)nickel iodide, Ni(dpg)I,4 has the same structural motif but exhibits much lower conductivity. To understand and control such divergent physical properties in related solid state structures has engendered considerable research, particularly since the possibility exists of tailor-making compounds with specific transport properties through well-defined chemical modifications.

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References

  1. Interrante, L. V., Bray, J. W., Hart, H. R., Jr., Jacobs, I. S., Kasper, J. S., Piacente, P. A., and Bonner, J. C., Quasi One-Dimensional Conductors II, Lecture Notes in Physics, No. 96, Springer, New York (1979), pp. 55–68.

    Book  Google Scholar 

  2. Schramm, C. J., Scaringe, R. P., Stojakovic, D. R., Hoffman, B. M., Ibers, J. A., and Marks, T. J., J. Am. Chem. Soc. 102, 6702 (1980).

    Article  Google Scholar 

  3. Schramm, C. J., Stojakovic, D. R., Hoffman, B. M., and Marks, T. J., Science 200, 47 (1978).

    Article  Google Scholar 

  4. Cowie, M., Gleizes, A., Grynkewich, G. W., Kalina, D. W., McClure, M. S., Scaringe, R. P., Teitelbaum, R. C., Ruby, S. L., Ibers, J. A., Kannewurf, C. R., and Marks, T. J., J. Am. Chem. Soc. 101, 2921 (1979).

    Article  Google Scholar 

  5. Miller, J. S., and Epstein, A. J., Prog. Inorg. Chem. 20, 1 (1976).

    Article  Google Scholar 

  6. Williams, J. M., Schultz, A., Underhill, A. E., and Carnerio, K., in Extended Linear Chain Compounds, Vol. 1, J. Miller, Ed., Plenum Press, New York (1981), p. 73.

    Google Scholar 

  7. Underhill, A. E., Watkins, D. M., Williams, J. M., and Carnerio, K., in Extended Linear Chain Compounds, Vol. 1, J. Miller, Ed., Plenum Press, New York (1981), p. 119.

    Google Scholar 

  8. Keller, H. J., Ed., Low-Dimensional Cooperative Phenomena, Plenum Press, New York (1975).

    Google Scholar 

  9. Miller, J. S., and Epstein, A. J., Eds., Synthesis and Properties of Low-Dimensional Materials, Ann. N.Y. Acad. Sci. 313 (1978).

    Google Scholar 

  10. Keller, H. J., Ed., Chemistry and Physics of One-Dimensional Metals, Plenum Press, New York (1977).

    Google Scholar 

  11. Hatfield, W. E., Ed., Molecular Metals, Plenum Press, New York (1979).

    Google Scholar 

  12. Devreese, J. T., Evrard, R. P., and Van Doren, V. E., Eds., Highly Conducting One-Dimensional Solids, Plenum Press, New York (1979).

    Google Scholar 

  13. Berlinsky, A. J., Contemp. Phys. 17, 331 (1976).

    Article  Google Scholar 

  14. Barišić, S., Bjeliš, A., Cooper, J. R., and Leontic, B., Eds., Quasi One-Dimensional Conductors I, Lecture Notes in Physics, No. 95, Springer, New York (1979).

    Google Scholar 

  15. Barišić, S., Bjeliš, A., Cooper, J. R., and Leontic, B., Eds., Quasi One-Dimensional Conductors II, Lecture Notes in Physics, No. 96, Springer, New York (1979).

    Google Scholar 

  16. Soos, Z. G., Ann. Rev. Phys. Chem. 25, 121 (1974).

    Article  Google Scholar 

  17. Soos, Z. G., and Klein, D. J., in Molecular Association, Vol. 1, R. Foster, Ed., Academic Press, New York (1979), pp. 1–119.

    Google Scholar 

  18. Williams, R. M., and Wallwork, S. C., Acta Crystallogr. 23, 448 (1967).

    Article  Google Scholar 

  19. Torrance, J. B., in Synthesis and Properties of Low-Dimensional Materials, Ann. N.Y. Acad. Sci. 313 (1978), pp. 210–233.

    Google Scholar 

  20. Torrance, J. B., Acc. Chem. Res. 12, 79 (1979).

    Article  Google Scholar 

  21. Gutman, F., and Lyons, L. E., Organic Semiconductors, John Wiley & Sons, New York (1967).

    Google Scholar 

  22. Mott, N. F., and Davis, E. A., Electronic Processes in Non-Crystalline Materials, Clarendon Press, Oxford (1971).

    Google Scholar 

  23. Beni, G., Holstein, T., and Dincus, P., Phys. Rev. B 8, 312 (1973).

    Article  Google Scholar 

  24. Klein, D. J., Phys. Rev. B 8, 3452 (1973).

    Article  Google Scholar 

  25. Bailey, A. S., Williams, R. J. P., and Wright, J. D., J. Chem. Soc, 2579 (1965).

    Google Scholar 

  26. Koizumi, S., and Iida, Y., Bull. Chem. Soc. Jpn. 46, 629 (1973).

    Article  Google Scholar 

  27. Prout, C. K., and Powell, H. M., J. Chem. Soc, 4882 (1965).

    Google Scholar 

  28. Koizumi, S., and Iida, Y., Bull. Chem. Soc. Jpn. 44, 1436 (1970).

    Article  Google Scholar 

  29. Iida, Y., Bull. Chem. Soc. Jpn. 44, 2564 (1971).

    Article  Google Scholar 

  30. Kamenar, B., Prout, C. K., and Wright, J. D., J. Chem. Soc. A 661 (1966).

    Google Scholar 

  31. Kamenar, B., Prout, C. K., and Wright, J. D., J. Chem. Soc., 4851 (1965).

    Google Scholar 

  32. Bailey, A. S., and Prout, C. K., J. Chem. Soc., 4867 (1965).

    Google Scholar 

  33. Murray-Rust, P., and Wright, J. D., J. Chem. Soc. A 247 (1968).

    Google Scholar 

  34. Schmitt, R. D., Wing, R. M., and Maki, A. H., J. Am. Chem. Soc. 91, 4394 (1969).

    Article  Google Scholar 

  35. Wheland, R. C., and Gillson, J. L., J. Am. Chem. Soc. 98, 3916 (1976).

    Article  Google Scholar 

  36. Keller, H. J., Leichert, L., Mégnamisi-Bélombé, M., Nöthe, D., and Weiss, J., Z. Anorg. Allg. Chem. 429, 231 (1977).

    Article  Google Scholar 

  37. Keller, H. J., Leichert, L., Mégnamisi-Bélombé, M., Moroni, W., Nöthe, D., and Weiss, J., Mol. Cryst. Liq. Cryst. 32, 155 (1976).

    Article  Google Scholar 

  38. Mayerle, J. J., Inorg. Chem. 16, 916 (1977).

    Article  Google Scholar 

  39. King, A. W., Swann, D. A., and Waters, T. N., J. Chem. Soc. Dalton Trans., 1819 (1973).

    Google Scholar 

  40. Castellano, E. E., Hodder, O. J. R., Prout, C. K., and Sadler, P. J., J. Chem. Soc. A, 2620 (1971).

    Google Scholar 

  41. Cassoux, P., and Gleizes, A., Inorg. Chem. 19, 665 (1980).

    Article  Google Scholar 

  42. Matsumoto, N., Nonaka, Y., Kida, S., Kawano, S., and Ueda, L., Inorg. Chim. Acta 37, 27 (1979).

    Article  Google Scholar 

  43. Grigg, R., Trocha-Grimshaw, J., and King, T. J., J. Chem. Soc. Chem. Commun., 571 (1978).

    Google Scholar 

  44. Piovesana, O., Bellitto, C., Flamini, A., and Zanazzi, P. F., Inorg. Chem. 18, 2258 (1979).

    Article  Google Scholar 

  45. Pace, L. J., Ulman, A., and Ibers, J. A., Inorg. Chem., 21, 199 (1982).

    Article  Google Scholar 

  46. Jacobs, I. S., Hart, H. R., Jr., Interrante, L. V., Bray, J. W., Kasper, J. S., Watkins, G. D., Prober, D. E., Wolf, W. P., and Bonner, J. C. Physica B + C 86-88, 655 (1977).

    Article  Google Scholar 

  47. Bray, J. W., Hart, H. R., Jr., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Watkins, G. D., Wee, S. H., and Bonner, J. C., Phys. Rev. Lett. 35, 744 (1975).

    Article  Google Scholar 

  48. Kasper, J. S., and Interrante, L. V., Acta Crystallogr. B32, 2914 (1976).

    Google Scholar 

  49. Jacobs, I. S., Bray, J. W., Hart, H. R., Jr., Interrante, L. V., Kasper, J. S., Watkins, G. D., Prober, D. E., and Bonner, J. C., Phys. Rev. B 14, 3036 (1976).

    Article  Google Scholar 

  50. Delker, G., Ph.D. thesis, University of Illinois, 1979.

    Google Scholar 

  51. Bonner, J. C., Wei, T. S., Hart, H. R., Jr., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Watkins, G. D., and Blôte, H. W. J., J. Appl. Phys. 49, 1321 (1978).

    Article  Google Scholar 

  52. Kasper, J. S., and Moncton, D. E., Phys. Rev. B 20, 2341 (1979).

    Article  Google Scholar 

  53. Moncton, D. E., Birgeneau, R. J., Interrante, L. V., and Wudl, F., Phys. Rev. Lett. 39, 507 (1977).

    Article  Google Scholar 

  54. Ehrenfreund, E., and Smith, L. S., Phys. Rev. B 16, 1870 (1977).

    Article  Google Scholar 

  55. Smith, L. S., Ehrenfreund, E., Heeger, A. J., Interrante, L. V., Bray, J. W., Hart, H. R., Jr., and Jacobs, I. S., Solid State Commun. 19, 377 (1976).

    Article  Google Scholar 

  56. Wei, T. S., Heeger, A. J., Salamon, M. B., and Delker, G. E., Solid State Commun. 21, 595 (1977).

    Article  Google Scholar 

  57. Geiger, W. E., Jr., and Maki, A. H., J. Phys. Chem. 75, 2387 (1971).

    Article  Google Scholar 

  58. Singhabhandhu, A., Robinson, P. D., Fang, J. H., and Geiger, W. E., Jr., Inorg. Chem. 14, 318 (1975).

    Article  Google Scholar 

  59. Vu Dong, Endres, H., Keller, H. J., Moroni, W., and Nöthe, D., Acta Crystallogr. B33, 2428 (1977).

    Google Scholar 

  60. Endres, H., Keller, H. J.; Moroni, W., and Nöthe, D., Acta Crystallogr. B35, 353 (1979).

    Google Scholar 

  61. Rundle, R. E., J. Am. Chem. Soc, 76, 3101 (1954).

    Article  Google Scholar 

  62. Yamada, S., and Tsuchida, R., Bull. Chem. Soc. Jpn. 30, 715 (1957).

    Article  Google Scholar 

  63. Hara, Y., Shirotani, I., and Onodera, A., Solid State Commun. 19, 171 (1976).

    Article  Google Scholar 

  64. Wing, R. M., and Schlupp, R. L., Inorg. Chem. 9, 471 (1970).

    Article  Google Scholar 

  65. Jacobs, I. S., Interrante, L. V., and Hart, H. R., Jr., A.I.P. Conf. Proc. 24, 355 (1975).

    Google Scholar 

  66. Herbstein, F. H., Perspect. Struct. Chem. 4, 166 (1971).

    Google Scholar 

  67. Chappell, J. S., Bloch, A. N., Bryden, W. A., Maxfield, M., Poehler, T. O., and Cowan, D. O., J. Am. Chem. Soc. 103, 2442 (1981).

    Article  Google Scholar 

  68. Reis, A. H., Jr., Preston, L. D., Williams, J. M., Peterson, S. W., Candela, G. A., Swartzendruber, L. J., and Miller, J. S., J. Am. Chem. Soc. 101, 2756 (1979).

    Article  Google Scholar 

  69. Mayoh, B., and Prout, C. K., J. Chem. Soc. Faraday Trans. 2, 1072 (1972).

    Google Scholar 

  70. Mazumdar, S., and Soos, Z. G., Synth. Met. 1, 77 (1979/1980).

    Article  Google Scholar 

  71. Soos, Z. G., and Mazumdar, S., Phys. Rev. B 18, 1991 (1978).

    Article  Google Scholar 

  72. Bonner, J. C., and Fisher, M. E., Phys. Rev. 135, A640 (1964).

    Article  Google Scholar 

  73. McConnell, H. M., and Lynden-Bell, R., J. Chem. Phys. 36, 2393 (1962).

    Article  Google Scholar 

  74. Chestnut, D. B., J. Chem. Phys. 45, 4677 (1966).

    Article  Google Scholar 

  75. Pincus, P., Solid State Commun. 9, 1971 (1971).

    Article  Google Scholar 

  76. Beni, G., and Pincus, P., J. Chem. Phys., 57, 3531 (1972).

    Article  Google Scholar 

  77. Beni, G., J. Chem. Phys. 58, 3200 (1973).

    Article  Google Scholar 

  78. Dubois, J. Y., and Carton, J. P., J. Phys. (Paris) 35, 371 (1974).

    Article  Google Scholar 

  79. Luther, A., and Peschel, I., Phys. Rev. B 12, 3908 (1975).

    Article  Google Scholar 

  80. Pytte, E., Phys. Rev. B 10, 4637 (1974).

    Article  Google Scholar 

  81. Yamada, S., Bull. Chem. Soc. Jpn. 24, 125 (1951).

    Article  Google Scholar 

  82. Eisenberg, R., Prog. Inorg. Chem. 12, 295 (1970).

    Article  Google Scholar 

  83. Gray, H. B., Trans. Met. Chem. 1, 239 (1965).

    Google Scholar 

  84. Livingstone, S. E., Q. Rev. Chem. Soc. 19, 386 (1965).

    Article  Google Scholar 

  85. McCleverty, J. A., Prog. Inorg. Chem. 10, 49 (1968).

    Article  Google Scholar 

  86. Hove, M. J., Hoffman, B. M., and Ibers, J. A., J. Chem. Phys. 56, 3490 (1972).

    Article  Google Scholar 

  87. Endres, H., Keller, H. J., Moroni, W., Nöthe, D., and Vu Dong, Acta Crystallogr. B34, 1823 (1978).

    Google Scholar 

  88. Kasper, J. S., Interrante, L. V., and Secaur, C. A., J. Am. Chem. Soc. 97, 890 (1975).

    Article  Google Scholar 

  89. Interrante, L. V., Browall, K. W., Hart, H. R., Jr., Jacobs, L S., Watkins, G. D., and Wee, S. H., J. Am. Chem. Soc. 97, 889 (1975).

    Article  Google Scholar 

  90. Interrante, L. V., Bray, J. W., Hart, H. R., Jr., Kasper, J. S., Piacente, P. A., and Watkins, G. D., J. Am. Chem. Soc. 99, 3523 (1977).

    Article  Google Scholar 

  91. Interrante, L. V., Bray, J. W., Hart, H. R., Jr., Kasper, J. S., Piacente, P. A., and Watkins, G. D., in Synthesis and Properties of Low-Dimensional Materials, Ann. N.Y. Acad. Sci. 313 (1978), pp. 407–416.

    Google Scholar 

  92. Bray, J. W., Hart, H. R., Jr., Interrante, L. V., Jacobs, I. S., Kasper, J. S., Piacente, P. A., and Watkins, G. D., Phys. Rev. B 16, 1359 (1977).

    Article  Google Scholar 

  93. Forrester, J. D., Zalkin, A., and Templeton, D. H., Inorg. Chem. 3, 1507 (1964).

    Article  Google Scholar 

  94. Davison, A., Edelstein, N., Holm, R. H., and Maki, A. H., Inorg. Chem. 2, 1227 (1963).

    Article  Google Scholar 

  95. Maki, A. H., Edelstein, N., Davison, A., and Holm, R. H., J. Am. Chem. Soc. 86, 4580 (1964).

    Article  Google Scholar 

  96. Schmitt, R. D., and Maki, A. H., J. A. Chem. Soc. 90, 2288 (1968).

    Article  Google Scholar 

  97. Hamilton, W. C., and Bernai, L., Inorg. Chem. 6, 2003 (1967).

    Article  Google Scholar 

  98. Weiher, J. F., Melby, L. R., and Benson, R. E., J. Am. Chem. Soc. 86, 4329 (1964).

    Article  Google Scholar 

  99. Williams, R., Billig, E., Waters, J. H., and Gray, H. B., J. Am. Chem. Soc. 88, 43 (1966).

    Article  Google Scholar 

  100. Kobayashi, A., and Yukiyoshi, S., Bull. Chem. Soc. Jpn. 50, 2650 (1977).

    Article  Google Scholar 

  101. Perez-Albuerne, N. A., Isett, L. C., and Haller, R. K., J. Chem. Soc. Chem. Commun., 417 (1977).

    Google Scholar 

  102. Davison, A., Edelstein, N., Holm, R. H., and Maki, A. H., J. Am. Chem. Soc. 85, 2029 (1963).

    Article  Google Scholar 

  103. Fritchie, C. J., Jr., Acta Crystallogr. 20, 107 (1966).

    Article  Google Scholar 

  104. Baker-Hawkes, M. J., Billig., E., and Gray, H. B., J. Am. Chem. Soc. 88, 4870 (1966).

    Article  Google Scholar 

  105. Baker-Hawkes, M. J., Dori, Z., Eisenberg, R., and Gray, H. B., J. Am. Chem. Soc. 90, 4253 (1968).

    Article  Google Scholar 

  106. Enemark, J. H., and Ibers, J. A., Inorg. Chem. 7, 2636 (1968).

    Article  Google Scholar 

  107. Lauher, J. W., and Ibers, J. A., Inorg. Chem. 14, 640 (1975).

    Article  Google Scholar 

  108. Cassoux, P., Interrante, L., and Kasper, J., Mol. Cryst. Liq. Cryst. 81, 293 (1982).

    Article  Google Scholar 

  109. Bekaroglu, Ö., El Sharif, M., Endres, H., and Keller, H. J., Acta Crystallogr. B32, 2983 (1976).

    Google Scholar 

  110. Beurskens, P. T., Blaauw, H. J. A., Cras, J. A., and Steggerda, J. J., Inorg. Chem. 7, 805 (1968).

    Article  Google Scholar 

  111. Beurskens, P. T., Cras, J. A., and van der Linden, J. G. M., Inorg. Chem. 9, 475 (1970).

    Article  Google Scholar 

  112. Alcácer, L., and Maki, A. H., J. Phys. Chem. 78, 215 (1974).

    Article  Google Scholar 

  113. Alcácer, L., and Maki, A. H., J. Phys. Chem. 80, 1912 (1976).

    Article  Google Scholar 

  114. Alcácer, L., Novais, H., and Pedroso, F., in Molecular Metals, W. E. Hatfield, Ed., Plenum Press, New York (1979), pp. 415–418.

    Google Scholar 

  115. Plumlee, K. W., Hoffman, B. M., Ibers, J. A., and Soos, Z. G., J. Chem. Phys. 63, 1926 (1975).

    Article  Google Scholar 

  116. Plumlee, K. W., Ph.D. thesis, Northwestern University, 1975.

    Google Scholar 

  117. Plumlee, K. W., Hoffman, B. M., Ratajack, M. T., and Kannewurf, C. R., Solid State Commun. 15, 1651 (1974).

    Article  Google Scholar 

  118. Davison, A., Howe, D. V., and Shawl, E. T., Inorg. Chem. 6, 458 (1967).

    Article  Google Scholar 

  119. Hoffman, B. M., unpublished results.

    Google Scholar 

  120. Senftleber, F. C., and Geiger, W. E., Jr., Inorg. Chem. 17, 3615 (1978).

    Article  Google Scholar 

  121. Underhill, A. E., and Ahmad, M. M., J. Chem. Soc. Chem. Commun., 67 (1981).

    Google Scholar 

  122. Underhill, A. E., and Ahmad, M. M., Mol. Cryst. Liq. Cryst. 81, 223 (1982).

    Article  Google Scholar 

  123. Petersen, J. L., Schramm, C. J., Stojakovic, D. R., Hoffman, B. M., and Marks, T. J., J. Am. Chem. Soc. 99, 286 (1977).

    Article  Google Scholar 

  124. Hoffman, B. M., Phillips, T. E., Schramm, C. J., and Wright, S. K., in Molecular Metals, W. E. Hatfield, Ed., Plenum Press, New York (1979), pp. 393–398.

    Google Scholar 

  125. Phillips, T. E., and Hoffman, B. M., J. Am. Chem. Soc. 99, 7734 (1977).

    Article  Google Scholar 

  126. Phillips, T. E., Scaringe, R. P., Hoffman, B. M., and Ibers, J. A., J. Am. Chem. Soc. 102, 3435 (1980).

    Article  Google Scholar 

  127. Hoffman, B. M., Phillips, T. E., and Soos, Z. G., Solid State Commun. 33, 51 (1980).

    Article  Google Scholar 

  128. Schramm, C. J., Ph.D. thesis, Northwestern University, 1979.

    Google Scholar 

  129. Euler, W. B., Martinsen, J., Pace, L. J., Hoffman, B. M., and Ibers, J. A., Mol. Cryst. Liq. Cryst. 81, 231 (1982).

    Article  Google Scholar 

  130. Nohr, R. S., Kuznesof, P. M., Wynne, K. J., Kenney, M. E., and Siebenman, P. G., J. Am. Chem. Soc. 103, 4371 (1981).

    Article  Google Scholar 

  131. Wynne, K., and Nohr, R. S., Mol. Cryst. Liq. Cryst. 81, 243 (1982).

    Article  Google Scholar 

  132. Martinsen, J., Schramm, C. J., Euler, W. B., Pace, L. J., Hoffman, B. M., and Ibers, J. A., manuscript in preparation.

    Google Scholar 

  133. Martinsen, J., Pace, L. J., Phillips, T. E., Hoffman, B. M., and Ibers, J. A., J. Am. Chem. Soc. 104, 83 (1982).

    Article  Google Scholar 

  134. Euler, W. B., Martinsen, J., Pace, L. J., Hoffman, B. M., and Ibers, J. A., manuscript in preparation.

    Google Scholar 

  135. Wright, S. K., Schramm, C. J., Phillips, T. E., Scholler, D. M., and Hoffman, B. M., Synth. Met. 1, 43 (1979/1980).

    Article  Google Scholar 

  136. Pace, L. J., Martinsen, J., Ulman, A., Hoffman, B. M., and Ibers, J. A., manuscript in preparation.

    Google Scholar 

  137. Schoch, K. F., Jr., Kundalkar, B. R., and Marks, T. J., J. Am. Chem. Soc. 101, 7071 (1979).

    Article  Google Scholar 

  138. Schneider, O., Metz, J., and Hanack, M., Mol. Cryst. Liq. Cryst. 81, 273 (1982).

    Article  Google Scholar 

  139. Hanack, M., Mitulla, K., Pawlowski, G., and Subramanian, L. R., J. Organomet. Chem. 204, 315 (1981).

    Article  Google Scholar 

  140. Smith, K. M., Ed., Porphyrins and Metalloporphyrins, American Elsevier, New York (1975).

    Google Scholar 

  141. Dolphin, D., Ed., The Porphyrins, Academic Press, New York (1978).

    Google Scholar 

  142. Lever, A. B. P., Adv. Inorg. Chem. Radiochem. 7, 27 (1965).

    Article  Google Scholar 

  143. Jackson, A. H., The Porphyrins, Vol. I., Academic Press, New York (1978), pp. 365–386.

    Google Scholar 

  144. Ulman, A., Gallucci, J., Fisher, D., and Ibers, J. A., J. Am. Chem. Soc. 102, 6852 (1980).

    Article  Google Scholar 

  145. Schramm, C. J., and Hoffman, B. M., Inorg. Chem. 19, 383 (1980).

    Article  Google Scholar 

  146. Called, M., Ferraris, G., and Viterbo, D., Inorg. Chim. Acta 1, 297 (1967).

    Article  Google Scholar 

  147. Called, M., Ferraris, G., and Viterbo, D., Acta Crystallogr. 22, 468 (1967).

    Article  Google Scholar 

  148. Murmann, R. K., and Schlemper, E. O., Acta Crystallogr. 23, 667 (1967).

    Article  Google Scholar 

  149. Ferraris, G., and Viterbo, D., Acta Crystallogr. B25, 2066 (1969).

    Google Scholar 

  150. Godycki, L. E., and Rundle, R. E., Acta Crystallogr. 6, 487 (1953).

    Article  Google Scholar 

  151. Williams, D. E., Wohlauer, G., and Rundle, R. E., J. Am. Chem. Soc. 81, 755 (1959).

    Article  Google Scholar 

  152. Gomm, P. S., Thomas, T. W., and Underhill, A. E., J. Chem. Soc. A, 2154 (1971).

    Google Scholar 

  153. Bowers, R. H., Banks, C. V., and Jacobson, R. A., Acta Crystallogr. B28, 2318 (1972).

    Google Scholar 

  154. Frasson E., and Panattoni, C., Acta Crystallogr. 13, 893 (1960).

    Article  Google Scholar 

  155. Frasson, E., Panattoni, C., and Zannetti, R., Acta Crystallogr. 12, 1027 (1959).

    Article  Google Scholar 

  156. Endres, H., Keller, H. J., van de Sand, H., and Vu Dong, Z., Naturforsch. 33b, 843 (1978).

    Google Scholar 

  157. Leichert, I., and Weiss, J., Acta Crystallogr. B31, 2877 (1975).

    Google Scholar 

  158. Brill, J. W., Mégnamisi-Bélombé, M., and Novotny, M., J. Chem. Phys. 68, 585 (1978).

    Article  Google Scholar 

  159. Leichert, I., and Weiss, J., Acta Crystallogr. B31, 2709 (1975).

    Google Scholar 

  160. Endres, H., Mégnamisi-Bélombé, M., Little, W. A., and Wolfe, C. R., Acta Crystallogr. B35, 169 (1979).

    Google Scholar 

  161. Mégnamisi-Bélombé, M., J. Solid State Chem. 27, 389 (1979).

    Article  Google Scholar 

  162. Mégnamisi-Bélombé, M., J. Solid State Chem. 22, 151 (1977).

    Article  Google Scholar 

  163. Brown, L. D., Kalina, D. W., McClure, M. S., Schultz, S., Ruby, S. L., Ibers, J. A., Kannewurf, C. R., and Marks, T. J., J. Am. Chem. Soc. 101, 2937 (1979).

    Article  Google Scholar 

  164. Endres, H., Keller, H. J., Moroni, W., and Weiss, J., Acta Crystallogr. B31, 2357 (1975).

    Google Scholar 

  165. Endres, H., Keller, H. J., Mégnamisi-Bélombé, M., Moroni, W., Pritzkow, H., Weiss, J., and Cornés, R., Acta Crystallogr. A32, 954 (1976).

    Google Scholar 

  166. Endres, H., Mégnamisi-Bélombé, M., Keller, H. J., and Weiss, J., Acta Crystallogr. B32, 457 (1976).

    Google Scholar 

  167. Pritzkow, H., Z. Naturforsch. 31b, 401 (1976).

    Google Scholar 

  168. Foust, A. S., and Soderberg, R. H., J. Am. Chem. Soc. 89, 5507 (1967).

    Article  Google Scholar 

  169. Endres, H., Keller, H. J., Lehmann, R., and Weiss, J., Acta Crystallogr. B32, 627 (1976).

    Google Scholar 

  170. Kalina, D. W., Lyding, J. W., Ratajack, M. T., Kannewurf, C. R., and Marks, T. J., J. Am. Chem. Soc. 102, 7854 (1980).

    Article  Google Scholar 

  171. Underhill, A. E., Watkins, D. M., and Pethig, R., Inorg. Nucl. Chem. Lett. 9, 1269 (1973).

    Article  Google Scholar 

  172. Edelman, L. E., J. Am. Chem. Soc. 72, 5765 (1950).

    Article  Google Scholar 

  173. Lin, L.-S., Marks, T. J., Kannewurf, C. R., Lyding, J. W., McClure, M. S., Ratajack, M. T., and Whang, T.-C., J. Chem. Soc. Chem. Commun., 954 (1980).

    Google Scholar 

  174. Wuu, Y.-M., and Peng, S.-M., J. Inorg. Nucl. Chem. 42, 205 (1980).

    Article  Google Scholar 

  175. Wuu, Y.-M., Peng, S.-M., and Chang, H., J. Inorg. Nucl. Chem. 42, 839 (1980).

    Article  Google Scholar 

  176. Hatfield, W. E., private communication.

    Google Scholar 

  177. Scaringe, R. P., and Ibers, J. A., Acta Crystallogr. A35, 803 (1979).

    Google Scholar 

  178. Teitelbaum, R. C., Ruby, S. L., and Marks, T. J., J. Am. Chem. Soc. 100, 3215 (1978).

    Article  Google Scholar 

  179. Teitelbaum, R. C., Ruby, S. L., and Marks, T. J., J. Am. Chem. Soc. 102, 3322 (1980).

    Article  Google Scholar 

  180. Mertes, K. B., and Ferraro, J. R., J. Chem. Phys. 70, 646 (1979).

    Article  Google Scholar 

  181. Jircitano, A. J., Timken, M. D., Mertes, K. B., and Ferraro, J. P., J. Am. Chem. Soc. 101, 7661 (1979).

    Article  Google Scholar 

  182. Jircitano, A. J., Colton, M. C., and Mertes, K. B., Inorg. Chem. 20, 890 (1981).

    Article  Google Scholar 

  183. Wolberg, A., and Manassen, J., J. Am. Chem. Soc. 92, 2982 (1970).

    Article  Google Scholar 

  184. Lever, A. B. P., and Wiltshire, J. P., Can. J. Chem. 54, 2514 (1976).

    Article  Google Scholar 

  185. Dolphin, D., Ed., The Porphyrins, Vol. V., Academic Press, New York (1978).

    Google Scholar 

  186. Bobrovskii, A. P., and Sidorov, A. N., J. Struct. Chem. (Engl. Transi.) 17, 50 (1976).

    Article  Google Scholar 

  187. Tomkiewicz Y., Taranko, A. R., and Torrance, J. B., Phys. Rev. Lett. 36, 751 (1976).

    Article  Google Scholar 

  188. Mégnamisi-Bélombé, M., Z. Anorg. Allg. Chem. 473, 196 (1981).

    Article  Google Scholar 

  189. Kübel, F., and Strähle, J., Z. Naturforsch. 36b, 441 (1981).

    Google Scholar 

  190. Endres, H., Keller, H. J., Lehmann, R., Poveda, A., Rupp, H. H., and van de Sand, H., Z. Naturforsch. 32b, 516 (1977).

    Google Scholar 

  191. Egneus, B., Anal Chim. Acta 48, 291 (1969).

    Article  Google Scholar 

  192. Mehne, L. F., and Wayland, B. B., Inorg. Chem. 14, 881 (1975).

    Article  Google Scholar 

  193. Reddy, J. W., Knox, K., and Robin, M. B., J. Chem. Phys. 40, 1082 (1964).

    Article  Google Scholar 

  194. Miller, J. S., Inorg. Chem. 16, 957 (1977).

    Article  Google Scholar 

  195. Cullen, D. L., and Meyer, E. F., Jr., J. Am. Chem. Soc, 96, 2095 (1974).

    Article  Google Scholar 

  196. Meyer, E. F., Jr., Acta Crystallogr. B28, 2162 (1972).

    Google Scholar 

  197. Robertson, J. M., and Woodward, I., J. Chem. Soc, 219 (1937).

    Google Scholar 

  198. Mason, R., Williams, G. A., and Fielding, P. E., J. Chem. Soc. Dalton Trans., 676 (1979).

    Google Scholar 

  199. Robertson, J. M., J. Chem. Soc, 1195 (1936).

    Google Scholar 

  200. Scheldt, W. R., and Dow, W., J. Am. Chem. Soc. 99, 1101 (1977).

    Article  Google Scholar 

  201. Brown, C. J., J. Chem. Soc. A, 2488 (1968).

    Google Scholar 

  202. Robertson, J. M., and Woodward, I., J. Chem. Soc, 36 (1940).

    Google Scholar 

  203. Brown, C. J., J. Chem. Soc. A, 2494 (1968).

    Google Scholar 

  204. Ukei, K., Acta Crystallogr. B29, 2290 (1973).

    Google Scholar 

  205. Gouterman, M., in The Porphyrins, Vol. III., D. Dolphin, Ed., Academic Press, New York (1978), pp. 1–165.

    Google Scholar 

  206. Euler, W. B., and Hoffman, B. M., manuscript in preparation.

    Google Scholar 

  207. Hoard, J. L., in Porphyrins and Metalloporphyrins, K. M. Smith, Ed., American Elsevier, New York (1978), pp. 321–327.

    Google Scholar 

  208. Hilti, B., and Mayer, C. W., Helv. Chim. Acta 61, 501 (1978).

    Article  Google Scholar 

  209. Bloch, A. N., Cowan, D. O., Beckgaard, K., Pyle, R. E., Banks, R. H., and Poehler, T. O., Phys. Rev. Lett. 34, 1561 (1975).

    Article  Google Scholar 

  210. Thomas, G. A., Schafer, D. E., Wudl, F., Horn, P. M., Rimai, D., Cook, J. W., Glocker, D. A., Skove, M. J., Chu, C. W., Groff, R. P., Gillson, J. L., Wheland, R. C., Melby, L. R., Salamon, M. B., Craven, R. A., De Pasquali, G., Bloch, A. N., Cowan, D. O., Walatka, V. V., Pyle, R. E., Gemmer, R., Poehler, T. O., Johnson, G. R., Miles, M. G., Wilson, J. D., Ferraris, J. P., Finnegan, T. F., Warmack, R. J., Raaen, V. F., and Jerome, D., Phys. Rev. B 13, 5105 (1976).

    Article  Google Scholar 

  211. Esposito, J. N., Sutton, L. E., and Kenney, M. E., Inorg. Chem. 6, 1116 (1967).

    Article  Google Scholar 

  212. Meyer, G., Hartmann, M., Wöhrle, D., Makromol. Chem., 176, 1919 (1975).

    Article  Google Scholar 

  213. Delhaes, P., Coulon, C., Amiell, J., Flandrois, S., Toreilles, E., Fabre, J. M., and Giral, L., Mol. Cryst. Liq. Cryst. 50, 43 (1979).

    Article  Google Scholar 

  214. Batail, P., La Placa, S. J., Mayerle, J. J., and Torrance, J. B., J. Am. Chem. Soc. 103, 951 (1981).

    Article  Google Scholar 

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  1. Department of Chemistry and Materials Research Center, Northwestern University, Evanston, Illinois, 60201, USA

    Brian M. Hoffman, Jens Martinsen, Laurel J. Pace & James A. Ibers

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    Joel S. Miller

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Hoffman, B.M., Martinsen, J., Pace, L.J., Ibers, J.A. (1983). Structural, Magnetic, and Charge-Transport Properties of Stacked Metal Chelate Complexes. In: Miller, J.S. (eds) Extended Linear Chain Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4175-8_10

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